钌的

The role of ruthenium- and rhodium-complexes as photosensitizers under irradiation with lights of different wavelengths has ...

在几种不同波长范围的照射条件下，比较了钌和铑的络合物作为光敏剂时的不同反应特性，讨论了它们的差别。

Currently, a type of ruthenium catalyst is already being used in a commercial ammonia plant (3), proving its potential for promising applications in industry.

目前，钌催化剂的类型用于一棵商业氨植物(3)已经，证明它的潜力为在产业的有为的应用。

In the photolysis of 9, phosphine dissociation is followed by addition of HCl yielding the neutral vinylidene complex Cl[Ru1]=C=CHC(CCl3)2 10, [Ru1] = Cp

当进行光裂解错合物的反应时，在加入氯化氢分子的状况下，产生一个中性的钌金属亚乙烯基错化合物Cl[Ru1]=C=CHC(CCl3)2 10， [Ru1] = Cp(PPh3Ru 并且伴随著一个三苯基磷分子的离去。

In order to solve the backward electron transfer problem, 9 kinds of rhenium bipyridyl photosensitive dyes with different electron donating groups on the p or m-position of the pyridine rings, 2 kinds of rhenium bipyridyl and 2 kinds of ruthenium tris-bipyridyl photosensitive dyes with two tyrosine ethyl ester groups on the bipyridyl rings were designed and synthesized.

本文针对该类太阳能电池中存在的电子回传问题，设计合成了在吡啶配体的间位和对位带有不同供电基团的9种铼联吡啶光敏染料，在联吡啶配体上带有两个酪氨酸基团的2种铼联吡啶和2种钌三联吡啶光敏染料。

A set of in situ infrared apparatus which can beoperated at liquid nitrogen temperature is established. The structuralstudies of polyhydride of Ruthenium is carried out from roomtemperature to liquid nitrogen temperature. The structural conversion of〓 between dihydrogen and dihydride is observed firstly. It issuggested that with temperature changing, a fluxional structureconversion between terminal and bridged hydrogen appears. NMR studyand DV-Xα calculation are performed in this paper.

建立了可至液氮温度的原位红外测试装置，进行了室温至液氮温度区间钌多氢化合物的结构研究，首次发现了〓在室温存在分子氢与原子氢的结构流变，发现了新化合物存在随温度变化而出现桥氢与端氢的结构转化；进行了NMR测试及DV—〓计算。

Ruthenium-modified solid catalyst Ru-Co2-CeO2 was applied to the lactonization of diols in the presence of molecular oxygen and achieved highly efficient catalytic performance.

将钌改性的固体催化剂Ru-Co2-CeO2用于以分子氧作为氧化剂的二元醇的催化氧化内酯化反应中，发现该催化剂具有很好的催化反应性能。

This part includes chapter 5, 6, 7, 8, and chapter 9. In chapter 5, we synthesized four Ruthenium chelates, which can be used as ECL reagents. We also investigated their fluorescent properties as well as their electrochemical and ECL properties.

在第5章中，我们合成了四种带有标记基团的钌配合物电化学发光试剂，并对所合成的四种化合物的荧光性质、电化学性质及电化学发光性质等进行了初步探讨。

Meso-Tetrakis(2,6-dichlorophenyl)porphyrinmanganese chloride and carbonyl ruthenium meso-tetrakis(2,6-dichlorophenyl)porphyrin were prepared and used to catalyze the diastereoselective epoxidation and amidation of 3β-substituted Δ 5-steroid derivatives.

研究了 5 ，10 ，15 ，2 0 (2 ，6 二氯苯基)卟啉锰及其钌配合物这类非手性的催化剂催化3β取代的Δ5 甾体衍生物的非对映选择性环氧化及酰胺化反应。

A study is presented concerning the three different structural levels of isotactic polypropylene.

本文应用光学显微镜，扫描和透射电子显微镜从三种不同层次的结构水平上研究了α和β两种晶型的全同立构聚丙烯的球晶和晶片形态结构，特别是应用四氧化钌染色技术直接观察到两种不同晶型聚丙烯球晶中单独分离的晶片形态。

Energy dispersive spectrometer data confirm existence of zinc oxide and ruthenium oxide hexacyanoferrate in the hybrid film. The effect of type of monovalent cations on the redox behavior of hybrid film was investigated.

由能量分散性分光仪光谱证明了复合薄膜中氧化锌和氧化钌赤血盐的存在，并且研究不同单价的阳离子所显示的形式电位作用。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。