金属键

The sulphur atom in the intermediate has sp2 hybridization, and the remaining p orbital is symmetrical to the d orbital of the metal center. Thus, the lone pair on the p orbital can have interaction with the d orbital to form a π bond, which leads to the coplanarity of the center of Cp ring, Ru, P, S and Si atoms, rather than the deviation of P, S and Si atoms from the plane.

该中间体中，硫原子采取sp2杂化，硫原子剩余的一个p轨道与金属中心上的d轨道具有相同的对称性，因而该p轨道上的孤电子对可与金属中心上的d轨道形成π键，导致Cp环中心， Ru， S1， P和Si原子在同一平面内，而不是S1， P和Si原子偏离该平面。

The Xray diffraction analysis of the compounds (3) and (4) shows the presence of an intramolecular coordination of oxygen to the tin atom giving rise to a fivemembered ring in which the metal exhibits a distorted trigonal bipyramidal geometry.

并通过X-射线衍射测定了（3）和（4）的晶体结构，其空间群均为P2〓/c，晶胞内分子数Z=4，分子结构是以锡原子为中心金属原子、含分子内O→Sn配位键五员环的扭曲三角双锥结构，碳碳双键的两个氢是顺式构型。

In contrast to ordinary liquid and amorphous alloys, the number of 1551 bonds related to the icosahedral structure becomes very smaller with the decrease of temperature,but the numbers of 1311,1301,1201 bonds related to the rhombohedral structure are increased remarkably.

结果表明，与通常液态及非晶态金属相反，随着温度降低，与二十面体相关的1551键型数越来越少，而与菱面体相关的1311，1301和1201键型数目显著增加，最后形成以菱面体结构单元为主的非晶态结构。

The analyses of electronic structures shows that the catalytic reactivities for H2 adsorption of the different surfaces are dependent on the numbers of s orbital bonding electrons around Fermi level for the uppermost layer metal atoms which interact directly with H2. It is easy to form vacancy for hydrogen atoms next to iron atom, which indicates that hydrogen atom cannot be escaped, but it is difficult to from vacancy for hydrogen atoms next to magnesium atom, which indicates that hydrogen atom can be escaped. Hence it is thought that the change of dehydrogenating properties of MgH2 with or without a little iron addition attributes to the weakened bonding between magnesium and hydrogen.

分析电子结构发现：空位缺陷有助H2吸附于Mg表面，与Mg(0001)表面最上层与H2直接产生吸附作用的金属原子在费米能级附近s轨道的成键电子数密切相关；在Fe合金化MgH2体系中，与合金化元素Fe近邻的H原子形成空位的难度增加，H原子较难释放；与Mg近邻的H原子形成空位的难度减少，H原子容易释放；Fe合金化导致Mg-H之间存在较弱的成键作用，因此，MgH2体系的解氢性能得到提高。

A circle shear device for cutting holes in sheet metal as in claim 10 wherein said means for synchronous movement of said center shafts includes: a a motion linking mechanism including a plurality of gear cogs, cog belts and a jack shaft; and b said motion linking mechanism includes a motor for powered rotation of said center shafts.

削减的孔一个圆盘剪设备在金属板在要求10，说的中轴的同步运动的说的手段包括： a行动键路机构包括齿轮嵌齿轮、嵌齿轮传送带和副轴的复数；并且 b说的行动键路机构包括说的中轴的供给动力的自转的一个马达

A circle shear device for cutting holes in sheet metal as in claim 10 wherein said means for synchronous movement of said center shafts includes: a a motion linking mechanism including a plurality of gear cogs, cog belts and a jack shaft; and b said motion linking mechanism includes a hand crank to power the rotation of said center shafts.

削减的孔一个圆盘剪设备在金属板在要求10，说的中轴的同步运动的说的手段包括： a行动键路机构包括齿轮嵌齿轮、嵌齿轮传送带和副轴的复数；并且 b说的行动键路机构包括手摇把供给说的中轴的自转动力。

The calculated results show that azido in azides has linear structure , the most optimized CaN6 has linear structure , and the most optimized (CaN6)n (n=2～5) clusters have chain structure of perpendicularity of approximate diamond composed by two azido with two Ca atoms . The middle N atoms of azido show positive, the N atoms at both ends of azido show negative, and the N atoms effected with Ca atoms directly show more negative . There is strong ionic bond between the Ca and N atoms. The IR spectra of the most optimized (CaN6)n (n=1～5) clusters have four vibrational sections , the whole strongest vibrational peak lies in 2195～2280cm-1,and the vibrational mode is anti-symmetric stretching vibration of N-N bonds in azido . Stability analysis show that (CaN6)3 and (CaN6)5 clusters are more stable than other clusters .

