金属化

The calculational results are in good agreement with the X-ray data and show that different substitute group results in different charge distribution, the exocyclic sulfur atom has the biggest negative charge value and this site is the most likely site of protonation and methylation as well as the potential coordination site with metallic ions.

计算结果与X-射线衍射数据相符合，并显示虽然不同的取代基导致了不同的电荷分布，但四唑环外的硫原子总是具有最大的负电荷分布，从而使其成为最有可能的质子化、甲基化及与金属离子进行反应的点位。

Four new salicylaldehyde derivatives with a glucose or mannose moiety were synthesized with 2-tert-butylphenol or 4-tert-butylphenol as the starting material, followed by the formylation, chloromethylation, nucleophilic substitution reaction with the desired carbohydrate. The salicylaldehyde derivatives condensed with ethylenediamine to give the Schiff bases, which coordinated with Mn to afford four novel sugar-based Salen Mn complexes.

首先，分别以2-叔丁基苯酚和4-叔丁基苯酚为起始原料，经过甲酰化反应、氯甲基化反应、和糖类衍生物的亲核取代反应制得了四种新型并入葡萄糖基或甘露糖基的水杨醛衍生物，将它们与乙二胺缩合生成希夫碱配体，得到的配体与过渡金属Mn~(3+)配位制备出四种新型含糖基的Salen Mn配合物。

The investigation and comparison of chlorination activity of chloroperoxidase from Caldariomyces fumago in metal ion solutions to those in pure buffer indicated that CPO could be effectively activated by some alkaline-earth metals and transition metals.

基于氯过氧化物酶的卤化活性分析，发现某些碱土金属（Ca2+， Mg2+）和过渡金属（Co2+， Ni2+）对CPO具有明显的激活及稳定化作用。

LISTEN SH Super high temperature grease is made from special organic gelatinizer which is added of many anti-oxidation and anti-corrosive additive and super fine soft metal powder.

雷萨SH超级高温润滑脂采用特殊有机稠化剂，稠化高档合成油，并添加抗氧、防腐等多种复合添加剂以及超细软金属粉末制成。

Hybrid mesoporous molecular sieve materials with hexagonal mesoporous structure and covalent bonded polyoxometalates were synthesized based on tetraethoxysilane anti lacunary polyoxometalate, SiW11, via sol-gel method in the presence of triblock copolymers P123 as the structure-directing agent. The influences of molar ratio of inorganic precursors and aging temperature on the structure and the loadings of SiW11 in the hybrid materials were investigated. Some reaction details in the synthesis were revealed.

用嵌段共聚物P123为模板剂，正硅酸乙酯和缺位结构的多金属氧酸盐SiW11为无机前驱体，由溶胶－凝胶法合成了具有六方结构和SiW11共价键联的介孔分子筛杂化材料SiW11/SBA-15，着重考察了无机前驱的配比和老化温度对杂化材料结构及SiW11负载量的影响。

The result shows that modification can make the β-Si phase thin when the joining amount is 0.3wt%, making the best modification result. Alloying elements Mn and Ni are always used to neutralize iron"s harm in aluminum alloys. They can form many kinds of complicated metallically compounds with Fe and Al, and eliminate needle-like iron-rich phases to reduce iron"s harm in Al-Fe alloy. Copper makes the alloy microstructure thick and electromagnetic stirring obviously makes the alloy microstructure thin, round the second phase, when the stirring voltage is 200V, making the best result; Reheat makes liquid phases emerge in the alloy, when the warming temperature is 650?

研究结果表明：红磷可以明显细化合金中的初晶硅，当加入量为0.3wt%时，取得最佳变质效果；锰、镍合金中加入后，通过形成多种复杂金属间化合物，细化针片状富铁相，减小铁对铝硅合金性能的危害；铜使合金微观组织发生粗化；电磁搅拌明显细化合金组织，使第二相圆整化，搅拌电压为200V时，取得最佳细化效果；二次加热使合金组织中产生部分液相，在650？

Based on the studies of moderate temperature isomerization catalysts carried out by domestic and foreign researchers, the paper systematically discussed the influence of a variety of factors in process of commercial preparation on the performance of catalyst which applied Pd as its metal component and HM as its acid carrier. The paper also explored the deactivated reasons of catalyst and its regenerating measure. Preparation of mordenite and scaled up production of catalyst, stability of catalyst was demonstrated in a 100kt/a commercial plant. The findings provide important basis for preparing Pd isomerization catalyst and industrial application.

本文在国内外学者对中温异构化催化剂及工艺研究的基础上，以钯作为金属组份，氢型丝光沸石作为酸性载体，系统研究了工业制备过程中各种因素对催化剂性能的影响，以及催化剂失活的原因及再生方法，进行了丝光沸石及催化剂的放大生产，并在10万吨/年工业装置上考察了催化剂的稳定性，为制备载Pd异构化催化剂及工业应用提供了重要依据。

Niobic acid as a solid catalyst can be directly applied in the hydrolysis, esterification, condensation and alkylation reaction etc.

铌酸可直接作为固体催化剂，应用于水解、酯化、缩合、烷基化等反应中；铌酸也作为载体负载金属，应用于F-T合成、氧化反应和加氢等反应中；含铌化合物也可作为负载型催化剂，负载到不同类型的载体上；含铌化合物也作为助剂或光催化剂，广泛地应用于催化多种化学反应。

The floatation separation behaviuor of Pd (superscript 2+) by KBr-cetyl pyridinium bromide system in the presence of NaNO3 and the conditions for the separation of Pd (superscript 2+) from other metal ions were studied.

研究了硝酸钠存在下，溴化十六烷基吡啶－溴化钾体系浮选分离钯的行为及与一些金属离子分离的条件。

After that , simulated the Die Casting filling process of liquid metal .First use the spical soft Pro/E to construct the model of Die Casting part; Input it to another soft I-deas to form mesh and put the mesh document to the special soft ProCAST.

接着模拟了金属液在模具型腔的充填过程：运用Pro/E软件对泵盖进行三维实体造型，然后把图形导入软件I-deas中进行网格化处理，并将网格化后的模型输入到ProCAST软件中进行了关于压铸工艺参数的多组正交试验的流场，温度场的偶合模拟，进而从多组试验参数中找出最优的压铸工艺参数。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。