醛类

Starting with two reactive methylene compounds, ethyl cyanoacetate and malononitrile, two 5-amino-1H-pyrazoles were prepared through the intermediates ketene dithioacetal.

从两个活泼亚甲基化合物开始，经过乙烯酮二硫代缩醛中间体，合成了两个5-氨基-1H-吡唑，以这个两个化合物为中间体，与芳香族和脂肪族α-溴代酮反应，而后经酸催化亚胺化互变异构后得到含咪唑并[1，2-b]吡唑甲硫醚类化合物6a-6g。

Furoin was synthesized from furol with VB1 as the catalyst,which was then reacted with acetyl chloride, lauroyl chloride ,benzoyl chloride,α-furoyl chloride and 3-α-furyl acryloyl chloride,respectively;corresponding monoester compounds of furoin were synthesized in THF in the presence of sodium hydroxide under reflux.

以糠醛为基础原料，经维生素B1催化合成糠偶姻，再由糠偶姻分别和乙酰氯、月桂酰氯、苯甲酰氯、α-呋喃甲酰氯和3-α-呋喃烯丙酰氯反应，在NaOH/无水THF体系中，于水浴回流条件下合成了相对应的糠偶姻单酯类化合物。

(1)PAL is better entrapped by PAG with a T∶C ratio of 8∶30.(2)PAL immobilized by glutaric dialdehyde on Bio-Gel P-300 is better than by CDC.(3)The best one is the dehydration and redehydration method.(4)Immobilized and permeated PAL active yeast cells are resistant to trypsin digestion and retain its PAL activity.

(1)固定化酶活性采用T∶C比为8∶30明显高于8∶19；(2)以戊二醛将PAL固定于Bio-GelP300优于用DCD固定化的酶；(3)质脂体包被中以脱水再加水法对酶活性影响较少，脂类组成以磷脂酰胆碱：胆固醇：磷脂酰丝氨酸比值7∶2∶1最好；(4)固定化PAL活性酵母细胞能较好地抵抗人工肠液中胰蛋白酶的水解作用，亦能明显降低苯丙氨酸的浓度。

Thirteen benzimidazole derivatives were synthesized by one-step oxidative cyclisation of 1, 2-phenylenediamine or 4-methyl-1, 2-phenylenediamine at room temperature and a series of aromatic aldehydes under imidazolium salt grafted iodobenzene diacetate assisted.

以水为溶剂，在咪唑盐二醋酸碘苯促进下，通过邻苯二胺或4-甲基邻苯二胺与各种芳醛室温氧化环合，一步合成了13种苯并咪唑类衍生物，反应时间25~45 min，反应产率92%~98%。

Thus,α,β-unsaturated ketones were prepared by base-catalized aldol condensation between substituted arylaldehydes and acetones. Using iodosobenzene diacetate as oxidants, the resulting α,β-unsaturated ketones will be transformed to β,γ-unsaturated carboxylic acid esters.

以不同取代的芳香醛跟丙酮缩合后可以得到α，β-不饱和酮，再用iodosobenzene diacetate做氧化剂氧化，可以成左卤o到β，γ-不饱和碳酸酯类化合物。

Oxidation of alkenes catalyzed by metalloporphyrin imidazolium salts in the presence of N-hydroxyphthalimide and isobutyraldehyde as co-catalysts provided the epoxidation product at room temperature. And the solvent with a weak coordinating ability such as acetonitrile gave the best result.

金属紫质咪唑盐於烯类的氧化催化反应上，若与NHPI及异丁醛共催化，可在室温进行环氧化反应，反应溶剂选择具有弱配位能力的乙腈，则可获得较佳结果。

The novel title compound was synthesized with benzaldehyde, isobutyraldehyde, phosphorus trichloride as raw materials. The total yield was 40.8%. The structure was confirmed by 1H NMR, 31P NMR and elemental analysis.

摘要以苯甲醛、异丁醛、三氯化磷为原料合成了新型的1，3，2-氧磷杂环类化合物2-苯羟甲基－5，5-二甲基－4-苯基－2-氧代－1，3，2-二氧磷杂环己烷，总收率为40.8%，并对其进行了NMR研究和结构表征。

The major causes of off-flavour of the cooked rice was due the intractions among rice proteins, lipids and carbohydrates, which result in the production of carbonyl compounds,the increase of caproaldehyde,and the decrease of acetaldehyde and mercapto group as well as the changes in the cell wall structures.

本文结合近几年研究工作及国内外对大米陈化研究的新进展，综合阐述了随大米存放时间的延长，其化学组织特别是大米蛋白质、类脂与淀粉的共同作用，促使羰基化合物的生成、乙醛减少、己醛增加、SH基减少，以及胞壁改变，是造成大米陈化、米饭&陈米臭&的主因。

Isolation and identification results of volatile compounds showed that aldehydes, alcohols and ketones were the major volatile compounds formed in the processing of XUANWEI ham, and had the highest relative contents in the 6-month-old, which were 11326.18, 947.29 and 554.95 μg nonane 100g-1, respectively. The result was relevant to intense hydrolysis of intramuscular fat in the pre-processed ham (4-month-old).

挥发性化合物的分离鉴定结果表明：醛、醇和酮类是火腿加工过程中形成的主要挥发性化合物，在6月龄时，它们的相对含量最高，分别为11326.18、947.29和554.95μg壬烷／100 g，此结果与加工前期（4月龄）肌内脂肪发生强烈水解相关。

By using gas chromatography technique nine kinds of fragrance components(acetic aldehyde,ethyl acetate,ethanol,propyl acetate,3-hydroxy-2-butanone,acetic acid,furfural,metacetonic acid,2,3-butylene glycol)were measured quantitatively in different kinds of Shanxi overmature vinegar and the other kinds of vinegar.

应用气相色谱方法对山西老陈醋和其他种类醋的9种香气成分(乙醛、乙酸乙酯、乙醇、乙酸丙酯、3-羟基-2-丁酮、乙酸、糖醛、丙酸、2，3-丁二醇)进行了定性、定量测定，并用聚类分析、模糊综合评判、方差分析、回归分析的方法对实验结果进行了数理分析。

And Pharaoh spoke to Joseph, saying, Your father and your brothers have come to you.

47：5 法老对约瑟说，你父亲和你弟兄们到你这里来了。

Additionally, the approximate flattening of surface strip using lines linking midpoints on perpendicular lines between geodesic curves and the unconditional extreme value method are discussed.

提出了用测地线方程、曲面上两点间短程线来计算膜结构曲面测地线的方法，同时，采用测地线间垂线的中点连线和用无约束极值法进行空间条状曲面近似展开的分析。