量热

In this paper,a set of high temperature calorimetric system for measurement of heat sink of endothermic fuels has been developed. Its constructional details and operational principles are also related.

报道了一套适用于高温条件下工作的新型量热系统，通过电能标定和氮气热沉的测定，证明该量热系统设计合理，工作正常，其性能符合 Tian's方程的要求，测量精度能满足工程需要。

A novel high-temperature flow calorimetric system of conduction type was designed, with a built in chromatograph suitable for on-line analysis.

建立并完善了一套高温流动型热导式量热装置，实现了量热与色谱在线分析的有机结合。

The result indicated that, DTA and DSC apparatus constants of CDR-1 dynamic differential thermal analyzer increase along with temperature increment, but influence of temperature on DTA apparatus constant is more remarkable.

采用6种标准物质测定CDR-1型差动热分析仪的差热分析法和差示扫描量热法仪器常数，结果表明：CDR-1型差动热分析仪的差热分析法和差示扫描量热法仪器常数均随温度的升高而增大，而差热分析法仪器常数受温度的影响更为显著。

The fabrication of fibers was attempted. The copolymers, the copolymers containing MOCT and the copolymer films containing MOCT were characterized by using Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy, Differential Scanning Calorimetry, Thermogravimetric Analyzer and X-ray Diffraction etc. The conclusions were summarized as following,1. The AN/MMA copolymers were testified that copolymerization of most AN and MMA occurred and the ratio of AN and MMA in copolymer was less than the ratio of monomers. With the increase of the contents of MMA, the viscosity of copolymer solution, molecular weight and decomposition temperature of copolymers increase.

通过傅立叶变换红外光谱、扫描电子显微镜、差示扫描量热分析、热重分析、X-射线衍射分析等测试方法对得到的AN／MMA共聚物、含有正十八烷微胶囊的共聚物以及共聚物膜等进行了测试和分析，得到如下的研究结论： 1、丙烯腈—甲基丙烯酸甲酯之间发生了聚合反应，共聚物的组成比略小于投料比；共聚物的粘度和分子量随着第二单体MMA加入量的增加有增大的趋势；第二单体加入量的增大使得共聚物的分解温度升高，通过热重分析证实当AN／MMA摩尔比为85／15时，共聚物的耐热稳定性较高。

The paper first constructs the relating technology framework between coal low temperature self-heating thermal properties parameters and spontaneous combustion, by means of testing on coal samples of diffusibility relative to oxygen, gas-producing simulation in self-ignition process, adiabatic oxidation process, coal spontaneous combustion processing simulation, coal basic physical and chemical parameters, thermal analysis by differential scanning calorimeter , differential thermal analyzer , Thermogravimeter .

通过对试验煤样进行煤对氧的扩散特性试验、煤自然发火过程中气体产物模拟实验、DSC差示扫描量热热分析测试、DTA与TG热分析测试、煤自然发火绝热氧化过程试验、煤自然发火过程模拟试验、煤基础物理化学参数测试的试验研究，就煤对氧的扩散与吸附特性、煤自燃氧化过程中的热力特性与气体产物特性及其与煤自然发火过程之间的相关特性进行了较系统的研究，初步建立了煤低温氧化自热热物理特性参数与煤自然发火之间相关联的技术内涵。

The heat generation curves of seven rubber materials used in tires with the changes of temperature have been obtained by using Dynamic Mechanics Analysis technique on NETZSCH DMA242 instrument, knowing that the heat generation of every other rubber materials except inner liner rubber changes lightly alone with the temperature within 10℃～80℃. According to the Fourier law, the heat transfer coefficients of tire rubber are measured by stable method on self-made experiment instrument. The coefficients changes lineally within 20℃～80℃ and the relation formulas λ=λ〓+bt are given out attached with λ〓 and b. The specific heat of tire rubber are measured on Differential Scanning Calorimeter NETZSCH DSC204 and the relations with temperature are linear and the formula is c=c〓+bT, where c〓 and b gained from experiment result data are presented in the paper. The heat convection coefficients on the surface of rolling tire are measured according to the principle of heat-mass transfer analogy principle after simplifying rolling tire into rotating disk with straight movement on wind channel. The relation with rotation speed of disk is linear as h=5. 399+0.0258n and the relation with straight line speed of tire is linear too, h=

