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In this study, the electrical conductive composites (comprised of thermoplastic matrix resins-high density polyethylene, polyphenylene sulfide and polyarylethersuifone with cardo group, and conductive fillers-short carbon fiber, carhon black and graphite) are prepared and characterized in detail. The relation among composite structure and directalternating electric properties, some electric and magnetic parameters under X-band microwave and shielding effect, the mechanical behaviour are analysed. And furthermore, some relative experimental devices are developed.

本工作利用短切碳纤维、炭黑、石墨为导电填料填充热塑性树脂高密度聚乙烯、聚苯硫醚、酚酞型聚芳醚砜,制得具有良好导电性能和机械性能的导电性高分子复合材料,并以此为对象,研究了材料的稳恒电场和交变电场的基本特性与材料结构的关系,研究了在X波段微波场下的电磁参量及屏蔽效应,以及研究了复合材料及其基体树脂的力学行为,与此同时还建立了相应的表征测试手段。

The effects of feeding way of phosphorus pentoxide, ratio of C8H174OH to P2O5, reaction temperature and time on the synthesized isooctanol polyethenoxy ether phosphate were investigated. Its optimum synthesis technology conditions were as follows: feeding at batches while stirring tempestuously at 45℃, the ratio of nC8H17(EO4OH:n(P2O5)=2:1, esterifying at 70℃ for 4h, and add given volume of water at 70℃ for hydrolysing 2h.

研究五氧化磷的投料方式、反应物的用量比、反应温度和反应时间等因素对合成的异辛醇聚氧乙烯醚C8H17(EO4OH磷酸酯性能的影响,得到优化的异辛醇聚氧乙烯醚磷酸酯的合成工艺条件:在强烈搅拌下,分批投入P2O5,加料时的温度不超过45℃,nC8:H17(EO4OH:n(P2O5)=2:1,酯化温度为70℃,酯化时间为4h,在温度70℃时加入定量的水再水解2h。

The analysis methods for the determination of micro or trace elements in high moisture jellyfish were developed. The fatty acid compositions in difderent parts of fresh jellyfish were determined by GC/MS method. Thirty-five fatty acids were identified, and most of them were found in R. esculentum jellyfish for the first time. Especially, two unusual very long chain polyunsaturated fatty acids that were never detected in the other jellyfish also were determined. Amino acids were abundant in R. esculentum jellyfish, especially containing sulfur amino acids, and could be supplied for human diet. The polysaccharide in umbrella part of jellyfish was composed of glucose, galactose and uronic acid, and its molecular weight was 40,000, but the polysaccharide of the oral arms part consisted of glucose, mannose and glycuronic acid, and its molecular weight was 43,000. Above-mentioned data were never reported. The ethanolic extract of oral arms part of jellyfish were extracted by different polar solvents (petroleum ether, acetic ether, n-butanol), and antibacterial activity was tested to these extracts by four species of terricolous pathogenic bacilli and three species of botanic pathogenic fungi. The result demonstrated that the petroleum ether extract had certain bactericidal activity for two species of pathogenic bacilli, and n-butanol extract had certain inhibited activity on apple rot pathogenic fungus.

建立了 高含水量的海蜇产品中微量、痕量元素成分测定的分析方法;采用 GC/MS 方法测定了新鲜海蜇不同部位的脂肪酸组成,共鉴定出 35 种脂肪酸,其中大多数脂肪酸是首次在海蜇中被检测到,尤其是两种不常见的 C24:5 超长链多不饱和脂肪酸的分析和鉴定在其它水母种属中也从未见报道;海蜇三个部位中氨基酸成分齐全,含量丰富,含硫氨基酸含量较高,可与其它食物蛋白质的氨基酸互补;其中海蜇皮多糖是由葡萄糖、半乳糖和糖醛酸组成,分子量为 40,000,海蜇头多糖是由葡萄糖、甘露糖和糖醛酸组成,分子量为 43,000,以上工作均未见报道;利用石油醚、乙酸乙酯、正丁醇三种不同极性溶剂分别萃取海蜇头乙醇浸提物,用纸碟法和生长速率法分别对四株陆源病原菌和三株植物病原真菌进行了抑菌实验,结果表明海蜇头石油醚提取物和正丁醇提取物具有一定的抑菌活性。

