金属

They are:In the third chapter, the crystal structures of these new dca complexes are described anddiscussed in detail. Besides two mononuclear complexes, 1 and 2, complexes 3～15 arecoordination polymer with novel and interesting structural characteristics. 3, 6, 7, 8, 9 are 1Dpolymers, 4 and 5 are of 2D extending structure, while 10, 11, 12, 13, 14, 15, 16, 17 form thefirstly reported series heteronuclear dca coordination polymer, in which (except 10) differentbuilding blocks, with different metal ions in them, construct interesting architecture, like α-and β-type 〓 chains, ladder chain 〓, scaffold structure of 12, and "sandwich"layer structure in 15 and 16, etc..

这些配合物是：第三章中，我们详细描述讨论了这些新型的二氰胺配合物的晶体结构，除两个单核配合物1和2之外，其余十五个为配位聚合物并具有新颖和有趣的结构特征。3，6，7，8，9是一维配位聚合物，4和5则呈现二维扩展结构，而10，11，12，13，14，15，16，17属于首次报道的一系列的二氰胺异金属配位聚合物，其中(除10外)含有不同金属离子的构造&砌块&可构建出有趣的结构，如α-和β-型〓链，梯形链〓，12中的脚手架结构，以及15和16中的&三明治&层状结构等。

A series of studies by using X-ray monocrystal analysis as the main methods on rare earth complexes with p-amino acids, heteronuclear complexes with a-amino acids and some complexes with different ligands were reported in this paper.

本论文以单晶X-射线衍射为主要手段对β-氨基酸稀土配合物、α-氨基酸异核金属配合物和以α-氨基酸为混合配体的金属配合物进行了较为系统的研究。

Heterozygous metallic: One copy of the metallic gene and one copy of the non-metallic gene.

杂合金属：一份金属基因的副本，非金属基因。

The molecular sieve is prepared in the steps: at the room temperature, hexadecyl trimethyl ammonium bromide is mixed and dissolved with the sodium hydroxide, and is added with TEOS in dropping way, and simultaneously added with Me metal salt water solution and lanthanum nitrate solution in dropping way; the pH value of the mixed solution is adjusted by acetic acid to be 10 to 11, and is mixed for 1 to 2 hours after being stabilized; the sol is moved into a polyfluortetraethylene bottle to be heated and crystallized for 2 days in the oven at the temperature of 100 DEG C; after filtering, washing and drying for nights, and being calcined in a muffle at the temperature of 550 DEG C for 3 to 7 hours, the dual-metal-atom improved MCM-41 mesoporous molecular sieve is obtained.

该分子筛的制备为室温下，将十六烷基三甲基溴化铵和氢氧化钠混合溶解，搅拌并滴加入TEOS，同时滴加入Me金属盐水溶液和硝酸镧溶液并搅拌，用乙酸调节pH值至10～11，稳定后搅拌1～2小时，溶胶转入聚四氟乙烯瓶中在100℃下烘箱水热晶化2天，经过滤、洗涤、干燥过夜，马弗炉550℃焙烧3-7h，得双金属原子改性MCM-41介孔分子筛产品。

Both catalytic activity and selectivity of Ru(PPh_3)_3Cl_2 were improved in ionic liquid BMImPF_6/DME medium.The conversion of hexene and selectivity ofβ-adduct for the hydrosilylation reaction of 1-hexene with triethoxysilane catalyzed by Ru(PPh_3)_3Cl_2 in ionic liquid BMImPF_6DME (V/V=1/4) medium at 90℃were 100% and 89.0%,respectively.

实验结果表明，在乙二醇二甲醚/离子液体1-丁基-3-甲基咪唑六氟磷酸盐(BMImBF_6)(V/V =1/4)介质中，于90℃下，己烯与三乙氧基硅烷反应的转化率为100%，β加成物的选择性可达89.0%，而用Rh(PPh_3)_3Cl作为反应的催化剂，在纯离子液体BMImPF_6中，就可以高效催化烯烃与三乙氧基氢硅烷的加成反应，过渡金属Rh(PPh_3)_3Cl，Ru(PPh_3)_3Cl_2催化剂/离子液体BMImPF_6催化体系，不仅解决了产物与催化剂分离困难这一难题，同时，离子液体BMImPF_6的存在提高了过渡金属Rh(PPh_3)_3Cl，Ru(PPh_3)_3Cl_2催化硅氢加成反应的活性，特别是β加成物的选择性。

Both three-dimensional chiral compounds have intriguing chiral channels, which are built up of homochiral intertwined double helices. The circular dichroism spectra of 1 and 2 in water have shown they are stable in solution, which document they will be significantly useful in asymmetric catalysis and chiral medicine.

