钛

The research of this dissertation can not only be applied in preparation of titanium dioxide used in synthetics fiber, but also have important significance to improve general product quality of anatase and to exploder the other variety of titanium white such as titanium white slurry, titanium white with catalyze, titanium white used in food and so on.

本文的研究成果不但成功地应用于化纤钛白的制备，同时对提高一般锐钛钛白的产品质量。开发其它钛白品种（钛白水浆、光催化钛白、食品钛白）等具有重要的意义。

It was indicated by UV-Vis spectra characterization that the precursor always contains the tetrahedral Ti species and the octahedral Ti species regardless of the Ti content. Calcination of the precursor resulted in a partial condensation of the octahedral Ti species to form the anatase phase.

UV-Vis 光谱表明，Ti-MWW 合成原粉中含有四面体的钛和八面体的钛，而八面体的钛属于一种骨架外钛，未经酸处理而煅烧会使部分八面体钛缩合形成锐钛矿，而经过酸处理和煅烧后的分子筛则几乎不含有锐钛矿。

In the protein adsorption and osteoblast culture in vitro, more surface hydroxyl groups and higher polar component of surface energy led to more protein and cell adsorbed, and higher cellular activity.

在本论文中，通过金红石二氧化钛膜、锐钛矿二氧化钛膜、含钙的钛表面、含磷的钛表面和Ti-羟基磷灰石涂层的表征，结合羟基磷灰石沉积、蛋白质吸附和细胞体外培养，研究了钛的表面表征与生物活性的关系。

According to the practical needs of chrome-free tannage, titanium is abundant in nature, easily obtainable and ecologically friendly, titanium tannage can produce a leather with similar performance to chrome-tanned leather, so the research of titanium tannage to alternative chrome tannage was established as the research direction of this thesis. The preparation of novel titanium tanning agent, factors affecting titanium tannage, titannium tannage mechanism and titanium combining tannage were studied.

本文从对非铬鞣体系的实用性要求出发，在对几种常用金属盐鞣剂的鞣性和鞣革综合性能的分析基础上，并结合它们的资源和毒性等方面的因素，提出了钛鞣是理想的铬鞣的替代鞣法的观点，确定了以资源丰富、无毒和鞣革综合性能好的钛盐代替铬盐的研究方向，研究了新型钛鞣剂的制备方法、影响钛鞣的因素，并对钛鞣机理和钛结合鞣法等方面进行了深入的研究。

The results showed that the TiN andN films are polycrystalline phase. The properties and structure of TiN films are mainly determined by the N2 mass flow rate, and as the N2 mass flow rate increases, the structure of the TiN films transforms to f.c.c. type leading to better the properties of films. The presence of negative bias voltage can optimize the grain of TiN films, lower the defect proportion and denser the films, which improves the hardness of films. The TiN films conform to the free carrier absorption mechanism and there are many of free electrons with lower N content in TiN films. With the increase of N content, the quantity of free electrons and reflectivity of films decrease, and the plasma frequence shifts to the lower energy, which leads to the regular change of colors of films from silver, yellowy, golden to yellow-red, meanwhile the lightness of films decreases. The goldenN film consists of TiN and ZrN phase, but belongs to a sigle f.c.c. structure with (111) preferred orientation. The Zr-doping dosen't change the position of the valance band, conduction band and forbidden band ofN film, but leads to the presence of new energy levels, which is the reason thatN film remains golden. The transparent hard films with good corrosion resistance and high hardness have been prepared and the further reseachs showed that the grain size of those films is by far smaller than the wave length and the width of forbidden band of those films is very broad, is the reasons that those films are transparent.

研究表明：氮化钛和N 薄膜为多晶态，氮流量决定了氮化钛薄膜的结构和性能，增加氮流量能使氮化钛薄膜的结构向面心立方结构转变，从而得到性能良好的氮化钛薄膜；施加负偏压能优化氮化钛晶粒和减少薄膜中的缺陷，使膜层变得更致密，从而提高薄膜硬度；氮化钛主要遵循自由载流子光吸收，氮含量较少时薄膜中的自由电子数目较多，随着氮含量的增加，薄膜中的自由电子数目不断减少，反射率逐渐降低，等离子体频率向低能端移动，从而使薄膜颜色出现规律变化，由金属色银白色到淡黄、金黄再到红黄，并且薄膜亮度呈下降趋势；金黄色的N 薄膜中存在TiN 和ZrN 的分离相，但其为单一的面心立方结构并具有(111)面择优取向；相对于TiN 薄膜，Zr 掺杂后，并没有使薄膜的导带、价带和禁带发生变化，只是在TiN 禁带内增加了新能级，这也正是掺杂Zr 后，薄膜仍

This paper contains three parts: 1 Synthesis of novel titanium complexes; 2 Polymerization behaviors of alkoxyl substituted Cp Titanocenes as catalysts for styrene syndiotactic polymerization; 3 Polymerization behaviors of alkenyl substituted Cp Lanthanocenes as Methyl Methacrylate polymerization catalysts.

