金属键

In the presence of catalytic rhodium acetate, ethyl 2-diazo-3-oxo-per fluoroalkanoates, reacted readily with nitriles to give a series of 5-fluoroalkyl substituted 1, 3oxazoles with high regio-selectivity through a metal carbenoid intermediate. The reactions of carbenoids with noncyclic vinyl ethers or cyclic vinyl ethers afforded dihydrofuroates in good to excellent yields. Interestingly, only vinyl C-H insertion compound was obtained concerning of the reaction of carbenoids with 2, 5dimethylfuran due to the steric hindrance of methyl group

醋酸铑分解2-重氮-3-氧代-全氟羧酸乙酯形成的金属卡宾作为1，3-偶极体，可以与一系列芳基或烷基取代的腈反应，高度区域选择性地生成一系列4-乙氧羰基-5-氟烷基取代的噁唑化合物；也可以与富电子的链状和环状的烯基醚反应，以优良的产率得到一系列氟烷基取代的二氢呋喃类化合物；而与2，5-二甲基呋喃的反应，由于甲基的位阻作用，只得到金属卡宾对呋喃3-位烯基碳氢键插入产物。

The pinacol coupling of carbonyl compounds affording pinacol s is an important method for the formation of 1, 2-diols and one of the most powerful methods for constructing carbon-carbon bond.

醛酮的片呐醇偶联是合成片呐醇的经典而有效的方法之一，也是形成C-C键的有效途径，一般通过醛酮与金属试剂或金属络合物作用来实现。

The pinacol coupling of carbonyl compounds affording pinacols is an important method for the formation of 1, 2-diols and one of the most powerful methods for constructing carbon-carbon bond.

醛酮的片呐醇偶联是合成片呐醇的经典而有效的方法之一，也是形成C-C键的有效途径，一般通过醛酮与金属试剂或金属络合物作用来实现。

Written in the "Victoriandustrial", harpsichord-laden Gothic style of "Opheliac" but with a metal edge,"Laced / Unlaced" shows the evolution from child prodigy classical violinist to reigning queen of metal Gothic / Industrial violin, and beckons us ever deeper into EMILIE AUTUMN's strange world with a flick of her black-nail-polished fingers.

写于&Victoriandustrial&，其中满载着大键琴哥特风格的&Opheliac&更添一丝阴暗金属的风味。&Laced / Unlaced&向我们展示的是她从一个天才少年古典提琴手向一个哥特金属/工业提琴女王的蜕变，同时跟随着她那涂着黑色指甲油的手指在琴弦上的游动，我们也被深深吸引到EMILIE AUTUMN那神奇的世界中去。

Written in the "Victoriandustrial", harpsichord-laden Gothic style of "Opheliac" but with a metal edge,"Laced / Unlaced" shows the evolution from child prodigy classical violinist to reigning queen of metal Gothic / Industrial violin, and beckons us ever deeper into EMILIE AUTUMN's strange world with a flick of her black-nail-polished fingers.

写于&Victoriandustrial&，其中满载着大键琴哥特风格的&Opheliac&又带着一丝金属。&Laced / Unlaced&向我们展示的是她从一个少年古典提琴手向一个哥特金属/工业提琴女王的蜕变，同时跟随着她那涂着黑色指甲油的手指的轻弹，我们也被深深吸引到EMILIE AUTUMN那神奇的世界。

Metallothioneins are a group of cysteine-rich, low-molecular-weight proteins, which can bind metal ions through mercaptide bonds.

金属硫蛋白(metallothionein，简称MT)是一类富含半胱氨酸的低分子量蛋白质，能够通过配位键结合金属离子。

From the analysis of FT-IR spectra, XRD patterns and SEM morphologies, the special functions of the chelating agents as follow: citric acid chelates metal ions, EDTA adjusts pH values and ethylene glycol polymerizes complex and replaces hydrogen bonds in SBT sol solution.

利用红外光谱、X衍射及扫描电镜等手段，证明柠檬酸主要起络合金属离子作用；EDTA除辅助交联金属离子外，主要用于调节pH值；而乙二醇用来聚合柠檬酸和EDTA，防止氢键产生，起稳定溶胶作用。

The complexing properties of compounds 10a, 10b, 11a and 11b toward alkali metal ions were studied by 〓H NMR titration, ESI-MS, UV-Vis spectra, Fluoresence spectra and liquid-liquid extraction. The results show:(1) the 1:1 complexes were formed.(2) The calix-crown 10a, 11a have a higher selectivity for Na〓 ions, whereas 10b, 11b for K〓 ions.(3) The complexing ability toward alkali metal ions was enhanced when the calix-crown have side arm carbonyl.(3) The coordination of alkali metal ions toward phenoxy, carbonyl and crown ethereal oxygens take place by rotation around the carbon-carbon bond of carbonyl and methylene.

六，用〓H NMR滴定，ESI-MS，UV-Vis，Fluorescence，液-液萃取实验研究了10a，10b，11a和11b对金属离子的配位性质，研究结果表明：1）杯芳烃冠醚衍生物同碱金属离子形成了1：1配合物，化合物10a、11a对Na〓具有较高的配位能力，化合物10b、11b对K〓具有较高的配位能力；2）在杯冠醚环的旁边引入带有羰基氧原子的基团作为侧臂参与配位可以加强对碱金属离子的配位能力；3）金属离子分别同苯酚氧，羰基氧，聚氧醚链氧发生了配位，配位过程中侧链基团涉及到了羰基碳与亚甲基碳的碳碳键的旋转过程。

Five new solid complexes were synthesized by the coordination of tranisition metals with a Schiff base(C17H21NO,HL) derived from adamantaneamine and salicylaldehyde ,and characterized by elemental analysis,molar conductance,infrared spectra,1H NMR spectra,thermal analysis.

合成了金刚烷胺水杨醛Schiff碱配体(C17H21NO，以HL表示)与5种过渡金属的新的配合物[MCl22]M=Mn(Ⅱ、Co、Ni、Cu、Cd，用元素分析、摩尔电导、红外光谱、1H NMR谱和热重分析对产物进行了表征；讨论了配体与中心金属离子的键合情况，并推测了配合物的结构。

The calculations on the binding energy and the population analysis of the ribose-Ln complexes were made by using the coordinates obtained from its single-crystal structures. Theoretical interpretions on the coordination between ribose and rare-earth metal ions were given by the results of the calaulation.

利用本论文得到的一系列的核糖—稀土配合物的单晶结构数据，对各配合物分子的结合能、配合物中各原子的净电荷布居以及稀土金属离子中各原子轨道在成键中的作用等方面内容进行了量子化学计算，并为核糖与稀土金属离子的配位作用提供了理论解释。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。