以Keggin结构多金属氧酸盐为建筑单元，通过手性的铜-脯氨酸配合物作为模板剂构筑了2个基于Keggin结构多金属氧酸盐的3D纯手性化合物，化合物1和2是一对对映体，代表了世界上第一例3D手性多酸化合物，具有由同手性螺旋缠绕形成的手性孔道，水溶液中的圆二色谱表征这个3D手性化合物可稳定存在，显示这个物种可以在不对称催化及手性药物方面有潜在的巨大的应用价值。

Objective: To investigate the effects of Hovenia dulcis extract on mRNA expression of MMP-13 and TIMP-1 mRNA in hepatic tissue in experimental rats.

中文摘要：目的：探讨枳子提取物对实验大鼠肝组织基质金属蛋白酶-13(MMP-13)与金属蛋白酶组织抑制因子-1(TIMP-1)表达的影响。

Objective To explore the significance of expression of matrix metalloproteinases and tissue inhibitor of metalloproteinases -2(TIMP-2) in benign and malignant hydatidiform molr.

目的 探讨基质金属蛋白酶(MMP- 2 )及金属蛋白酶组织抑制因子(TIMP- 2 )在良、恶性葡萄胎组织中的表达及临床意义。

The invention relates to a metal plug-in layer in film of GaN and its preparation method by hydrogenide vapour phase denotation, which is characterizes in that it adopts structure of wolfram plug-in layer.

本发明涉及一种氢化物气相外延氮化镓膜中的金属插入层及制备方法，其特征在于采用了金属钨插入层的结构。

According to the variation in the components of intermediateacid igneous rocks coming from the lower crust, it is possible to restrain the depth of the source area and the minimum thickness of the crust, and thus to provide important information for the study of the deep process of the continental intraplate mineralizationGlobally, many world level porphyry copper deposits and metallogenic systems formed by hypabyssal hot liquid have their close relationship with the synchronous adakite in spacetime and genesis; domestically, the adakitelike rocks have been identified to be related to the metallogenesis in the main metallogenic areas in ChinaThe recognition of adakitelike rocks having no relationship with the process of subduction makes it possible to construct a metallogenic model of continental intraplate porphyry metal deposits by combining other geological evidences, and this model is totally different from the metallogenic model of porphyry copper deposits with Bsubduction setting constructed by Sillitoe (1972)The existence of adakitelike rocks may be the necessary condition but not the sufficient one for forming the largescale porphyry deposits and the hypabyssal hotliquid deposits, whose metallogenic elements mainly came from the mantleThe metallogenic potential of adakitelike rocks is achieved by the entering of the mantle material, and the metallogenic specialization of adakitelike rocks is decided by the distribution characteristics of the metallogenic elements in the upper mantleAn important reason for the adakitelike magma related to subduction being advantageous to mineralization is that there were abundant high pressure and high temperature liquid coming from the subducted platepieces and the magma of high fO2 coming from the melting of subducted platepiecesHowever, for those adakitelike rocks, whose occurrence has continental plate background but does not relate to the subduction, their metallogenic mechanism is not clear yetBased on the concept of modern mineral exploration and combined with the analysis of integrated geological information, we may better realize the practical prospecting significance of the adakitelike rocks

根据起源于下地壳的中酸性岩浆岩的成分变化，可以约束其源区深度以及地壳最小厚度，为大陆板内成矿作用的深部过程研究提供重要信息。全球范围内，许多世界级斑岩铜矿和浅成热液矿化系统与同期的埃达克质岩存在密切的时空与成因联系，在国内主要成矿区带也识别出与金属成矿作用有关的埃达克岩。与俯冲过程无关的埃达克质岩的识别，使我们有可能结合其他地质证据构建完全不同于Sillitoe(1972)B型俯冲环境的斑岩铜矿成矿模式的大陆板内斑岩型金属矿床成矿模式。对于规模巨大、矿质主要源自地幔的热液矿床的形成，埃达克岩可能是必要条件，但不是充分条件。埃达克岩的成矿潜力通过地幔物质加入而获取，埃达克岩的成矿专属性由上地幔成矿元素分布特征决定。与俯冲有关的埃达克质岩浆之所以有利于成矿，重要的原因是存在大量来自俯冲板片的高压、高温流体以及俯冲板片熔融形成高氧逸度(fO2)的熔体，但产出在大陆板内背景、与俯冲无关的埃达克岩的成矿机制还不清楚。根据现代资源勘查理念，结合综合地质信息分析，埃达克质岩具有实际找矿意义。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。