金属键

It indicates that the N—O bonds in the singlet dimer adsorption configurations are weaker than any other structures, and this is propitious to the NO direct decomposition. 7. Unlike NO molecules interaction with copper atoms, when two NO molecules interact with the adjacent silver atoms, the non-planar structures are more stable than the planar.

同时，单重态的二聚体与相邻的金属铜和银原子作用时，由于电子从金属原子转移到二聚体上的数量最多，因此在这种吸附构型中，金属原子被离子化的倾向最大，同时使得二聚体中N—O键被削弱的程度也最大，有利于NO的直接分解； 7。

The former is to prepare polymolybdates coordinated' directly by organic ligands using Na2MoO4 and MoO3 precursors; The latter plays emphasis on exploiting a simple and effective routine to synthesize Keggin polytungstates in which the transition metal or Si acts as the heteratom by reaction precursor Na2WO4.We have synthesized a 4,4'-bipyridine bridging dumbbell-like polymolybdates a metatungs...

前者主要是制备有机配体键合的多金属钼酸盐；后者重点是探索出一个简易、有效的合成过渡金属或主族元素硅作杂原子的Keggin多金属钨酸盐的方法，然后通过变换过渡金属或有机配体的种类探讨对产物结构的影响，再对所得化合物的结构和组成通过物理测试手段进行表征，同时研究其在光、电、磁等方面的性质。

Each starch reagent has its own mode of action on mineral surface, such as primary starch mainly by hydrogen bond, cationic starch by the co-action of hydrogen bond and electrostatic force (for minerals with negative charge on its surface), while carboxymethyl starch, hydroxamic acid starch and dialdehyde starch principally by chemical force accompanied with hydrogen bond and electrostatic force in part. Such chemical forces ensure the close adsorption of reagent on diaspore surface and enforces the hydrophilic of mineral surface. Also the branched chain enable the starch to cover the collector adsorbed on mineral surface, so as to depress diaspore furthermore.

不同淀粉药剂在矿物表面表现不同作用，原淀粉主要是氢键的作用，阳离子淀粉是氢键和静电力的共同作用，羧甲基淀粉、羟肟酸淀粉和双醛淀粉离子性药剂与矿物间的作用除了氢键、静电力外，更重要的是与矿物表面金属离子间产生的化学作用，使药剂能牢固地吸附在一水硬铝石矿物表面，增加矿物表面的亲水性，同时，淀粉支链结构的存在，使它能够掩盖吸附的捕收剂，达到抑制一水硬铝石的目的。

We have been interested in design and synthesis of macrocyclic lanthanide complexes which are capable of catalytically hydrolyzing phosphodiester bonds. Because of their high thermodynamics stability, low kinetics lability, high coordination numbers, and charge density, macrocyclic lanthanide complexes will be suitable as artificial nucleases.

合成设计能促进磷酸酯键水解的金属错合物，一直是我们实验室很感兴趣的研究领域，尤其是以镧系金属离子大环配位子错合物这方面的研究，因其具有高度的热力学稳定、动力学稳定、高配位数及电子密度等特性，使得镧系金属大环错合物非常适合作为人造水解酶。

As to thymine, the bond energy of the ion with the most stable tautomer of the free nucleic acid base is the weakest among the three tautomer＇ s complexes, and that of the ion with least stable tautomer of the free nucleic acid base is the strongest .

在互变异构体复合物中，键能是依赖于金属离子成键的位置，而总能量取决于全部的原子和它们之间的相对位置，这可能是造成几种互变异构体复合物键能和总能量变化趋势并不一致的原因。

The SEM-EDS showed that the content of surface elements was changed after treated with glutaraldehyde or albumin indicated that argon plasma only had surface cleaning effect and did not change surface composition and the allylamine deposition thickness was too thin to show the difference in SEM-EDS findings. The XPS results confirmed the argon plasma cleaning effect and revealed that the ratio and the binding energy of surface elements changed with different treatment procedures and were similar to what expected to coat on the titanium surface.

XPS更进一步证实，氩气电浆只有清洁钛金属表面的作用，并不会改变其表面化学组成；其余各组的钛、碳、氮、氧的比例及键结能量随著处理程序而改变，可知表面上有化学组成之改变，且随不同处理程序所得到表面元素之百分比及键结能量，与预期的表面披覆物元素百分比及键结能量相近。

The palladium-catalyzed allylation is a powerful tool for C-C, C-N, and C-O bond formation, which has been widely applied to organic chemistry.

而利用金属钯当作催化剂来进行烯丙基化反应，形成碳-碳键，碳-氮键和碳-氧键，在有机化学中是很广泛的合成方法。

The interaction between MT and AA was expressed by infrared spectra, the functional groups of -SH in MT had lone pair electrons, which could formπ-πwith -C=O in AA. The equilibrium binding experiment and Scatchard analysis showed, at least three kinds of binding sites would exist when MT-imprinted polymer formed, the most adsorption capacities were 3.3896mg/g, 0.9362mg/g, 1.6583mg/g respectively; most terminal thiolate sulfurs in MT were polymerized as binding sites in the process of polymerization, which could observed from TEM, binding capability of other thiolate sulfurs was weak since spatial hindrance existed.

采用红外光谱研究了加入金属硫蛋白后功能单体丙烯酸官能团谱峰的变化，结果表明金属硫蛋白分子中的-SH与丙烯酸中的C=O在氯仿溶液中能形成π-π键，由聚合物的吸附特性和Scatchard分析可以得出，金属硫蛋白印迹聚合物至少存在三种结合位点，其高、中、低的最大吸附量分别为3.3896mg/g、0.9362mg/g、1.6583mg/g；通过透射电镜可以观察到，金属硫蛋白在聚合过程中主要以分子两端的巯基作为结合位点，不同位置的巯基受到的空间位阻不同，导致产生了三种不同的结合位点。

In addition, there are a large number of strong hydrogenbondings(N-H…O,O-H…O) and weak hydrogen bondings in involving the cations,perchlorate counter-ions,PNOS and water molecules, which result in formation 3-D networkstructure.

晶体中Ni与配体希夫碱中的N 、N(吡吡啶醛类过渡金属希夫碱配合物的合成、晶体结构及谱学表征啶)、O原子配位形成变形的八面体构型，由于分子间，存在大量的强氢键和弱氢键，这些氢键的交互作用使得该配合物形成二维网状结构。

The synthesis and properties of metal-carbyne complexes is always a hot topic in the research field of organometallic chemistry since the first synthesis of transition metal complexes with a formal metal-carbon triple bond reported by E.O.

自从1973年E.O.Fischer合成了第一个含有金属碳叁键的金属卡拜化合物以来，金属卡拜化合物的合成和反应性能一直是金属有机化学中的前沿研究领域之一。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。