结果表明，叠氮化合物中叠氮基以直线型存在，CaN6团簇的最稳定结构为线型结构，(CaN6)n(n=2～5)团簇首先由两个叠氮基与两个Ca原子构成一个近似菱形，再由菱形相互垂直形成链状最稳定结构；叠氮基中间的N原子显示正电性，两端的N原子显示负电性，且与Ca直接作用的N原子负电性更强，金属Ca原子和N原子之间形成很强的离子键；(CaN6)n(n=1～5)团簇最稳定结构的IR光谱分为4个部分，其最强振动峰均位于2195～2280cm-1，振动模式为叠氮基中N-N键的反对称伸缩振动；稳定性分析显示，(CaN6)3和(CaN6)5团簇相对于其他团簇较为稳定。

The positive peptide cleavage promoted by complex, CuⅡL and the negative response of CuⅡ/dien complex suggest the merely hydroxy pendant in complex have no ability to attack the peptide bond. The synergic carbonyl activation by metal coordination is essential for the cleavage of peptide bond promoted by CuⅡL.

比较相应铜配合物及二乙烯三胺铜配合物的切割性能，提示羟乙基侧臂单独难以实现相邻肽键的切割，高配位数金属中心对肽键羰基的活化与羟基的协同进攻是该类配合物切割多肽的可能机制。

The main scope of application: Diamond Cutter welding, carbide saw blades, machining with carbide tools of welding, such as diamond tools, drill, tools, planing, milling cutter, reamer, such as welding and cutting tools; standard parts , bolts of hot upsetting, such as high strength bolts, nuts, etc.; hardware tools, hand tools, heat treatment, such as pliers, wrenches, rotary tools, hammers, axes; all kinds of automobile fittings, motorcycle fittings of high-frequency quenching treatment, such as : crankshaft, connecting rod, piston pin, crank pin, sprocket, camshaft, valves, all kinds of rocker arm, rocker shaft; gearbox various gears, spline shaft, axle bronchitis, all kinds of small shafts, high-frequency quenching, such as various fork of the handle; metal parts of the heat treatment, such as a variety of gears, chain wheel, the wheels, vibrating screen, a variety of shaft, spline shaft, and marketing of high-frequency quenching treatment, etc.; machine tool machine tool industry bed rail, such as the quenching treatment.

主要适用范围：金刚石刀头的焊接，硬质合金锯片、机械加工用硬质合金刀具的焊接，如金刚石刀具、钻具、车刀、刨刀、铣刀、铰刀等刃具的焊接；标准件、螺栓的热镦，如高强度螺栓、螺帽等；五金工具、手工工具的热处理，如钳子、扳手、旋具、锤子、斧头；各种汽车配件、摩托车配件的高频淬火处理，如：曲轴、连杆、活塞销、曲柄销、链轮、凸轮轴、气门、各种摇臂、摇臂轴；变速箱内各种齿轮、花键轴、传支半轴、各种小轴、各种拨叉等高频淬火的处理；金属零件的热处理，如各种齿轮、链轮、行车轮、振动筛、各种轴、花键轴、销等的高频淬火处理；机床行业的机床床面导轨的淬火处理等。

The main scope of application: Diamond Cutter welding, carbide saw blades, machining with carbide tools of welding, such as diamond tools, drill, tools, planing, milling cutter, reamer, such as welding and cutting tools; standard parts , bolts of hot upsetting, such as high strength bolts, nuts, etc.; Hardware tools, hand tools, heat treatment, such as pliers, wrenches, rotary tools, hammers, axes; a variety of auto parts, motorcycle accessories, high-frequency quenching treatment, such as : crankshaft, connecting rod, piston pin, crank pin, sprocket, camshaft, valves, all kinds of rocker arm, rocker shaft; gearbox various gears, spline shaft, axle bronchitis, all kinds of small shafts, high-frequency quenching, such as various fork of the handle; metal parts heat treatment, such as a variety of gears, sprocket, all kinds of shaft, spline shaft, and marketing of high-frequency quenching treatment, etc.; machine tool industry machine bed rails of Quenching disposal.

主要适用范围：金刚石刀头的焊接，硬质合金锯片、机械加工用硬质合金刀具的焊接，如金刚石刀具、钻具、车刀、刨刀、铣刀、铰刀等刃具的焊接；标准件、螺栓的热镦，如高强度螺栓、螺帽等；五金工具、手工工具的热处理，如钳子、扳手、旋具、锤子、斧头；各种汽车配件、摩托车配件的高频淬火处理，如：曲轴、连杆、活塞销、曲柄销、链轮、凸轮轴、气门、各种摇臂、摇臂轴；变速箱内各种齿轮、花键轴、传支半轴、各种小轴、各种拨叉等高频淬火的处理；金属零件的热处理，如各种齿轮、链轮、各种轴、花键轴、销等的高频淬火处理；机床行业的机床床面导轨的淬火处理等。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。