The analysis methods for the determination of microor trace elements in high moisture jellyfish were developed. The fatty acid compositions indifderent parts of fresh jellyfish were determined by GC/MS method. Thirty-five fatty acids wereidentified, and most of them were found in R. esculentum jellyfish for the first time. Especially,two unusual very long chain polyunsaturated fatty acids that were never detected in the otherjellyfish also were determined. Amino acids were abundant in R. esculentum jellyfish, especiallycontaining sulfur amino acids, and could be supplied for human diet. The polysaccharide inumbrella part of jellyfish was composed of glucose, galactose and uronic acid, and its molecularweight was 40,000, but the polysaccharide of the oral arms part consisted of glucose, mannose andglycuronic acid, and its molecular weight was 43,000. Above-mentioned data were never reported.The ethanolic extract of oral arms part of jellyfish were extracted by different polar solvents(petroleum ether, acetic ether, n-butanol), and antibacterial activity was tested to these extracts byfour species of terricolous pathogenic bacilli and three species of botanic pathogenic fungi. Theresult demonstrated that the petroleum ether extract had certain bactericidal activity for twospecies of pathogenic bacilli, and n-butanol extract had certain inhibited activity on apple rotpathogenic fungus.

建立了高含水量的海蜇产品中微量、痕量元素成分测定的分析方法;采用 GC/MS 方法测定了新鲜海蜇不同部位的脂肪酸组成,共鉴定出 35 种脂肪酸,其中大多数脂肪酸是首次在海蜇中被检测到,尤其是两种不常见的 C24:5 超长链多不饱和脂肪酸的分析和鉴定在其它水母种属中也从未见报道;海蜇三个部位中氨基酸成分齐全,含量丰富,含硫氨基酸含量较高,可与其它食物蛋白质的氨基酸互补;其中海蜇皮多糖是由葡萄糖、半乳糖和糖醛酸组成,分子量为 40,000,海蜇头多糖是由葡萄糖、甘露糖和糖醛酸组成,分子量为 43,000,以上工作均未见报道;利用石油醚、乙酸乙酯、正丁醇三种不同极性溶剂分别萃取海蜇头乙醇浸提物,用纸碟法和生长速率法分别对四株陆源病原菌和三株植物病原真菌进行了抑菌实验,结果表明海蜇头石油醚提取物和正丁醇提取物具有一定的抑菌活性。

The Schiff base transitional metal complexes of various structures and their metallomicelles as peroxidase models for the phenol and phenolic derivant oxidation have been investigated. Some results are obtained from the studies:(1) the Schiff base transitional metal complexes have high catalytic activity for the phenol and phenolic derivant oxidation, and the structure of the complexes has a great effect on its catalytic activity;(2)a novel kinetic mathematical model for the complexes and their metallomicelles catalyzing the phenolic derivant oxidation has been established;(3) the feasibility and mechanism for the phenolic derivant oxidation catalyzed by the metallomicelle(as the mimetic model of peroxidase)have been discussed.

研究了冠醚Schiff碱金属配合物作为过氧化物酶的模拟模型对酚类物质氧化反应的催化作用,取得如下结果:(1)几种冠醚Schiff碱金属配合物对催化酚类物质氧化具有良好的催化活性,其中配体结构对其催化活性有较大的影响;(2)建立了金属配合物与表面活性剂形成的金属胶束催化酚类物质氧化反应的动力学数学模型;(3)探讨了金属胶束模拟过氧化物酶催化酚类氧化反应的可行性及其机理。

The formation of charge transfer complex was studied in the first part. The second part includes the synthesis and characterization of the acrylated unsaturated polyester and the kinetic studies on the Ar-UPE/ triethylene divinyl ether (DVE-3) photocuring system, the rheology and properties of film after photocuring. The third part includes the synthesis and characterization of the urethane modified unsaturated polyester and the kinetic studies on the PU-UPE/DVE-3 photocuring system, the rheology and properties of film after photocuring. The fourth part includes the synthesis and characterization of the vinyl ether end capped polyurethane and the kinetic studies on the VE-PU/DVE3 photocuring system, the rheology and properties of film after photocuring.

