金属化

This thesis is mainly about the research on the synthesis, structures and reactivity of di-or tri-metal bridging carbene and bridging carbyne complexes

过渡金属桥卡宾和桥卡拜络合物本身即为简单的金属原子簇化合物或是合成金属原子簇化合物的重要前体，在有机合成和烯炔烃的聚合和异构化等催化反应中有广阔的应用前景以及在某些过渡金属参与的反应的机理研究中具有重要的研究价值。

The invention provides the flux-cored wire for welding the duplex stainless steel, 17 percent to 24 percent flux-cored powder is filled into stainless steel belt. The invention is characterized in that the mass percent of the components of the flux-cored is as follows: 35 percent to 40 percent of chromium powder, 11 percent to 15 percent of molybdenum powder, 2 percent to 4 percent of nickel powder, 3 percent to 5 percent of manganese powder, 1 percent to 5 percent of magnesia chrome, 1 percent to 3 percent of ferrosilicon, 4 percent to 9 percent of rock crystal, 2 percent to 6 percent of feldspar, 21 percent to 30 percent of rutile, 0.5 percent to 4 percent of Al2O3, 0 percent to 5 percent of zircon, 0.5 percent to 3 percent of Bi2O3, and 0.5 percent to 3 percent of manganese nitride.

一种用于焊接双相不锈钢的药芯焊丝，将药芯粉末以17～24％填充在不锈钢带内，其特征在于，所述的药芯质量百分比成分如下：35～40％的金属铬粉，11～15％的金属钼粉，2～4％的金属镍粉，3～5％的金属锰粉，1～5％的铝镁合金，1～3％的硅铁，4～9％的石英，2～6％的长石，21～30％的金红石，0.5～4％的Al 2 O 3 ，0～5％的锆英石，0.5～3％的Bi 2 O 3 ，0.5～3％的氮化锰。

According to geological characteristics of mineral area,geological conditions of mineralization,geochemical characteristics,material sources of mineralization,mineralization patterns,as well as physical and chemical conditions of mineralization,it summarize the mineralization pattern and genesis of ore deposit of Xianghualing mining areas,considering that mineralization materials in this deposit mainly come from magma,genesis patterns of deposit include high-temperature gas-liquid Nb、Ta deposit related to albitization laying in or on the edge of granite rock bodies,median-high temperature Skarn Sn,Be deposit related to skarnized laying at the inner contact-belt of granite and carbonate rock bodies;median-high temperature cassiterite -sulphide mineral deposit related to skamized laying at outer contact-belt of granite and carbonate rock bodies and median-low temperature hydrothermal liquid Pb-Zn-Ag deposit related to silicification,fluorite, propylitization laying in wall rocks;Series of generalized magma- hydrothermal liquid type Sn-polymatellitic related to magmatic activity in Yanshan period as a whole.

通过对矿区地质特征、成矿地质条件、地球化学特征、成矿物质来源、成矿作用、矿化型式以及成矿物理化学条件的分析，总结了香花岭矿区的矿床成因以及成矿模式，认为香花岭锡多金属矿成矿物质主要来源于岩浆，矿床成因类型包括花岗岩体内及其边部产出的与钠长岩化有关的高温气液型Nb、Ta矿床、花岗岩体与碳酸盐岩内接触带产出的与矽卡岩化有关的中高温矽卡岩型Sn、Be矿床、花岗岩体与碳酸盐岩外接触带产出的与矽卡岩化有关的中高温锡石硫化物矿床以及围岩中产出的与硅化、萤石化、青磐岩化有关的中低温热液型铅锌银矿床，整体构成与燕山期岩浆活动有关的广义岩浆热液型锡多金属成矿系列

The results showed that the TiN andN films are polycrystalline phase. The properties and structure of TiN films are mainly determined by the N2 mass flow rate, and as the N2 mass flow rate increases, the structure of the TiN films transforms to f.c.c. type leading to better the properties of films. The presence of negative bias voltage can optimize the grain of TiN films, lower the defect proportion and denser the films, which improves the hardness of films. The TiN films conform to the free carrier absorption mechanism and there are many of free electrons with lower N content in TiN films. With the increase of N content, the quantity of free electrons and reflectivity of films decrease, and the plasma frequence shifts to the lower energy, which leads to the regular change of colors of films from silver, yellowy, golden to yellow-red, meanwhile the lightness of films decreases. The goldenN film consists of TiN and ZrN phase, but belongs to a sigle f.c.c. structure with (111) preferred orientation. The Zr-doping dosen't change the position of the valance band, conduction band and forbidden band ofN film, but leads to the presence of new energy levels, which is the reason thatN film remains golden. The transparent hard films with good corrosion resistance and high hardness have been prepared and the further reseachs showed that the grain size of those films is by far smaller than the wave length and the width of forbidden band of those films is very broad, is the reasons that those films are transparent.

