金属氢

As well as activity was exhibited. Theaddition of cinchonidine led to a remarkable increase in the reaction rate, as confirmed bythe IR study that the modifier activates the carbonyl groups of the reactant through itsquinuclidine nitrogen. On the contrary,〓 exerted a strong inhibition effect on theenantioselective hydrogenation. Chapter 3 Finely dispersed polyvinylpyrrolidone-stabilized iridium andbimetallic clusters were prepared by the alcohol-water reduction method.

第三章 采用醇水还原的方法制备了聚乙烯基吡咯烷酮稳定的铱纳米簇及双金属纳米簇，对丙酮酸甲酯的催化氢化表明，在铱金属簇催化体系中，辛可尼定不仅诱导了一定的对映选择性，同时对反应活性有明显的促进作用，平均反应速率可提高2-6倍。

The mineralization of gold and silver is zoned and closely related to silicification of carbonate and clastic rocks, so siliceous ore dominates in the deposit.

矿化温度主要在300～170 C之间，成矿流体的主要成分为K~-、Na~-、Ca~(2+)、Mg~(2+)、Cl~。金属配合物的分配计算显示，金在成矿热液中主要以疏氢配合物迁移，而银、铁、铅、锌则以氯配合物为主，铁、铅、锌在成矿后期的中性-弱碱性环境下可转变为羟基和硫氢配合物。

There is an allotropic change temperature (1155K) for pure Ti and it is a hydrogen-absorbing metal for different solubility in a-phase titanium and 3-phase titanium. The hydrogen atom dissolves in lattice and occupies tetrahedron interstitial position, and then forms TiH2 sublattice of face-centered cubic.

钛是－种具有同素异型转变点T(1155K)的吸氢金属，氢在α钛和β钛中有不同的溶解度，在T以下易形成具有面心立方晶格结构的TiH2，氢原子溶解在晶格中，占据四面体间隙位。

Its very difficult to support metal on the surface of crude CNTs. Compared with Pt/C,Pt/CNTs have higher performances in term of efficiency and selectivity. It can be concluded that the interaction between metal and CNTs favors both the high activity and selectivity in cinnamaldehyde hydrogenation.

Pt/CNTs在选择性肉桂醛的选择性加氢中表现出很高的加氢活性和选择性，这是由于纳米碳管外表面独特的结构以及纳米碳管和金属之间相互作用的结果。

The results of catalytic activity show that both Ni-B and Ni-P sample have the same kinetic equation for hydrogenation of 1, 3-cyclopentadiene to cyclopentene and the same TOF. Therefore, it can be suggested that they have the similar active site. The catalytic activity of Ni-B sample is higher than that of Ni-P sample, and it is due to the more active sites of Ni-B sample having.

催化活性测试表明，Ni-B与Ni-P催化环戊二烯加氢反应对环戊二烯具有相同的动力学方程，而且两者具有相似的氢转换频率，表明两者的活性中心本质上是相似的，类金属不同导致的电子转移方向的不同仅仅影响反应的初活性，宏观活性的差别在于两者活性中心数量的不同。

LaNi〓 catalyst was metallurgically combined with V、Nb and TiFe by ball milling, and then V-LaNi〓、Nb-LaNi〓 and TiFe-LaNi〓 nano-compound materials formed.

利用机械球磨方法使LaNi〓催化剂有机地与室温难活化储氢金属V、Nb、TiFe合金结合，形成V-LaNi〓、Nb-LaNi〓、TiFe-LaNi〓纳米复合储氢材料。

Work 工作:(1) feasible process development for high-pure tetraalkyphosphonium salt as catalysts for polymerizations, potential sale 2-4 million us$;(2) simple and feasible preparation process for phosphonium salt as ionic liquids, biocides and phase transfer catalysts;(3) new and industrially feasible processes for highly sterically hindered alkylphosphines as catalyst ligands, these include tricyclohexyl-phosphine, phosphorinanes and dsmphos2,3- bis(9-phosphabicyclononylbutane;(4) sterically hindered dialkylphosphinic acid as new generation of co/ni extractant;(5) alkylphosphonium wittig reagents and the wittig reactions with them;(6) exploration of the application of borane chemistry in the synthesis of highly sterocally hindered organophosphines;(7) customer preparation of samples of a variety of organophosphorus compounds for customers all over the world.

