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The second intrusive rocks (the representative rocks: Tiantangzhai and Jiuzihe granites) are high-k calc-alkaline and a few are shoshonite rock series, Tiantangzhai and Jiuzihe intrusive rocks show respectively metaluminous and transitional charaterastics between metaluminous and peraluminous.

第二期侵入岩(以天堂寨、九资河侵入岩为例)为亚碱性的碱性岩系,多数属于高钾碱性岩系,少数为钾玄岩系。

The Paleoproterozoic Beidahe Group-complex remains as continental shivers in the interior of the North Qilian orogen. In its early stage of development, there occurred abundant amphibolite. The protolith of the amphibolite is basalts. The Alk-∑FeO-MgO plot, REE features and Rittmann index show that the protolith belongs to the calc-alkaline suite and exceptionally shows the subalkaline character. The rock is characterized by higher Al2O3 and ∑FeO and lower Mg#, indicating that it has a higher degree of compositional evolution and that the formation of volcanic rocks is related to activation of older crust. Highly fractionated REE patterns and amphibolite on the Ti-Zr-Y plot, Ni-FeO/MgO plot and Ta/Yb-Th/Yb plot all indicate the characteristics of volcanic arcs and active continental margins. On the geochemical diagram of basalt, the overall REE features are in the main analogous to those of calc-alkaline island-arc basalt, with Sr87/Sr86=0.71617–0.72033,Nd143/Nd144=0.512414–0.512495 and εNd=–2.79 to –4.37,εSr=245.78–305.3, showing that the magma was derived from the crust or subjected to contamination with the lower crust below the continent.

提要:以大陆碎块形式残存于北祁连造山带内部的古元古代北大河岩群早期发育有大量的斜长角闪岩,其原岩为玄武岩,Alk—∑FeO—MgO图解,REE特征,里特曼组合指数等均显示斜长角闪岩属碱性系列范围,个别显示弱碱性,斜长角闪岩具有较高的Al2O3,∑FeO和低的Mg#,这些特点反映其成分演化程度较高,表明火山岩的形成与古老地壳的活化有关,有较强分异的稀土元素分配模式,在Ti—Zr—Y图,Ni—FeO/MgO图解和Ta/Yb—Th/Yb图解上斜长角闪岩均显示火山弧或活动大陆边缘的特点,在玄武岩的地球化学形式图,稀土元素整体特征与碱性岛弧玄武岩基本相同;87Sr/86Sr=0.716 17~0.720 33, 143Nd/144Nd=0.512 414~0.512 495,εNd=-2.79~-4.37。

The adsorption behaviour of chemically different superplasticizers, such as melamine formaldehyde sulphite polycondensate,β-naphthalene sulfonate formaldehyde polycondensate and polycarboxylate, on early hydrating cement phases was studied. For this purpose, pure ettringite AF(subscript t, monosulfate AF(subscript m and syngenite were prepared. The adsorbed amount and zeta potential of early hydration products were measured.

制备了矾石AF(下标 t、单硫型硫铝酸AF(下标 m和钾长石类单矿物,并研究了三聚氰胺磺酸盐甲醛缩聚物、β-萘磺酸盐甲醛缩合物及聚发酸盐等几种化学成分不同的超塑化剂在其早期水化颗粒表面上的吸附行为。

Highquality hydrogen for industry uses,dilute nitric acid,refined nitric acid,calcium nitrate tetrahydrate,calcium nitrate dihydrate,corrugated metal structured packing,catalyst for polyethylene,ultrahighmolecular weight polyethylene,15N labelled compounds,purificants of petrochemical industry,highmolecular flame retardants,molecular sieve desiccant,chemical machinery and equipment,separation equipment for chemical industry,testing and monitoring analyzers,detectors and equipment.

工业用优质氢,优质硝酸,硝酸,硝酸,金属规整波纹填料,聚乙烯催化剂,超高分子量聚乙烯,N15标记化合物,石化净化剂,高分子材料阻燃剂,分子筛干燥剂,化工机械和设备,化工分离设备,化工检测设备。

The physical and chemistry simulation on TSA process was established, and the mechanism of thaumasite formation was taken on further discussion.

摘 要:研究水泥砂浆试件在碳硫硅酸型硫酸盐侵蚀过程中的物理化学性能变化,对TSA过程进行模拟,进一步探讨碳硫硅酸的形成机理。

This proves that concrete can produce thaumasite in a sulfate environment over 15 ℃, and the existence of Mg2+ can accelerate the formation of thaumasite.

证明水泥混凝土在>15 ℃的硫酸盐侵蚀环境下亦可生成碳硫硅酸,而Mg2+的存在对碳硫硅酸的形成过程具有加速催化作用。

X-ray diffraction, scanning electron microscope, energy dispersive spectrum and laser Raman spectrum analysis were used to identify thaumasite in paste sample stored in 10% of MgSO_(4) solution at different temperatures .

矾石型和石膏型等硫酸盐侵蚀破坏机理已得到广泛研究与认同,然而另一种硫酸盐破坏类型———碳硫硅石型却没有受到应有重视。

Meanwhile, the three-dimensional mechanical characteristics of calcium thenardite salt rock take great changes after a period of solution pervasion actions.

由于溶解渗透使得矿物组成及其结构的变化,芒硝盐岩在溶解渗透前后三轴力学特性差异也很大,在2.0MPa围压的作用条件下,溶解渗透49h之后,芒硝盐岩的强度由未溶解渗透时的46.53MPa,降低为溶解渗透后的11.42MPa:与此同时,弹性模量也由43.700MPa降低为0.834MPa。

It was found that halite was closely cemented with soil particles, thenardite (Na_2SO_4) was transformed from mirabilite (NasSO_4·VlOH_2O) by dehydration, and the glanberite [Na_2Ca (SO_4)_2] was formed by calcium sulfate and sodium sulfate. These salt crystals separated were clear, without any mixture.

扫描电子显微镜的照片,展示出某些盐类结晶的自然特征,它们是:与土粒胶结紧密的石盐、由芒硝(Na_2SO_4·10H_2O)脱水转变成的无水芒硝(Na_2SO_4)、或由硫酸钠、硫酸形成的复盐——芒硝Na_2Ca(SO_4)_2。

Meanwhile, the three-dimensional mechanical characteristics of calcium thenardite salt rock take great changes after a period of solution pervasion actions. The compression strength of calcium thenardite rock salt changes from 46.53MPa to 11.42MPa after 49h solution pervasion with 2.0MPa confining pressure. Accordingly, the elastic modulus changes from 43.700MPa to 0.834MPa.

由于溶解渗透使得矿物组成及其结构的变化,芒硝盐岩在溶解渗透前后三轴力学特性差异也很大,在2.0MPa围压的作用条件下,溶解渗透49h之后,芒硝盐岩的强度由未溶解渗透时的46.53MPa,降低为溶解渗透后的11.42MPa;与此同时,弹性模量也由43.700MPa降低为0.834MPa。

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