金属

The ru1es of crystal parameters varing with the scale of nonfreedom were found out. Spectrum series were theoretically interpreted as well.

经过初步研究表明，金属蛋白中，金属离子与氨基酸结合，可以通过金属离子和氨基酸配合物的结构得到指示。

The results show that, Au-19.25Ag-12.80Ge brazing alloy is better, its melting temperature range is 446.76494.40 ℃, and the temperature interval between the solidus and the liquidus is 47.64 ℃. When the brazing temperature is in the range of 510550 ℃, the alloy has a good spreadability and wettability with Ni. Interface structure observation reveals that there is one continuous intermetallic layer between the brazing alloy and the base metal Ni when welding. X-ray energy spectrum analysis results show that the intermetallic layer is Ge3Ni5, and because of its brittleness, the overthick intermetallic layer will decrease the shear strength of the welding joint, therefore, the welding technology should be controlled so as to gain an ideal welding interface structure.

研究结果表明：Au-19.25Ag-12.80Ge合金的性能较好，其熔化温度范围为446.76~494.40 ℃，结晶温度区间为47.64 ℃；焊接温度在510~550 ℃范围内时，Au-19.25Ag-12.80Ge钎料合金与Ni基体具有良好的铺展性和润湿性，焊接时钎料合金与Ni基体之间形成了一条连续的金属间化合物层，能谱分析表明该金属间化合物层为Ge3Ni5，由于该化合物较脆，过厚的金属间化合物层使焊接接头的剪切强度下降，故应适当控制焊接工艺以获得理想的焊接界面组织。

In the thesis, a series of novel single and multi-armed oxadiazole bridging ligands and pyridyl-4, 5-imidazole dicarboxylic acid ligands have been synthesized. The coordination chemistry of these novel ligands with transition metal ions was investigated. In addition, two 1, 3, 4-oxadiazole bridging ligands end-capped by chelating Schiff-base coordination sites have been designed and synthesized. The coordination chemistry based on one of the two ligands with metal ions was primarily investigated.

本文报道了一系列新颖的含1， 3， 4-Oxadiazole杂环的单臂及多臂有机配体，研究了它们与过渡金属离子的配位反应化学；合成了吡啶基-4，5-咪唑二羧酸有机配体，研究了它们在水热条件下与过渡金属离子的配位反应化学；另外，还合成了1， 3， 4-Oxadiazloe杂环桥联的双Schiff-base有机配体，初步探讨了其与过渡金属离子的配位反应化学。

Patu; Lei Oiongzhi; Ski Changxu (Shih Chang-hsu) Institute of Metal Research, Academia Sinica, Shenyang

中国科学院金属研究所；中国科学院金属研究所；中国科学院金属研究所

We study the express of heparinase,matrix metalloproteinase MMP-2,MMP-14 and cadherin in the gastric cancer tissue and perigastric normal mucosal tissue,and make a statistics analysis between heparinase, matrix metalloproteinase MMP-2,MMP-14,E-cadherin and gastric cancer biological behavior.We hope to knom the possibility that heparinase,matrix metalloproteinase MMP-2,MMP-14,E-cadherin are regared as clinical screen index of the gastric cancer recrudescence or metastasis.

本文就肝素酶、基质金属蛋白酶MMP-2、MMP-14、钙粘蛋白在胃癌组织及胃周正常粘膜的表达进行了研究，并就肝素酶、基质金属蛋白酶MMP-2、MMP-14、钙粘蛋白与胃癌的生物学行为进行了统计学分析，以期了解肝素酶、基质金属蛋白酶MMP-2、MMP-14、钙粘蛋白作为胃癌复发或转移的临床筛选指标的可能性。

The conductive coordinative polymolecular compounds,which contain thetransition metal ions〓and〓as central metal ions,transition metal ionsor rare earth ions as counter cations and〓or〓as ligand,have been synthesized.

合成出以过渡金属〓、〓、〓、〓和〓作为中心金属离子、过渡金属或稀土离子作为抗衡阳离子、有机小分子〓或〓作为配体的导电性配位高分子化合物，它们均为能在空气中稳定存在且难溶和难熔的无定形粉末状固体。

For the first time we synthesized nanoscale metal hydrides of lanthanum, neodymium, samarium, dysprosium, and ytterbium with high efficiency under mild condition by complexometric catalysis instead of traditional preparation at high temperature and high pressure. It is for the first time that we synthesized lanthanide organic compounds with catalysts or initiating agents at atmosphere and ambient temperature,and some of them are new compounds. Nanometric lanthanide metal powders are prepared by thermal decomposition of the compounds in vacuum. Differently from the traditional method, size of the products prepared by our method is less than 40nm, and the activity of the reaction is very high. They are pyrophoric at atmosphere. They can make some reactions without activity or low activity show extremely high activity .We investigated influent regulations of methods, conditions to scale and special surface.

我们首次成功地用络合催化等方法取代需在高温高压下进行的传统方法，在温和条件下高效率地合成出纳米尺寸镧、钕、钐、镝、镱的金属氢化物；首次在常压常温的条件下，通过催化、引发等方法合成镧系金属有机化合物，再将其真空热分解成功地制备了纳米尺寸的镧、钕、钐、镝、镱等金属粉末；与传统方法不同，这些方法得到的产品基本颗粒尺寸小于 40 nm，遇到空气燃烧，具有极高的化学反应活性，使原来活性很低甚至观察不到活性的反应大幅度提高反应速率和产率；考察了制备方法、制备条件等因素对晶粒尺寸、比表面积大小等的影响规律。

A highly active hydrogen added catalytic nanometer Ru/C is made by reducing metal ruthenate, getting nanometer ruthenate metal glue under the protection of surface activator, filtering, washing glue solution drawing by the carrier to get highly scattered loading nanometer ruthenate metal catalyst.

本发明涉及一种高活性加氢催化剂纳米Ru/C的制备方法，该方法首先通过化学还原金属钌盐，制得表面活性剂保护下的纳米钌金属胶体，然后用载体吸附制得的胶体溶液，经过滤，洗涤，获得高度分散的负载型纳米钌金属催化剂。

In this paper, material properties of the segment of the porous metal-bonded diamond grinding wheel were researched by finite element simulation. Segments were manufactured according to the design result and their elastic modulus was measured. The key points are as follows: The influence of the porosity on the elastic modulus was analyzed through a finite element method. In the FEM model, the design variable only includes the porosity, and the tetrakaidecahedron model is applied as the microstructure model of porous metal matrix. The corresponding porosity was decided in order to meet the requirement of the elastic modulus.

本文利用有限元软件对多孔金属结合剂金刚石砂轮节块的材料性能进行了数值模拟计算，依设计结果制备了节块试样，并测试了节块的弹性模量，主要内容有： 1、充分借鉴多孔材料结构设计和分析的方法，以十四面体模型为多孔金属胎体的微观结构模型，以孔隙率为设计变量，通过有限元分析，计算出满足一定弹性模量要求的多孔金属胎体的孔隙率范围。

HUMMEL Jiaxing Electric Co., Ltd., is a professional engaged in the production of industrial connector products manufacturers, the main products: hoses, hose connectors, hose right angle connectors, hose fixation, plastic waterproof connector cable, metal cable waterproof connectors, plastic package metal hose, metal hose connectors, towline and so on.

嘉兴胡默尔电气有限公司，是一家专业从事生产工业连接器产品的厂家，主要产品：软管，软管接头，软管直角接头，软管固定支架，塑料电缆防水接头，金属电缆防水接头，包塑金属软管，金属软管接头，拖链等。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。