钛氧

The substituted half-sandwich titaconece with bulky alkoxyl group [CpTiC1〓 or CpTi 〓] or indene ring can not be fluorinated by BF〓·Et〓O under the selected condition, but still coordinates with the BF〓, this coordination then enhances the steric effect that stabilizes the precursor and hinders the reduction of the Ti to the Ti species, reflected in the decrease in polymerization activity.

但是这个转化受主催化剂分子的空间位阻和聚合反应温度的影响，当主催化剂为大位阻的烷氧基取代茂钛络合物或茚钛络合物时，在一般的聚合温度下BF〓不能对它们进行氟化，但可以和其中的OR配位，这种配位进一步加剧了空间位阻，从而阻碍了活性中心的形成，导致催化活性的下降。

In the structure of the complex, two oxygens of phenol in the ligand are bound to Ti to form a five membered cyclic complex of titanocene.

在配合物结构中，茜素红配体中的两个羟基氧均与钛键合，形成五元环状二茂钛配合物，且化合物中还存在两个结晶水

The calculation method represented in this paper is very simple and convenient. By comparing the relative errors, the method is better than other methods. Moreover, it can be used to calculate molar Gibbs free energy and molar enthalpy of formation of all complex oxysalt minerals including a series of titanate whiskers that author's group has studied for many years. The thermodynamic data for the series of titanate whiskers provide necessary fundamentals to their preparation.

本文提出的方法计算步骤十分简单，从相对误差来看，本方法和其他方法相比精度较好，可以计算包含本课题组长期研究的钛酸盐系列晶须的所有复杂含氧盐矿物的摩尔生成Gibbs自由能和摩尔生成焓，为热力学在钛酸盐系列晶须制备中的应用提供理论支持。

Liquid-phase epoxidation of allyl chloride with hydrogen peroxide was carried out over Ti-MWW, a novel titanosilicate with the MWW structure, to synthesize epichiorohydrin selectively and effectively. Ti-MWW proved to be superior to the conventional TS-1 catalyst in both catalytic activity and product selectivity. Ti-MWW prefers aprotic solvents of acetone and acetonitrile, both of which can restrain the solvolysis of epichiorohydrin, whereas TS-1 favors a protic solvent of methanol.

研究了具有MWW结构的新一代钛硅分子筛Ti-MWW催化剂对烯丙基氯液相环氧化高效合成环氧氯丙烷的催化性能结果表明，Ti-MWW的催化活性以及产物选择性均优于传统的钛硅分子筛TS-1，对于Ti-MWW，合适的溶剂为非质子性溶剂丙酮和乙腈，在该溶剂中环氧化物不易发生溶剂化开环反应；而对于TS-1，合适的溶剂是质子性溶剂甲醇，但甲醇可导致醇醚副产物的生成。

In the last part of the thesis, synthesis of mesostructured titania has been explored with a selfassembly of hydrophilic polymer and anionic surfactant used as template, along with titanium alkoxide as inorganic precusor. The product was proved to have mesostructure and the fiber and spherical morphology is favored.

本文最后一部分首次探索以亲水性高分子和阴离子表面活性剂形成的自组装体为模板、烷氧基钛为无机原料合成介相结构氧化钛；产物具有介相结构，其颗粒形貌为纤维和圆球的混合物。

Peroxo titanic acid sol; needle-like anatase crystal sol; nano TiO2 thin films; hydrothermal reaction; photocatalysis

过氧钛酸溶胶，针状锐钛矿晶粒溶胶，纳米TiO2薄膜，水热反应，光催化

Pt-inserted nanotube titanic acid was prepared as follows: H_2PtCl_6 ethanol solution was filled into the titanic acid nanotubes and then annealed in air at 673 K for 3 h.X-ray photoelectron spectroscopy showed that H_2PtCl_6 has been converted to Pt~0 and PtO.The result of electron spin resonance revealed that there are single-electron-trapped oxygen vacancies to be formed in PNTA after heat treatment in air.

通过在真空条件下将氯铂酸的乙醇溶液引入到钛酸纳米管内，再经过热处理制备了镶嵌铂的纳米管钛酸。X射线光电子能谱表明氯铂酸大部分转变成Pt0和PtO，顺磁共振谱表明在PNTA中生成了束缚单电子的氧空位，在紫外-可见扩散漫散射谱谱上表现出对可见光有吸收能力。

We used ITO glass substrate and high purity（99.99%） titanium , put to use sputtering process, add to high purity O2 make it complete the best structure film and the thickness about 1400 . By way of 500℃ anneal could got a better anatase phase, this result could easy reaction with electrolyte to increase electron-transferred. Used as spin casting covering PR on ITO substrate, transferring patterns of array circular shapes on a mask to photography, used optimize temperature and time to hard bake. Finally used HCl to etching underexposed TiO2 area, and acetone to tripper top PR, make it to accomplish pillars shape TiO2 electrode.

本研究使用ITO玻璃基板为底材在以高纯度钛(99.99%)为靶材，利用溅镀方式通入纯氧使其行成高纯度TiO2镀於ITO基板上行成厚度约1400的薄膜，且经500℃高温烧结使其行成最强的锐钛矿结晶相，此晶相有利於与电解液反应进而增加电子的转移，提升太阳能电池最佳的效率，在以旋转涂布方式铺上光阻，以矩阵排列的圆孔光罩曝光、最佳的温度及时间来烘烤、显影后；使用盐酸以等向性湿蚀刻方式蚀刻未曝光之TiO2区域，最后利用鈵铜将最上层光阻去除，使其行成柱状TiO2的电极。

The deposition thickness of allylamine was increased with the treating time. The surface textures were changed following different procedures except allylamine groups and it means that the 30 min deposition thickness of allylamine is too thin to change the surface contours.

SEM-EDS的结果显示在未经任何处理及经氩气电浆清洁后的钛金属表面，侦测到主要为钛元素，丙烯胺电浆处理后，即可测到氮元素；戊二醛作用后表面有氧元素的出现；白蛋白处理后即可测得碳及氧元素。

The SEM-EDS showed that the content of surface elements was changed after treated with glutaraldehyde or albumin indicated that argon plasma only had surface cleaning effect and did not change surface composition and the allylamine deposition thickness was too thin to show the difference in SEM-EDS findings. The XPS results confirmed the argon plasma cleaning effect and revealed that the ratio and the binding energy of surface elements changed with different treatment procedures and were similar to what expected to coat on the titanium surface.

XPS更进一步证实，氩气电浆只有清洁钛金属表面的作用，并不会改变其表面化学组成；其余各组的钛、碳、氮、氧的比例及键结能量随著处理程序而改变，可知表面上有化学组成之改变，且随不同处理程序所得到表面元素之百分比及键结能量，与预期的表面披覆物元素百分比及键结能量相近。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。