金属环

The results of catalytic activity show that both Ni-B and Ni-P sample have the same kinetic equation for hydrogenation of 1, 3-cyclopentadiene to cyclopentene and the same TOF. Therefore, it can be suggested that they have the similar active site. The catalytic activity of Ni-B sample is higher than that of Ni-P sample, and it is due to the more active sites of Ni-B sample having.

催化活性测试表明，Ni-B与Ni-P催化环戊二烯加氢反应对环戊二烯具有相同的动力学方程，而且两者具有相似的氢转换频率，表明两者的活性中心本质上是相似的，类金属不同导致的电子转移方向的不同仅仅影响反应的初活性，宏观活性的差别在于两者活性中心数量的不同。

The azacrown ether complexes are formed by coordination of azacrown ether and metal ion, the azacrown ether is 1,12-diaza-3,4,9,10-dibenzo-5,8-diazacyclopentadecane-N,N'-diacetic acid, the metal ion can be any one of Cu2 , Ni2 , Co2 or Zn2 and so on.

所述氮杂冠醚配合物为氮杂冠醚与金属离子配位而成，氮杂冠醚为1，12-二氮杂-3，4，9，10-二苯并-5，8-二氮杂环十五烷-N，N'-二乙酸，所述金属离子可以为Cu 2 、Ni 2 、Co 2 或Zn 2 等中任一种。

The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.

第二章 研究了二碘化钐、金属钐促进的有机反应：1、二碘化钐促进下α，β-炔基酮的偶联环化反应，提供了一种制备多取代环戊二烯的新方法；2、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮的Michael加成反应，为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法；3、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮和醛、酮的Michael—aldol串联反应，提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法；4、烯丙基溴化钐与α，β-炔基酮的高度区域选择性的1，2-亲核加成反应；5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。

In recognition of its important value in ion-selective electrode study, this thesis aims to develop new types of carriers. Metallorganic compounds, Metal-Schiff base complexes, heterocyclic nitrogen compounds, derivatives of calixarene,Sudan Ⅰ and dialkyldithio phosphate have been tested as carriers for all kinds of ions.

鉴于新型载体的开发在离子电极研究中所具有的重要价值，本文主要开展了这方面的一些研究工作，重点考察了金属有机化合物、金属希夫碱配合物、含氮杂环化合物、杯芳烃、苏丹Ⅰ以及双硫代磷酸脂衍生物等各类物质用作离子载体的可能性。

The present invention provides a multinuclear half metallocene compound in which two or more of transition metals of groups 3 to 10 on periodic table are connected through bridge ligand simultaneously containing Pi-ligand cycloalkandienyl group and Alpha-ligand functional group and its preparation, and a process for preparing styrene polymer using the compound as a catalyst.

本发明提供了一种其中的两个或更多元素周期表第3-10族过渡金属通过同时包含π-配体环烷基二烯基团和α-配体功能基团的桥配体连接的多核半金属茂络合化合物及其制备方法，及使用本化合物为催化剂的苯乙烯聚合体的制备工艺。

Porphyrins is a general term of the homologue and derivative of porphine with substituting groups at the outside ring, becoming metalloporphyrins promptly after two protons on its nitrogen are replaced by the metal ion.

卟啉是卟吩环外带有取代基的同系物和衍生物的总称，当其氮上两个质子被金属取代后即成金属卟啉。

The work in this paper was mainly focused on the study of cyclization of dianions mediated by transition metals and during the course, several multi-component cyclization reactions were also observed by way of parenthesis.

本论文主要研究了过渡金属中介的双负离子成环反应，研究过程中也发现了一些多组份成环反应。

The two-ring monopole antenna can improve the wind resistance capability while maintaining the basic characteristics of the antenna.

此外，由于此超宽带双环单极天线的环宽很窄，可以用软金属做成可折叠的便携式天线，具有较高的实用价值。

Secondly, the syntheses of functionalized macrocyclic polyamine complexes containing nucleobases, PNA monomer, imidazolium side, crown ether, ferrocenyl side and their interaction with DNA were studies, respectively.

在功能化大环多胺方面，我们合成了含有碱基、PNA单体、咪唑鎓盐、冠醚、二茂铁等功能化基团的大环多胺衍生物及金属配合物，并研究了其与DNA的相互作用。

The reaction of sodium alkylcycloperitadienide with metal chlorides gave derivatives of bisdichlorides of titanium, zirconium and hafnium where alkyls were n-propyl and n-butyl.

本文报导烷基环戊二烯基钠与金属氯化物反应合成钛、锆和铪的双金属二氯化物以及通过卤素交换制备双钛的二氟化物的方法。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。