研究表明：氮化钛和N 薄膜为多晶态，氮流量决定了氮化钛薄膜的结构和性能，增加氮流量能使氮化钛薄膜的结构向面心立方结构转变，从而得到性能良好的氮化钛薄膜；施加负偏压能优化氮化钛晶粒和减少薄膜中的缺陷，使膜层变得更致密，从而提高薄膜硬度；氮化钛主要遵循自由载流子光吸收，氮含量较少时薄膜中的自由电子数目较多，随着氮含量的增加，薄膜中的自由电子数目不断减少，反射率逐渐降低，等离子体频率向低能端移动，从而使薄膜颜色出现规律变化，由金属色银白色到淡黄、金黄再到红黄，并且薄膜亮度呈下降趋势；金黄色的N 薄膜中存在TiN 和ZrN 的分离相，但其为单一的面心立方结构并具有(111)面择优取向；相对于TiN 薄膜，Zr 掺杂后，并没有使薄膜的导带、价带和禁带发生变化，只是在TiN 禁带内增加了新能级，这也正是掺杂Zr 后，薄膜仍

Based on reviewing of functionalization of saturated carbon by catalytic oxidation with metalloporphyrins and metal phthalocyanines as a mimic of the enzyme cytochrome P-450, two reaction systems of which one was the preparation of 4, 4'-dinitrostilbene-2, 2'-disulfonic acid from 4-nitrotoluene2-sulfonic acid and the other was the preparation of 4, 4'-bis (dimethylamino -diphenyl) phenylmethanol from 4, 4'-bis (dimethylamino-diphenyl) phenyl methane , were specifically studied as carfunctionalization and oxyfunctionalization of saturated carbon.

本文在全面综述金属卟啉和金属酞菁类模拟细胞色素P-450酶催化剂催化氧化饱和碳原子功能化的基础上，选择由4-硝基甲苯-2-磺酸制取4，4'-二硝基二苯乙烯-2，2'-二磺酸和由4，4'-二苯基甲烷制取4，4'-二苯基甲醇两个反应体系进行饱和碳原子碳功能化和氧功能化的具体研究。

By the B3LYP calculation of DFT, the difference in changes of energy and charge of ion probe C〓 and C〓 interacting with hBN and graphite respectively and the difference in frontier orbital energy level reveal difference in electroaffinity of hBN and graphite. It could be indicated that hBN only shows weak electropositivity, and will not be able to accept electrons from metal.

根据密度泛函B3LYP方法的计算结果，从六方氮化硼与石墨的前线轨道能级和两者对离子探针的作用能及C〓和C〓的电荷变化不同所表现出的在电亲和性上的差异，揭示了金属难以插入六方氮化硼层间的原因是六方氮化硼仅显弱的电正性，不能接受金属转移来的电子。

Ceramic bearings can produce oxidation-ho, silicon carbide, silicon nitride and so on, diameter from 3mm-50mm, precision Machinable P0, P6, P5 level; its performance characteristics are: high temperature, oil-free self-lubricating, acid, alkali and salt corrosion , wear resistance, low noise, insulating diamagnetic, since high-speed operation; metal nano-ceramic bearing its production process for a new generation of high content of nano-particles in the heat and pressure infiltration of metal surface is activated to fill the cracks and pits the metal so that 3-5 micron metal surface is more smooth solid surface, greatly reduce the friction, improve Chennai base metals, and greatly increased the life span of bearings, and its characteristics are: long life (as an ordinary stainless steel bearings 2 -- 10-fold), low noise (as an ordinary stainless steel bearings, 70%), wear-resisting, acid, alkali, salt corrosion, high temperature, load large; ceramic bearing and metal nano-ceramic bearing design and development to meet the needs of the market for high-speed, low - noise, high load, the demand for corrosion-resistant; Machinery Production Department to produce aircraft rod end joint bearing, linear guide bearings, the fuel tank of earrings, plastic bearing, non-standard side bearing components, glass door hardware, such as high-precision control products; and provide CNC machining.