用作高分子聚合反应催化剂的高纯度四烷基瞵盐的实用生产流程。产品销售前景 2-4 百万美元；(2)用作离子化液体，杀菌剂和相转移催化剂的烷基瞵盐的简单实用合成方法；(3)高位阻烷基磷化氢催化剂配体的工业实用合成路线的研究，这包括，三环己烷基磷， phosphorinanes 和 dsmphos 2，3-bis(9-phosphabicyclononylbutane ；(4)高位阻二烷基膦酸金属萃取剂的工业实用合成路线的研究；(5)烷基膦 wittig 反应试剂的研究；(6)硼化学在高位阻烷基磷化氢合成中的应用；(7)为世界各地提供顾客合成服务。

The oil shale ash is disintegrated into fine powder less than 150 eye to be calcined at a certain temperature, then sulfuric acid solution is added for performing acid dipping, after solid-liquid separation and solid residue removal, aluminum sulfate solution is obtained and is then filtered after sodium hydroxide solution is added in, further metallic ions as Ca2 , Mg2 , Fe3 , Fe2 and the like are filtered from the solution, thereby sodium aluminate solution is obtained, gas of carbon dioxide is communicated into the sodium aluminate solution to obtain aluminum hydroxide sediment, and after drying and calcining aluminum hydroxide powder is obtained.

将油页岩灰渣粉碎至＜150目的细粉，在一定温度下煅烧，加入硫酸溶液进行酸浸，固液分离，去除固体残渣，得硫酸铝滤液，加氢氧化钠溶液后过滤，滤除溶液中的Ca 2 、Mg 2 、Fe 3 、Fe 2 等金属离子，得偏铝酸钠溶液，向偏铝酸钠溶液通入二氧化碳气体，得到氢氧化铝沉淀，经烘干、煅烧得到氢氧化铝粉末。

The combination of these hydrides with some transition metal complexes exhibits high catalytic activity for the hydrogenation of olefins.

它们具有比一般市售碱金属氢化物高得多的反应活性，并能与过渡金属配合物组成高活性烯烃加氢催化。

It took Cockcroft and Walton five years to build a machine that worked. Finally, in April 1932, they had a machine that produced a steady stream of hydrogen nuclei with an energy of about half a million volts. They were carefully measuring the quality of the stream, in no hurry to begin doing nuclear experiments. On the morning of April 13, Rutherford came into their room, saw what they were doing, and lost his temper. He told them to stop wasting their time and do some science. The next day, Cockcroft was occupied with other business. Walton was alone in the laboratory, ready to do the first experiment, using his hydrogen nuclei to bombard a target made of the light metal lithium. The result was spectacular. The lithium nuclei were split in two and fell apart into pairs of helium nuclei.

用了五年时间，考克饶夫和华尔顿建造出了第一台能运行的加速器，最终，在1932年，他们制造出了能够提供稳定氢粒子流的加速器，粒子能量大约为50万伏特，他们并没有急着做核试验，而是精心测量了粒子流的性质，4月13日清晨，卢瑟福来到他们的房间，看到他们还在测量，大发雷霆，告诉他们停止浪费时间，开始科学研究，第二天，考克饶夫就被安排了其他事情，只剩华尔顿一个人在实验室里，准备做第一次实验，用他的氢粒子流轰击用轻质金属锂作的标靶，结果极为壮观，锂原子被分裂成两半形成一对氦原子，氦原子释放出的能量比氢原子注入的多达三十倍！

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。