整个研究工作分为四个部分:一是电荷转移复合物的研究;二是丙烯酰氧基化不饱和聚酯的合成,表征,Ar-UPE/二缩乙二醇二乙烯基醚(DVE-3)体系光固化动力学研究以及Ar-UPE/DVE-3体系流变性能和光固化后涂膜综合性能的研究;三是氨酯改性的不饱和聚酯的合成,表征,PU-UPE/DVE-3体系光固化动力学研究以及该体系光固化后涂膜综合性能的研究;四是乙烯基醚封端的聚氨酯的合成,表征,VE-PU/马来酸二甲酯体系光固化动力学研究以及VE-PU/DMA体系流变性能和光固化后涂膜综合性能的研究。

The improved method of konjac glucomannan carboxy methylation was proposed in this paper according to the effects of deacetylation. Carboxymethyl KGM were synthesized by blending KGM with etherification agent first and then basifying and catalyzing in ethanol. Basifying first and then etherifying prepared traditional carboxymethyl KGM.

针对脱乙酰基的这种影响进行羧甲基化方法的改进,在乙醇介质中先混合醚化剂,再进行碱化催化反应制备羧甲基魔芋葡甘聚糖,并通过与传统的先碱化再醚化的KGM羧甲基改性方法比较,达到乙酰基脱出顺序上的不同。

The effects of the brominated flame retardants, especially PBDPO, on the environment and human's health are attracted more and more attention.

阐述了溴系阻燃剂,特别是多溴二苯醚对环境保护及人类健康的影响和危害,包括BFR从阻燃材料中的逸出、在环境中的滞留、在生物体内的积累、燃烧产物的毒性等有关问题,并介绍了有关十溴二苯醚应用前景的最新信息。

It could be observed that the [2] catenanes showed absorption maxima in 438. 0nm, 463. 0nm and 517. 0nm respectively, due to the interaction between calix [4] arenocrowns and the bipyridinium ring units.

另外,通过紫外-可见光谱,研究杯[4]并冠醚[2]索烃类化合物中的电子转移情况,发现组装后生成的杯[4]芳烃[2]索烃类化合物中,由于富电子的杯[4]芳烃冠醚和缺电子的联吡啶盐之间π-π堆积相互作用依次增强,它们分别在438.0nm,463.0nm,517.0nm的位置产生新的吸收峰。

The concents of testosterone and NO of the mouses gavaged with high dosages of Chinese chive extractiong were not significantly more than that of giving middle dosages.This indicated that Chinese chives might be more safe than traditional chinese herbals of sexual improvement function.2、The screening of sexual improvement function chemical substances of Chinese chivesThe crude extract was leached to four phases by petroleum ether, ethyl acetate,n-butanol and water.By doing animal tests to detect the contents of testosterone and NO in serum of mices,the result was showed that the extracts of petroleum ether and n-butanol have sexual improvement function,especial the n-butanol phase.

从小鼠灌喂不同剂量的韭菜提取液试验结果来(来源:ABCa539a5论文网www.abclunwen.com)看,灌胃高剂量的小鼠的睾酮含量和NO含量相对于中剂量来说并不上升,而是保持稳定,因为睾酮含量和NO含量过度上升可能会带来付作用,所以由此可以说明其食用安全性高,副作用小。2、韭菜改善性功能物质的筛选将韭菜粗提物依次通过不同溶剂萃取,分成石油醚、乙酸乙酯、正丁醇和水四个萃取相,通过小鼠灌胃的动物试验,以小鼠血液NO含量和睾酮含量为指标,发现正丁醇和石油醚萃取相中的物质有改善性功能的效果,尤其是正丁醇相效果非常显著。

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