醚合物

The absorption spectra of the terpyridyl platinum acetylide complex containing monoazacrown moiety in the acetylide ligand was blue-shifted upon complexation with metal cations.

对位带有氮杂-15-冠-5冠醚的苯乙炔为辅助配体的三联吡啶Pt络合物TAC在金属离子的存在下吸收光谱的变化明显不同。

The energy of excited state depended on the nature of different cations. 3. 4-(4-tolyl)-6-phenyl-2, 2'-bipyridine platinum acetylide complex containing a monoazazcrown moiety in the acetylide ligand could signal Mg〓 specifically and displayed large changes both in color and in luminescence intensity upon complexation with Mg〓. The most striking result was that it could signal Mg〓 specifically even in the presence of alkali and alkaline earth metal ions in high concentrations.

对位带有氮杂-15-冠-5冠醚的苯乙炔为辅助配体的4-（4-甲基苯基）-6-苯基-2，2'-联吡啶Pt络合物AC，不仅在碱金属和碱土金属的存在下吸收光谱明显改变，更有意义的是，它只有在Mg〓离子存在时能够发光，因此可以通过发射光谱选择性的识别Mg〓，尤其可以在高浓度的其它金属离子存在下选择性的检出Mg〓离子。

The study of fluorescence spectrum proved that the excited phenylenerings of amorphous PES copolymer with high density phenylenerings in its main chain could form an excimer with the surrounding unexcited phenylenerings, and the emission peak intensity of excimer was strengthened with the increase of aging time.

荧光光谱的研究证明，非晶态聚醚砜共聚物由于主链苯环密度较高，苯环受激处于激发态时易与周围激态苯环相互作用形成激基缔合物，缔合物发射峰的强度随老化时间增加而增强。

The study of fluorescence spectrum proved that the excited phenylene-rings of amorphous PES copolymer with high density phenylene-rings in its main chain could form an excimer with the surrounding unexcited phenylene-rings, and the emission peak intensity of excimer was strengthened with the increase of aging time.

荧光光谱的研究证明，非晶态聚醚砜共聚物由于主链苯环密度较高，苯环受激处于激发态时易与周围激态苯环相互作用形成激基缔合物，缔合物发射峰的强度随老化时间增加而增强。

The yield was 84%. With OP-10, NPE as the the catalyzer for the diazo reaction, the use of hydrolyzed propenenitrile instead of propenoic acid, and OP-10 as the catalyzers of the aminate reaction, these experiments showed the feasibility of industralization, due to the much reduced costs, shortened reaction time and a higher yield.

采用壬基酚聚氧乙烯醚（OP-10）、萘磺酸甲醛缩合物作重氮化反应催化剂，丙烯腈加成、水解替代丙烯酸，OP-10做氨化反应催化剂，通过四因子三水平正交试验法实验，得到较佳反应参数，反应时间、收率、成本都大大降低，适宜工业化生产。

More than 75%of dodecene,decene,allylplenylether,phenylpropene(1.9×10－3mol) were completely hydrosilylated with 23.2 mg complex containing 4.9×10－6 mol platinum within 0.75 hour.

使用23.2 mg络合物(含4.9×10－6 mol Pt)为催化剂、分别使用1.9×10－3 mol 1－十二烯、癸烯、烯丙基苯基醚、苯丙烯进行硅氢加成反应，在0.75 h内产率超过75%。

The poisoning effects of alkyl sulfur compounds on the reactivity of isoprene hydrogenation over supported Pd catalyst are more and more serious with the decrease of the molecular mass of alkyl thiols and dialkyl disulfides.

乙硫醇和二甲基二硫醚使Pd／树脂催化剂中毒的机理是，它们分别在催化剂上发生SH和S-S键断裂，并与Pd形成带烷基基团的S-Pd吸附络合物，致使催化剂上异戊二烯选择加氢活性降低。

Herein, we synthesized six metalloporphyrins linked with stable nitroxyl radials, and evaluated their catalytic activity for the oxidation of glycosyl sulfides to glycosyl sulfoxides.

本论文设计、合成了6个连有稳定氮氧自由基的卟啉及其铁、锰的络合物，考察了它们对糖基硫苷等硫醚类化合物氧化成亚砜的催化性能。

It was found that manganese porphyrins linked with stable nitroxyl radials could oxidize sulfides using NaOCl as the oxidant to give the corresponding sulfoxides in good to excellent yields (80-97%) with high chemoselectivity and diasteroselectivity (dr≥7:1 for glycosyl sulfoxides).

发现连有稳定氮氧自由基的卟啉锰络合物对NaOCl选择性氧化各种硫醚底物有较好的催化效果，获得了高的产率(80％～97％)、化学选择性和非对映选择性(糖基亚砜非对映异构体的比例大于7：1)。

The photophysical properties of anthraquione crown ether and its 〓complex have been investigated.

研究了蒽醌冠醚及其铕离子络合物的光物理性质。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。