金属环

In fact, attractive features of cyclometalated PtII systems for biolabelling and bioimaging go beyond their outstanding linear photophysical properties.

事实上，环金属PtII系统的吸引力为biolabelling和bioimaging超越他们的出色线性光物理性质。

Compared to bis(1-phenylisoquinolyl-N,C2') iridium, the iridium complex containing the triarylamine-based picolinic acid displays increased MLCT transition and low oxidation potential and is expected to be a promising red phosphorescent material.

与传统的二(1-苯基异喹啉)(吡啶-2-甲酸)合铱配合物相比，设计的环金属铱配合物具有增强的MLCT电子跃迁吸收和低的氧化电位，是一种有发展潜力的红色磷光材料。

The results show thatthe substitutions containing sulfur atom in the pyrazole ring remarkably affectthe steric and electronic properties of the pyrazole ligands.

因此，我们研究了吡唑环上带上S原子取代基对形成双吡唑烷配体及其与VIB金属羰基配合物的光化学反应的影响。

In the third chapter, the synthesis of5-[(1"S)-1",2"-diacetyl-oxyethyl]-1-phenylpyrazol-3-carboxaldehyde oxime(2) from5-[(1"S)-1",2"-diacetyl-oxyethyl]-1-phenylpyrazol-3-carboxaldehyde(1) and phenyl-hydrazine were introduced firstly. The synthesis of nine dioxapyrrolino[3,4-c]pyrazoles containing chiral pyrazolyl moiety(6a-i) from 2 with N-substituted-phenylmaleimide by nonmetal oxidant IBD-initiated intermolecular 1,3-dipolarcycloaddition was described in detail.

第三章首先以5-[(1′S)-1′，2′-二乙酰氧基乙基]-1-苯基吡唑-3-醛(1)和苯肼为原料，合成了化合物5-(1′S)-1′，2′-二乙酰氧基乙基1-1-苯基吡唑-3-醛-苯腙(2)；再用化合物(2)与N-取代苯基马来酰亚胺反应，利用无金属氧化剂—IBD引发1，3-偶极反应，发生分子间的环加成，合成了9种新型手性吡唑连二氧代吡咯啉并

In thesecond chapter, eleven 1,3,4-oxadizoles bearing chiral pyrazolyl moieties(4a-k) andfive triazolotriazines bearing chiral pyrazolyl moieties(5a-e) were obtained from5-[(1"S)-1",2-diacetyl-oxyethyl]-1-phenylpyrazol-3-carboxaldehyde(1) with arylcar-bohydrazide or (5-aryl-1,2,4-triazin-3-yl)hydrazine through an intramolecular1,3-dipolar cycloaddition in the presence of the non-metal oxidant IBD.

其中第二章介绍了以D-葡萄糖为原料制得的5-[(1′S)-1′，2′-二乙酰氧基乙基]-1-苯基吡唑-3-醛(1)分别与芳基甲酰肼、(5-取代苯基-1，2，4-三嗪-3-基)肼反应，在无金属氧化剂—IBD引发下，发生分子内1，3-偶极环加成，采用&一锅煮&法合成了11种含手性吡唑基的1，3，4-噁二唑类化合物(4a-k)和5种含手性吡唑基的三唑并三嗪类化合物(5a-e)。

Feasibility of tricocyst test with Tetrahymena pyriformis were evaluated by serial chemicals (Cu2+, Cr2O2-4,Cd2+,MMC, CP, Colchicine). There is no significant difference between control and treated groups with negative chemical (Cu2+).

应用致突变阴性、阳性对照(Cu2+， Cr2O2-4， Cd2+，丝裂霉素MMC，环磷酰胺CP，秋水仙素Colchicine)评价四膜虫刺泡发射实验方法的可行性，并应用该方法检测稀土金属离子La3+，Ce3+， Sm3+， Y3+， Gd3+对四膜虫刺泡发射的影响效应。

Objective To determine the scattering and density effects of intrauterine contraceptive ring on pelvic radiotherapeutic dosage distribution.

目的 测量元宫型金属宫腔内节育环对放射治疗引起的密度效应及次级射线引起的散射效应对放射治疗剂量分布的影响。

Our main research work has been focused on the synthesis, characterization of substituted salicylaldehyde Schiff bases and their complexes, which are not reported in articles now. There are twenty-one new compounds in total.

本论文研究了目前未见国内外文献报道的、水杨醛中苯环上含有取代基的水杨醛缩脱氢枞胺Schiff碱及其金属配合物的合成与表征，共计获得了21个新的化合物，从而为后期生物活性的测定及不对称催化提供研究基础和实验样品。

Salicylaldehyde and its derivatives often produce a formation of Schiff base metal chelate. They are special anti-cancer, anti-inflammatory, sterilization matters. At the same time because of therir structure similar to porphyrin ring, they can set of oxygen and simulated biological effect, So many scientist take interest in this field.

水杨醛及其衍生物与某些伯胺类化合物缩合形成的 Schiff 碱及其金属螯合物，具有特殊的抗癌、抗炎、杀菌、抑霉等活性，同时由于其结构类似于卟啉环，有较好的载氧和模拟生物酶的催化作用，已经引起了各国化学家的广泛兴趣。

The cyclopropanation reaction of ethylene with samarium carbenoid was studied by means of the B3LYP hybrid density functional method.

用密度泛函B3LYP方法研究了过渡金属钐类卡宾与乙烯的环丙烷化反应的机理。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。