中文题名新型茂钛、噁唑啉钛络合物的合成、表征以及茂钛、茂稀土络合物催化性能的研究副题名外文题名 Synthesis，characterization of novel Cp，oxazoline titanium complexes and polymerization behaviors of titanocenes and lanthanocenes 论文作者张浩导师钱延龙黄吉玲学科专业应用化学研究领域\研究方向金属有机与均相催化学位级别博士学位授予单位华东理工大学学位授予日期2003 论文页码总数148页关键词金属有机化学稀土络合物噁唑啉类钛络合物茂钛络合物馆藏号BSLW /2003 /O627 /27 本论文包括三部分内容：1）有机金属钛络合物的合成；2）烷氧基取代茂钛络合物催化苯乙烯间规聚合的研究；3）烯基取代茂稀土络合物催化甲基丙烯酸甲酯聚合的研究。

Because there are many kinds of matrixes in titanium matrix composite, we select some typical ones as investigated subject in many titanium alloys or titanium aluminide intermetallics, and then simulate the distribution of thermal residual stresses under the appropriate composites fabrication and heat treatment parameter. We not only hope to seek better titanium matrix, but also discover the relationship between the material properties and the thermal residual stresses, and then provide some theoretical guidance for the selection of the matrix in titanium matrix composites.

鉴于当前钛基复合材料中钛基体的多样性，我们将在各种类型的钛合金和钛铝金属间化合物中，挑选出较为典型的作为研究对象，利用本文得到的较为理想的复合材料加工和热处理工艺参数，逐一模拟它们的残余热应力，找到残余热应力分布较为理想的钛基体，并且，希望能够寻找到材料性能与热残余应力的相互关系，为钛基复合材料基体的选择提供一定的理论指导。

Composition of suspension will chang from titanium monoxide to titanium dioxide during standstill procedure. Experimental results show that the proposed method can successfully prepare the anatase phase of titanium dioxide .In the photocatalysis experiment, the prepared titanium dioxide nanofluid absorbs the Ultraviolet when light wavelength was 360 to 380 nm. Adsorption experimental results show that the efficiency of absorbing methylene blue using TiO2 is higher than that for TiO2 (Degussa P-25) or ZnO. Depigmentation of methylene blue experimental using TiO2 can depigmentize methylene blue reach 100% in 60 min.

悬浮液所含之奈米颗粒在静置过程中，成份方面会由似一氧化钛转变为二氧化钛；在结晶组成方面，所制备之二氧化钛颗粒之结晶组成为锐钛矿结构；在光催化方面，所制备之奈米二氧化钛悬浮液在光波长360nm~380nm时产生吸收紫外光现象，在吸附实验中本制程所制备的二氧化钛颗粒的吸附效果优於商用的二氧化钛及氧化锌，在亚甲基蓝的脱色实验中本制程所制备的二氧化钛颗粒能在60分钟内达到脱色率100%。

Our product is a titanium , sparse noble metal material such as nickel, Mu , tantalum , zirconium processes; The tube , stick , silk , belt , board , foil , net , cake are encircled by reaching alloy products; Reaction equipment (500 L reaction boilers , titanium steel compound reaction boilers , titanium outside plate manage the warmup reaction boiler , the nickel steel compound reaction boiler); Heat exchanger (the titanium enumerates a pipe heat exchanger , titanium plate-type heat exchanger , the nickel heat exchanger , titanium helix plate-type heat exchanger); Compound board (titanium steel compound board , titanium copper compound board , titanium aluminium compound board finished product); The accessory and the heater titanium net are blue , the titanium flange , titanium nut titanium filter , titanium pump , titanium plate manage , the positive electrode , titanium centrifugal machine , titanium heater , various mistake are labeled with equipment and the accessory.

我们的产品是钛、镍、钼、钽、锆等稀贵金属材料加工；管、棒、丝、带、板、箔、网、饼环及合金制品；反应设备（500L反应釜、钛钢复合反应釜、钛外盘管加热反应釜、镍钢复合反应锅）；换热器（钛列管式换热器、钛板式换热器、镍换热器、钛螺旋板式换热器）；复合板（钛钢复合板、钛铜复合板、钛铝复合板成品）；配件及加热器（钛网蓝、钛法兰、钛螺母钛过滤器、钛泵、钛盘管、阳极、钛离心机、钛加热器、各种非标设备及配件。

Titanium products processing factory mainly producing and processing titanium plate, titanium ingot, titanium tube, titanium wire, titanium rod, titanium shaft, titanium target, titanium flange, such as non-ferrous metal products, Agere are Baoji Titanium Co., Ltd.

钛制品加工分厂主要生产加工钛板、钛锭、钛管、钛丝、钛棒、钛轴、钛靶、钛法兰等有色金属制品，是宝鸡杰尔钛业有限公司生产加工主要力量。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。