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醛烯酮

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Secondly,a mixture of acetone and methyl formate was added into the methanol solution of sodium methoxide to prepare sodium formyl acetone by Claisen reaction.

以金属钠为原料,甲醇为溶剂,先制成甲醇钠的饱和甲醇溶液,再滴加丙酮和甲酸甲酯进行Claisen酯缩合制得丁酮烯醇钠,最后在强酸作用下与甲醇进行缩醛化反应合成了4,4-二甲氧基-2-丁酮,过程总收率达到73.1%,纯度98.7%。

In chapter four molecular modeling method is employed to comparatively study five S-allyl γ-hydroxy ketene dithioacetals reactions of Thio-Claisen rearrangement with and without zeolite catalysts.

第四章用分子模拟途径研究了在有、无分子筛催化条件下五种丙烯基羟基乙烯酮二硫代乙缩醛Thio-Claisen重排反应。

Chapter 4: Synthesis of 1,5-diary 1-1,4-pentadien-3-ones from acetone or benzalacetone with aromatic aldehydes results in 86-97% yield with potassium hydroxide as catalyst under ultrasound irradiation in 5-60min.

为合成氰基环己醇找到一条方便高效的合成方法。第四章:研究了超声辐射下,以氢氧化钾为催化剂,芳香醛与丙酮及亚苄基丙酮之间反应合成1,5-双苄基-1,4-戊二烯-3-酮。

Quinone methides, generated in situ from the reaction of 4-hydroxycoumarin with benzaldehyde, formaldehyde and pentanal, underwent the Diels-Alder reaction with silyl enol ethers to give a series of 3,4-dihydro-2H,5H-pyrano[3,2-c][1]benzopyran derivatives in high yields.

通过4-羟基香豆素与苯甲醛、甲醛和戊醛缩合产生的quinone methide与烯醇硅醚的Diels-Alder反应,以较高产率合成了一系列含有硅氧基的3,4-二氢-2H,5H-吡喃并[3,2-c][1]苯并吡喃-5-酮衍生物。

Several routes for synthesizing methyl isopropyl ketone were introduced, including the main methods based on isobutyl aldehyde-acetic acid, isobutyric acid -acetic acid, methyl ethyl ketone-formaldehyde and isoprene.

介绍了甲基异丙酮的多种合成路线,主要有异丁醛-乙酸法、异丁酸-乙酸法、甲基乙基酮-甲醛法和异戊二烯法。

A series of 3 - aryl - 3 -( 5,5 - dimethyl - 3 - hydroxy - 2 - cyclohexene - 1 - one - 2 - yl) propanoic ester s were synthesized by reaction between aromatic aldehydes ,5,5- dimethyl -1,3-cyclohexanedione and isopropylidene malonate catalyzed by KF - Al2O3 in alcohols.

在KF-Al_2O_3催化下,将芳香醛3,5-二甲基-1,3-环己二酮及丙二酸亚异丙酯在醇中反应,一锅式合成了一系列的3-芳基-3-(5,5-二甲基-3-羟基-2-环己烯-1-酮-2-基)丙酸酯。

Chemical Products, Chemicals: inorganic acid, sodium compounds, potassium compounds, calcium compounds, barium compounds, manganese compounds, chromium compounds, nickel compounds, zinc compounds, magnesium compounds, aluminum compounds, single-element chemical products, even items of the five machines Chemical products, paraffin, waxes other chemicals, coke, oil and chemicals, alcohol, aldehyde chemicals, acetate chemicals, ketones, ethers, phenols chemicals, alkanes, alkenes, acetylene chemicals, amine chemicals, aromatic chemicals, Miscellaneous organic chemicals, acid chemicals, other chemicals, dyes and intermediates, pigment materials, plastic materials, agricultural chemicals: fertilizers, pesticides, growth agents, plastic sheeting, etc., equipment, pyrophoric alloys, articles of combustible materials , chemical reagents, rubber, imports, machinery and equipment, machinery and equipment, apparatus; photographic equipment; printing equipment; general machinery; textile equipment; Machine Components; a variety of equipment, Shanghai, Zhejiang, Guangdong, Jiangsu high-quality, low-carbon The new satellites technology goods manufacturers, exporters, wholesalers, traders, USA, United States importers, wholesalers, retailers, investors, designers, planners, please contact our office, George Chen, Mobile :+

化工产品类,化工原料:无机酸,钠化合物,钾化合物,钙化合物,钡化合物,锰化合物,铬化合物,镍化合物,锌化合物,镁化合物,铝化合物,单元素化工品,什项五机化工品,石蜡、蜡类其他化工品,焦、油化工品,醇、醛化工品,酯化工品,酮、醚、酚化工品,烷、烯、炔化工品,胺化工品,芳烃化工品,什项有机化工品,羧酸化工品,其它化工原料,染料及中间体,颜料原料,塑料原料,农用化工品:化肥,农药,生长剂,农膜等,器材,引火合金,易燃材料制品,化学试剂,橡胶,进口,机械设备,机械及设备,仪器;摄影器材;印刷器材;通用机械;纺织器材;机械基础件;各种成套设备,中国上海,浙江,广东,江苏优质,低碳,新颗科技商品生产商,出口商,批发商,贸易商,美国,美利坚合众国进口商,批发商,零售商,投资商,设计师,规划师们,请与我处联系,George Chen,Mobile:+

The neutral/basic fraction was furthermore separated into 4 fractions using silica gel normal phase chromatography, and each fraction was then concentrated and analyzed using gas chromatography-mass spectrometry. In comparison with the pure standards and the retention indices reported in the literature, a total of 302 volatile compounds were identified in Changyu XO brandy, including 30 alcohols, 35 aldehydes and ketones, 20 carboxylic acids, 104 esters, 24 substituted benzenes and derivatives, 14 phenolic derivatives, 14 acetals, 16 furan derivatives, 22 terpenic and norisoprenoidic derivatives and 23 others.

实验先采用液-液萃取方法提取张裕XO级白兰地的挥发性成分,然后将酸性成分与碱性和中性成分分离,再采用柱色谱分离手段将其分离为若干个级分并浓缩,采用气相色谱-质谱、标准品比对、保留指数值比较等方法对分离得到的各级分中的成分进行了鉴定,在白兰地中共鉴定出302种挥发性成分,包括醇30种、醛酮类35种、酸类20种、酯类104种、苯同系物及其衍生物24种、酚类14种、缩醛14种、呋喃类16种、萜烯类22种和其他物质23种。

A conjugate addition of alkadienyl carbonyl compound with vinyl palladium intermediates which can be formed from oxypalladation of alkynes or allenes was studied, and 1, 6-addition products were obtained.

发现不饱和烃的分子内氧钯化得到的烯基钯中间体能够与不饱和共轭双烯的醛酮反应,选择性的得到1,6-加成产物。

Progresses on reactions of NO, CAN, and hydrazone Reactions of NO with olefines, phenols, amines, arylhydrazines, Schiff bases and nucleosides are firstly reviewed.

本论文主要研究了一氧化氮及硝酸铈铵与简单醛酮腙、α,β-不饱和酮腙的反应,全文共分五个部分: 1、一氧化氮、硝酸铈铵及腙的反应研究首先对具有特殊生物活性的NO与烯、酚、胺、肼、Schiff碱、核酸碱基等有机物的反应做了全面的总结。

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