金属化

Fourthly, based onour experiments and the literatures', the necessities of endohedralmetallofullerenes' formation are the existence of well graphitized of carbonand metal acetylide.

四在实验和文献报导的基础上，提出原料中完好石墨化的碳和电石型金属碳化物的存在是形成Fullerene笼内金属包合物的必要条件。

Synthesis of the phenylhydrazone, oxime and semicarbazonederivatives of calix[4]arenesThe reaction of p-formylcalix[4]arenes with phenyl hydrazine,hydroxylamine hydrochloride or semicarbazide hydrochloride afforded thephenylhydrazone, oxime or semicarbazone derivatives of calix[4]arenes,respectively.

酯型杯[4]冠醚的全醚化及性能研究利用氢化钠作为碱，对酯型杯[4]冠醚剩余酚羟基进行烷基化，合成中性杯芳烃酯型冠醚，初步研究了其对金属离子、有机阳离子和中性分子的识别情况，发现其对这些底物缺乏有效作用能力。

The analyses of electronic structures shows that the catalytic reactivities for H2 adsorption of the different surfaces are dependent on the numbers of s orbital bonding electrons around Fermi level for the uppermost layer metal atoms which interact directly with H2. It is easy to form vacancy for hydrogen atoms next to iron atom, which indicates that hydrogen atom cannot be escaped, but it is difficult to from vacancy for hydrogen atoms next to magnesium atom, which indicates that hydrogen atom can be escaped. Hence it is thought that the change of dehydrogenating properties of MgH2 with or without a little iron addition attributes to the weakened bonding between magnesium and hydrogen.

分析电子结构发现：空位缺陷有助H2吸附于Mg表面，与Mg(0001)表面最上层与H2直接产生吸附作用的金属原子在费米能级附近s轨道的成键电子数密切相关；在Fe合金化MgH2体系中，与合金化元素Fe近邻的H原子形成空位的难度增加，H原子较难释放；与Mg近邻的H原子形成空位的难度减少，H原子容易释放；Fe合金化导致Mg-H之间存在较弱的成键作用，因此，MgH2体系的解氢性能得到提高。

Using hydrotreated gas oil as solvent, under the conditions of a reaction temperature of 400 C, a hydrogen partial pressure of 10 MPa and a reaction time of 1 h, a portion of coke deposits could be removed yet without the function of hydrogenating coke.

采用溶剂萃取法除去工业失活催化剂上沉积的焦炭和金属的研究结果表明，用四氢呋喃、吡啶和喹啉这3种含杂原子的有机强溶剂常温萃取催化剂，其去除焦炭能力很弱，而且会因这些溶剂的强吸附作用污染催化剂；盐酸洗涤能有效去除催化剂表面的钙、铁沉积层，但不能去除焦炭；低芳香性的加氢瓦斯油在400 C、H2压力为10MPa、反应1h的条件下可部分去除催化剂上的焦炭，但不具备强的氢化焦炭作用；1，2，3，4-四氢化萘因具有供给原子氢的能力，可以有效地氢化和去除催化剂上的焦炭。

The only difference was that the total content of Cr in passivated film on electrodeposited zinc alloys was higher.

它们的区别在于：合金镀层钝化膜中总铬量较高，膜层完整、致密，镀层/钝化膜界面存在铁系金属的富集层，这是锌基合金镀层钝化膜具有高耐蚀性的主要原因。

80 Mm special alloy steel wire for metal card clothing were studied,and their technique parameters were respectively found out.

研究了φ2.15mmSWRH72B、金属针布专用φ3.50mm合金钢Ⅰ和φ3.80mm合金钢Ⅱ三种钢丝的球化退火工艺，分别找出了其最佳的球化退火工艺参数；同时分析了球化退火工艺参数对最终碳化物球粒度的影响。

For a deep understanding of electron screening effects, the DT reaction has been studied in a series of deuterated metal-, insulator- and semiconductor targets using the 100 kV accelerator of the Dynamitron-Tandem-Laboratorium at the Ruhr-University-Bochum.

为深入了解电子屏蔽效应的机制，在鲁尔大学DTL实验室100kV加速器上采用一系列氘化金属靶、氘化绝缘体靶和氘化半导体靶进行了DT反应的研究。

The disordered solid solution Al was obtained for Fe_(25)Al_(65)Ni_(10) mixture powder. The mechanical alloying of Fe_(0.25)Al_(0.75-x)Ni_x(x=0.05,0.175,0.25) mixture powders result in intermetallic compounds. The results of mechanical alloyed_(1-x)Ni_x (x=0.4,0.6) and (FeAl_3)_(1-x)Ni_x(x=0.1,0.3) mixture powders indicate that the ratio of iron and aluminum determines the formation of intermetallic compounds. The FeNi intermetallic compound, cerium oxide and one unidentified phase were obtained by mechanical alloying FeCeNi_3 and Ce_2 mixture powders.

对于合金化过程中的结构演变采用X射线衍射仪、DTA或DSC热分析仪、SEM进行分析，对Al-Fe-Ni和Ce-Fe-Ni两个三元系的机械合金化过程的研究表明：对于Al-Fe-Ni三元系来说，成分为Fe_(25)Al_(65)Ni_(10)的混合粉末经机械合金化后可生成非晶与纳米晶的混合物；球磨成分为Fe_(0.25)Al_(0.75-x)Ni_x(x=0.05，0.175，0.25)混合粉末，可形成Al_3Ni_2，AlFe_3，AlFe_(0.23)Ni_(0.77)，球磨成分为_(1-x)Ni_x(x=0.4，0.6)和(FeAl_3)_(1-x)Ni_x(x=0.1，0.3)混合粉末，Fe与Al比例相同时球磨所形成的金属间化合物也相同。

Our group first reported a novel dialkylation reaction of alkyl zinc iodides with aromatic aldehydes and an olefination reaction of benzyl zinc bromides with aromatic aldehydes respectively.

我们实验室分别首次报道了在过渡金属络合物催化下带官能团有机卤化锌试剂与芳香醛的双烷化反应和烯基化反应。

Photoelectric materials with organic-inorganic hybrid perovskite structure are novel molecular-scale composites through organic and inorganic compounds self-assembling.The layered perovskite framework comprised of metal halide octahedra provides a distinct set of advantages including good electrical mobility, mechanical and thermal stability,while organic component offers a number of useful properties including structural diversity and ease of processing et al.

有机/无机杂化钙钛矿结构光电功能材料是通过有机分子与无机分子的自组装形成的一类新型的分子复合晶体材料，无机金属卤化物构成的钙钛矿结构提供了有序的载流子传输网络并提高杂化材料的机械稳定性和热稳定性，而有机组份的功能性和易加工性使杂化材料具有光电功能和大面积成膜性能。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。