醚的

To improve the cyano reactivity, cyano-terminated PPENs were prepared by the end-capping reaction of PPEN-OL with CBN; benzonitrile terminated polys were also prepared by the polycondensation of excess 4,4'-oxydianiline with 1,2-dihydro-2-(4-carboxyphenyl)-4-[4-(4-carboxyphenoxyl)phenyl]-phthalazinone, followed by end-capping with CBA. The polymers synthesized exhibited good solubility in NMP, DMAc and DMF, and were crosslinked to afford phenyl-s-triazine-containing polymers under the similar conditions.

为提高氰基活性，以对氯苯腈为原料，对PPEN-OL进行封端，设计合成了含氰端基的聚芳醚腈；以含二氮杂萘酮联苯结构二酸单体与4，4'-二氨基二苯醚为原料，经Yamazaki膦酰化缩聚，并用对氰基苯甲酸进行封端，合成了含氰端基的聚芳醚酰胺。

Two triphase catalysts of comb-like polyether s supported by silicas were synthesized,and their catalytic behavior in the iodo-substitution,etherization and the addition reaction of dichlorocarbene to styrene were also studied.

以表面经偶联剂修饰的二氧化硅为载体，通过聚(β-氯乙基缩水甘油醚)和醇钠反应，合成了两种梳状聚醚三相转移催化剂，研究了它们在碘代、二氯卡宾对双键加成和混合醚制备反应中的催化活性。

Rats were anesthetizedwith pentobarbital and then randomized into four groups: control,ISO-control (pretreatment with 30 min of 1.4% ISO), lipopolysaccharide(LPS; 10 mg/kg IV), and ISO-LPS.The mesentery was prepared for intravital videomicroscopy.

大鼠戊巴比妥麻醉后随机分为四组：对照组、异氟醚组（吸入1.4%的异氟醚30分钟）、脂多糖组（ LPS ；10mg/kg IV ）、 ISO-LPS 组（先吸入异氟醚后使用 LPS ）。

Crystallographic equivalence of ether and ketone group in the crystal structure of poly s was discussed again on the basis of the work reported in the literatures, which there were different viewpoints to.

对存有争议的聚芳醚酮晶体结构醚酮等效性问题进行了研究。首先设计并合成两种新型聚芳醚酮类聚合物PEDK与PEDEKDK，并对其晶体结构进行解析。

Goal compound synthesis namely: Take the vanillic acid as outset raw material, obtains 4- hydroxyl - 3- anisole methyl formate with the methyl alcohol reflux conditions, then after the etherification, the nitration, the return to original state, the ring closure response obtains 6- methoxy - 7- animal pen oxygen radical kui zuo lin - 4- alkone, then passes through the chlorination, the substitution aniline, to escape responses again and so on animal pen oxygen radical, etherification to obtain the goal compound; The goal compound and the diethylamine had the amine substitution reaction to obtain TM1, namely 4- benzene amino - 6- methoxy - 7- [2- hydroxyl - 3-(N, N- two ethyl aminos) third oxygen radical] kui zuo lin; Through zuo has the etherification with the Austria niter to respond obtains TM2, namely 4- benzene amino - 6- methoxy - 7- [2- hydroxyl - 3-(2- methyl - 5- nitryl imidazole) third oxygen radical] kui zuo lin.

目标化合物的合成即：以香草酸为起始原料，与甲醇回流条件下得到4-羟基-3-甲氧基苯甲酸甲酯，然后经过醚化、硝化、还原、环合反应得到6-甲氧基-7-苄氧基喹唑啉-4-酮，然后再经氯化、取代苯胺、脱苄氧基、醚化等反应得到目标化合物；目标化合物与二乙胺发生胺取代反应得到了TM1，即4-苯氨基-6-甲氧基-7-[2-羟基-3-丙氧基]喹唑啉；通过与奥硝唑发生醚化反应得到TM2，即4-苯氨基-6-甲氧基-7-[2-羟基-3-(2-甲基-5-硝基咪唑)丙氧基]喹唑啉。

The invention relates to polyimide molding powder with low melt viscosity and a preparation method, which uses 3,4'- diamino diphenyl ether, 3,3',4,4'-diphenyl ketone dicarboxylic anhydride, 3,3',4,4'-biphenyltetracarboxylic dianhydride, 3,3',4,4'- triphenyl diether dicarboxylic anhydride, 3,3',4,4'- diphenyl ether dicarboxylic anhydride and other monomers to polymerize at 100 to 140 DEG C, to get molding powder with a melt viscosity in the range of 1000Pa.s to 5000Pa.s.

本发明属于一种低熔体粘度聚酰亚胺模塑粉及制备方法，是采用3，4′-二氨基二苯醚同3，3′，4，4′-二苯酮四酸二酐、3，3′，4，4′-联苯四酸二酐、3，3′，4，4′-三苯二醚四酸二酐、3，3′，4，4′-二苯醚四酸二酐等单体在100～140℃聚合，获得熔体粘度在1000Pa.s～5000Pa.s范围内的模塑粉。

The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.

第二章 研究了二碘化钐、金属钐促进的有机反应：1、二碘化钐促进下α，β-炔基酮的偶联环化反应，提供了一种制备多取代环戊二烯的新方法；2、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮的Michael加成反应，为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法；3、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮和醛、酮的Michael—aldol串联反应，提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法；4、烯丙基溴化钐与α，β-炔基酮的高度区域选择性的1，2-亲核加成反应；5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。

The optimal conditions were obtained that isopropanol concentration 95% mass ratio of sodium hydroxide to soybean dietary fiber and monochloracetic acid 1.00:1.25:1.20, alkalization time 60 minutes, etherification temperature 70 degrees C, and etherification time 120~150 minutes.

以大豆膳食纤维为原料，一氯乙酸为醚化剂，异丙醇为溶剂，制备了羧甲基大豆膳食纤维，研究了异丙醇溶液质量分数、NaOH用量、MCA用量、碱化时间、醚化温度、醚化时间对产品羧甲基质量分数的影响。

We researched the high molecular polyether,polyamide hot melt adhesive, 2-phenoxy ethanol phenyl cellosolve,propylene glycol phenylate,etc,which have passed appraisal of the provincial science and technology achievement.the company gains higher economy profit after putting into production.

公司设有专业科研机构从事新产品的开发研制工作。先后研制开发成高分子聚醚，聚酰胺热熔胶，乙二醇苯醚，丙二醇苯醚等十多项新产品，均通过省级科技成果鉴定。

Two azobenzene-containing polyethers were synthesized and their thermotropic liquid crystalline properties were investigated.

氯乙基缩水甘油醚和GCE/羟丁基乙烯基醚分别通过阳离子聚合、光引发共聚合，获得两种聚醚，然后再分别与 4-硝基-4' -羟基偶氮苯反应，制备了两种侧链含偶氮苯生色团的液晶聚合物。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。