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After SBF solution cultivation for some days, the Ca/P coating was very easily deposited on the porous surface that was constituted of cystiform polygon made up with irregular nanometer circles like honeycomb. The energy spectrum showed that n/n atom ratio is about 1.61:1 which is very similar to that of HA and human bone. The active surface of the porous titanium after acid-alkali treatment and SBF solution condition which calcium-phosphorus ions was supersaturated induced the formation of Ca/P deposition layer.

SBF溶液培养后发现沉积层由蜂巢状多边形胞状物组成,这些胞状物是由网状纳米环无规则排列构成,能谱测定、磷元素原子比n/n约为1.61∶1,与HA和人骨中的磷原子比很接近;通过对沉积机理的分析,认为微孔钛的活性表面和SBF溶液过饱和离子浓度的环境造成了液相中磷盐的沉积。

The chemical activating mechanism of UA is that CG can stimulate pozzolanicity more effective than gypsum because of higher solubility and looser crystal structure; but CG has poor property on retardation setting, and this shortage can be solved by mixing with gypsum; CS can offer alkali activity, which can depolymerize silica and aluminum glass, and benefit for other activity methods and overcome the disadvantage of HF on setting time; Sodium sulfate improves early strength greatly but loses the final strength. NF can improve both early and final strengths.

联合激发技术的化学激发机理是,煅烧石膏溶解度高及晶体结构松弛,比天然石膏的活性激发效率高,但降低石膏的缓凝作用,与天然石膏混合既可提高活性又能保持缓凝作用;干法电石渣提供碱激发,促进高灰中硅、铝玻璃体解聚,并克服高灰对凝结时间的不利影响;硫酸钠虽然早强作用明显,但使后期强度倒缩,NF使各龄期活性都得到提高;磨细的物理激发使高灰大颗粒中的CaO和富集碳组分被磨细、分散,活性增加而危害性降低。

SiO2 causes early decomposition of CaSO4 due to the formation of calcium silicate and dicalcium silicate during the reaction of CaO and SiO2 at high temperature, and the formation of calcium sulphosilicate above 1200℃ helps to retard CaSO4 decomposition.

SiO2在高温下易与CaO发生固相反应形成硅酸二和硅酸使得CaSO4的初始分解温度降低,在1200℃以后硫硅酸的形成对CaSO4的分解有一定的延缓作用。

The results showed that the CPC powder mainly consists of dicalcium phosphate dehydrate and tetracalcium phosphate. DCPD changed into hydroxyapatite during the harden process.

结果表明,CPC粉末的主要成分为磷酸氢、磷酸四,在固化过程中磷酸氢转化为羟基磷灰石。

In the high alumina cement , dicalcium aluminate silicate is transformed into Q phase.

将高铝水泥中的惰性成分硅铝酸二(C2AS)转化为水化活性良好的Q相,组成Q相铝酸一七铝酸十二(C12A7)高铝水泥系统,对此系统的烧成条件进行研究。

The investigated potassium carboxylates included: monocarboxylate potassium acetate, dicarboxylate potassium tartrate (K2Tart), tricarboxylate potassium citrate (K3Cit), and tetracarboxylate dipotassium of ethylenediaminetetraacetic acid (K2EDTA). KOAc can only induce calcium oxalate monohydrate, while K3Cit and K2EDTA induce COM and calcium oxalate dihydrate. The ability of multicarboxylates to induce COD formation was increased with increasing their concentrations.

加入一元醋酸钾只生成一水草酸晶体;三元柠檬酸钾(K3Cit)和四元乙二胺四乙酸二钾(K2EDTA)可诱导二水草酸形成,且随着其浓度增加,对COD的诱导能力增加,而二元酒石酸钾(K2Tart)同时诱导了COM, COD和三水草酸生成。

NADPH oxidase inhibitor, diphenylene iodonium chloride (DPI, 10 μmol/L), abolished histamine-stimulated calcium oscillations both in normoxic and posthypoxic PAECs.(3) Xanthine oxidase inhibitor, oxypurinol (100 μmol/L), did not affect the calcium oscillation kequency in normoxic PAECs. However, it significantly decreased the elevation of calcium oscillation frequency in posthypoxic PAECs.

黄嘌呤氧化酶抑制剂,别嘌呤醇(oxypurinol,100 μmol/L)能显著降低组胺刺激的缺氧后肺动脉内皮细胞升高的振荡频率,但降低后的振荡频率仍高于常氧组,别嘌呤醇对组胺刺激的常氧组肺动脉内皮细胞振荡频率无显著影响。

NADPH oxidase inhibitor, diphenylene iodonium chloride (DPI, 10μmol/L), abolished histamine-stimulated calcium oscillations both in normoxic and posthypoxic PAECs.(3) Xanthine oxidase inhibitor, oxypurinol (100μmol/L), did not affect the calcium oscillation frequency in normoxic PAECs. However, it significantly decreased the elevation of calcium oscillation frequency in posthypoxic PAECs.

黄嘌呤氧化酶抑制剂,别嘌呤醇(oxypurinol, 100μmol/L)能显著降低组胺刺激的缺氧后肺动脉内皮细胞升高的振荡频率,但降低后的振荡频率仍高于常氧组,别嘌呤醇对组胺刺激的常氧组肺动脉内皮细胞振荡频率无显著影响。

The polymeric sol is obtained by process of preparing a calcium salt solution, containing calcium ethoxide dissolved in organic acid, and a phosphate solution, containing triethyl phosphite or triethyl phosphate dissolved in the organic acid, mixing the calcium salt solution with the phosphate solution to produce a mixed solution, and aging the mixed solution.

本发明的磷酸化合物的聚合物溶胶是通过如下步骤制备的:制备含有溶解在有机酸中的乙醇盐溶液和含有溶解在该有机酸中的亚磷酸三乙酯或磷酸三乙酯的磷酸盐溶液;及将该盐溶液和该磷酸盐溶液混和制得混合溶液,并老化该混合溶液。

The high compressive strength is obtained when the modulus of the activator viz., molar ratio of SiO2/Na2O is 1.5, and the proper content of this activator evaluated by the amount of Na2O to the high-calcium fly is 10 %. The compressive strength of these samples is 63.4 MPa when they is cured at 75 oC for 8 hours flowed by curing at 23 oC for 28 days. The main gels of geopolymer and calcium silicate hydrate, and Gismondine co-exist and bond some remaining unreacted fly ash spheres.

结果表明:复合碱激发剂适宜的模数M =n(SiO2)/n(Na2O)为1.5,掺量为Na2O当量10%;适宜养护条件为,75oC养护8h,然后在23oC室温养护至所需龄期,其28d抗压强度达63.4MPa;碱激发高粉煤灰同时生成地聚合物凝胶和水化硅酸凝胶,并有类沸石矿物生成,反应产物与未反应的粉煤灰颗粒胶结成较为密实的高粉煤灰地聚合物。

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