陶瓷轴承可生产氧化镐、碳化硅、氮化硅等，内径从3mm-50mm，精度可加工P0、P6、P5级；其性能特点为：耐高温、无油自润滑、耐酸、碱、盐腐蚀、耐磨、低噪音、绝缘抗磁、起高速运转；金属纳米陶瓷轴承其生产工艺为新一代的高含量纳米级微粒在热和压力的作用下被激活渗入金属表面，填补金属缝隙和凹坑，使金属表面3-5微米表面更光滑坚固，大大降低其摩擦力，提高金属的奈酸碱性，并大大提高了轴承的寿命，其特性为：长寿命（为普通不锈钢轴承的2-10倍）、低噪音（为普通不锈钢轴承的70%）、耐磨、耐酸、碱、盐腐蚀、耐高温、负载大；陶瓷轴承与金属纳米陶瓷轴承的设计开发以满足市场对高转速、低噪音、高负载、耐腐蚀的需求；机械生产部以生产机杆端关节轴承、直线导轨轴承、油缸耳环、塑料轴承、非标端轴承零部件、玻璃门控五金等高精度产品；并对外提供数控加工。

The results show that WO_3 can be nitrided in the mixture gas of hydrogen and nitrogen, and ...

结果表明，WO3可以在氢氮混合气中被还原氮化；氮化反应分两段进行；在氢氮体积比(4～5)∶1，反应温度650℃的条件下，WO3可以被还原为产物W2N；在不同氢氮比的混合气中氮化，WO3会生成不同的中间产物WO2和WOXNY，中间产物WOXNY进一步氮化生成W2N要比WO2容易；助剂Ni的加入使氮化反应温度降低了100℃；载体γ-Al2O3的加入使金属氧化物的氮化过程变为一步氮化还原反应。

The thesis are divided into two parts. In the first part, we used 2,4,6-trichloro-1,3,5-triazine as the precursor to react with sodium which have been achieved by decomposing sodium hydrate at 623 K. At a low reaction temperature of 623 K, carbon nitride nanosphere、porous carbon nitride material and byproduct sodium chloride, would be produced.

本研究将分成两部份，第一部分是在低温下(623 K)将氢化钠粉末热裂解，生成表面积较大的熔融态金属钠，使气态的氰尿醯氯通入与熔融态金属钠在623 K反应，生成奈米氮化碳球、奈米孔洞性氮化碳材料及副产物氯化钠。

A process for making an electronic device which comprises applying a nonaqueous plate-resistant ink by ink jet printing to selected areas of a dielectric substrate, optionally laminated with an electrically conductive metal, exposing the plate resistant ink to actinic and/or particle beam radiation to effect polymerisation, adding one or more metal layers by electrolytic or electroless deposition, the upper layer of which is an etchresistant metal, removing the polymerised plate-resistant ink with alkali and finally removing the electrically conductive metal which are optionally directly laminated to the dielectric substrate and not protected by an upper layer of etch-resistant metal by chemical etching wherein the plate-resistant ink is substantially solvent-free and comprises: A 30 to 90 parts acrylate functional monomers free from acid groups comprising mono- or higher functionality wherein 5 to 95% by weight are mono-functional monomers; B 1 to 30 parts acrylate functional monomer containing one or more acid groups; C 0 to 20 parts polymer or prepolymer; D 0 to 20 parts radical initiator; E 0 to 5 parts colorant; F 0 to 5 parts surfactant; and where the ink has a viscosity of not greater than 30 cPs at 40 DEG C and all parts are by weight.

一种制备电子装置的方法，所述方法包括以下步骤：通过喷墨印刷在任选层压了一种或多种导电金属的介电底材的选定区域涂覆非水的阻沉积油墨，将所述阻沉积油墨暴露在光化辐射和/或微粒束辐射中以完成聚合，通过电解沉积或无电沉积增加一层或多层金属层，其中最上层的金属层为一种或多种阻蚀刻金属，用碱除去聚合的阻沉积油墨，最后通过化学蚀刻将任选直接层压在所述介电底材上并且不被一种或多种阻蚀刻金属的上层保护的导电金属除去，其中所述阻沉积油墨基本不含溶剂，并且包含以下组分：A30-90份不含酸基团的丙烯酸酯功能性单体，所述单体包括单官能或多官能单体，其中5-95％重量为单官能单体；B1-30份包含一个或多个酸基团的丙烯酸酯功能性单体；C0-20份聚合物或预聚物；D0-20份自由基引发剂；E0-5份着色剂；和F0-5份表面活性剂；其中所述油墨的粘度在40℃下不高于30cPs，并且所有的份数以重量计。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。