论文采用动态力学分析技术，使用NETZSCH DMA 242型实验仪，获得了轮胎用七种胶料的生热率随温度变化曲线，确知除内衬层胶以外，其它各种胶料在一般胎温范围内（10℃～80℃）的生热率随温度变化不大；轮胎胶料的导热系数根据傅立叶定律的基本原理，采用稳态法在自行搭建的实验台上进行测试，结果表明，材料的导热系数在20℃～80℃的温度范围内随温度呈线性变化，论文给出了各种材料导热系数的线性变化的关系式λ=λ〓+bt及其λ〓和b的值；轮胎胶料的比热运用差式扫描量热原理，在NETZSCH DSC204型DSC实验仪上进行测试，结果表明，胶料的比热随温度的变化呈线性变化，其关系可用c=c〓+bT表示，文中给出了根据实验数据拟合的c〓、b的值；对轮胎表面的对流换热系数的测定，本文先将滚动的轮胎简化为有直线运动的旋转圆盘，而后采用萘升华热质比拟技术，在风洞中测量了滚动轮胎表面的对流换热系数，结果表明，圆盘表面对流换热系数与转速呈线性关系，即h=5.399+0.0258n，轮胎表面对流换热系数与其直线运动的速度呈线性关系，即h=

In this thesis, the phase diagram of Zn-Al binary system on 10~69.5 w% was reinvestigated by using differential scanning calorimeter, X-ray diffraction and pushrod dilatometer. The process of isothermal transformation during the aging of high-Aluminum-Zinc-based alloy was studied by using differential scanning calorimetry, and the aging behavior of the alloy was analyzed at the aspect of thermal analysis kinetics. The change of microstructure which the alloy was being heated was observed on high-temperature metallurgical microscope. The microstructure and wear-friction properties were compared among the alloys treated with several different heat treatment processes, and a model for heat treatment processes was proposed based on artificial neural network,so as to predict the relationship between friction coefficient and parameters of aging treatment such as aging temperature and time.

本文采用高温X射线衍射、示差扫描量热分析、热膨胀等方法重新测定含锌量范围为10％～69.5％的Zn-Al系二元相图，利用示差扫描量热分析法，研究高铝锌基合金时效等温转变过程，并从热分析动力学的角度分析高铝锌基合金合金时效行为；使用高温金相显微镜观察合金加热时的组织变化；比较几种不同热处理工艺对高铝锌基合金显微组织与耐磨性能的影响并利用人工神经网络建立高铝锌基合金热处理工艺模型，预测合金摩擦系数随时效温度及时间变化规律。

This paper discussed the determination method of solid decompound enthalpy with oxygen bomb calorimeter. After the solid sample and standard substance were accurately quantified and uniform mixed, and the pressed piece was put into the oxygen bomb and combustion.

探讨了利用氧弹量热计测定固体物质分解焓的方法，准确称取一定量的固体样品和基准物质，均匀混合后压片，放入氧弹量热计燃烧，记录燃烧前后时间和氧弹量热计温度变化数据。

A study on thermal denaturation of hen egg-white lysozyme was carried out by differential scanning calorimetry and modulated temperature differential scanning calorimetry. It was found that DSC profiles of HEWL were dependent on heating rates and concentrations of enzyme as well as cosolvent.

利用差示扫描量热和温度调制差示扫描量热研究了鸡蛋白溶菌酶在纯水及二甲基亚砜/水混合溶剂中的热变性过程，探讨了酶的浓度、扫描速率和共溶剂的含量对热变性行为的影响规律。

Firstly, micro-thermal calorimeters were used to qualitatively analyze the thermochemistry behaviour of reactants system under adiabatic mode; Subsequently a series of toluene nitration experiments were carried out in an isothermal reaction calorimeter to study the influences of different operating conditions such as stirring speed feeding rate and setting temperature and so on . The thermal hazard assessment of toluene nitration was derived from the measured calorimetric data, the rate of the reaction the adiabatic temperature increase △T_ad and maximal temperature attainable MTSR_max in a runaway situation can also been derived.

首先采用微量热分析仪对反应体系在绝热状态下的热行为进行分析；再采用等温条件下的反应量热器实验研究不同的工艺条件如搅拌速度、加料速度和设定温度等参数对反应结果的影响；结合热分析数据和RCle数据，对甲苯的一段硝化过程进行了初步的热危险分析，推导出反应速率方程、反应失控条件下的绝热温升△T_和反应所能达到的最大温度MTSR等参数。

The concept of equivalent rotationally rigidity is offered and the formula of rotationally rigidity is obtained.

主要做了如下几个方面的工作：对伸臂位于顶部的单层框架—筒体模型进行分析，提出了等效转动约束的概念和转动约束刚度的表达式。

Male cats normally do not need aftercare with the exception of the night after the anesthetic.

男猫通常不需要善后除了晚上的麻醉。