醚

Under the condition of 3 time mol equivalent magnesium,CuI 15mo1%, 45℃temperature and 10 hours reaction time, this preparation is notefficient to facilitate unsymmetry selenides.

我们选择溴苯与对溴甲苯在1倍镁量不同的催化剂的条件下反应，我们在光谱数据进行分析对比，可以看出只有溴基硒醚，并不能生成不对称有机硒醚。

Firstly, Vinyl ethers were prepared in a one-pot, two-step transformation by O-alkylation reaction of 2-hydroxyalkyl phenyl selenides with primary or secondary organic halides followed by oxidation-elimination with 30 % hydrogen peroxide.

1.2-羟基烷基苯基硒醚和伯、仲卤代烃通过O-烷基化反应，然后用30％的双氧水进行氧化消除反应，提供了&两步、一锅法&合成烯基醚的新方法，该方法反应条件温和，操作简便，产物收率中等到良好(70-85％)。

Selenium; Se Grignard Reagent; Organic selenides; symmetry selenides; unsymmetry selenides; synthesis

工程科技I，化学，有机化学硒；硒格氏试剂；有机硒化合物；对称硒醚；不对称硒醚；合成

In this dissertation, preparation of polysubstituted ethene and heterocyclic compounds based on 2-hydroxyalkyl phenyl selenides andα-phenylselenopropionic acid reagents were further investigated as follow: Firstly, O-ethyl-O-vinyl phosphonates were prepared in a one-pot, two-step transformation by Mitsunobu reaction of 2-hydroxyalkyl phenyl selenides with monoethyl esters of phosphonic acid in the presence of diethyl azodicarboxylate and triphenyl phosphine (PPh3) followed by oxidation-eliminatio...

中文摘要：本文主要进一步探索了2-羟基烷基苯基硒醚、α-苯硒基丙酸试剂在制备多取代乙烯和杂环化合物反应中的应用，具体研究内容和结果如下：一、在偶氮二羧酸乙酯和三苯膦(PPh3)存在下，苯基-2-羟基烷基硒醚和O-乙基膦酸单酯发生Mitsunobu反应，无需分离和纯化反应中间体，直接使用30 %的双氧水进行氧化-消除反应，提供了&两步、一锅&合成O-乙基-O-乙烯基膦酸酯的新方法，该方法反应条件温和，操作简便，产物收率良好(76-82 %)。

Chocolate brown fog corrosion inhibitor could be prepared by using of waste materials with organic amine being the main contents from production of pharmaceutical industry intermediate 1;8diazabicyclo\hendecene7,built with surfactant compound nonyl phenol polyoxyethylene ether and aliphatic alcohol polyoxyethylene ether.

利用制药工业中间体1，8-二氮杂二环[5，4，0]十一烯-7生产中的废料，与复合表面活性剂壬基酚聚氧乙烯醚、脂肪醇聚氧乙烯醚等，复配得到棕褐色缓蚀抑雾剂。

Propanediol phenyl ether was synthesized from phenol and propylene oxide in the presence of a series of solid-based catalysts derived from hydrotalcite-like compounds. The effects of the composition and structure of the catalysts, and the reaction conditions on the synthesis of propanediol phenyl ether were studied.

以不同类水滑石化合物为前驱体制得的复合氧化物作为合成丙二醇苯醚反应的固体碱催化剂，考察了催化剂组成、结构及反应条件对催化合成丙二醇苯醚反应的影响。

In the mixed solvent of dimethyl phthalate / TBP or phenyl ether / TBP, the selectivity for styrene oxide is good but the conversion of styrene is low due to the coordination to the catalyst of the solvent.

邻苯二甲酸二甲酯或二苯醚等与磷酸三丁酯的混合溶剂中环氧化的选择性较高，但由于溶剂对催化剂的配位作用抑制了催化剂的活性，苯乙烯转化率很低；当部分的邻苯二甲酸二甲酯或二苯醚被甲苯取代后，苯乙烯的转化率提高，生成环氧苯乙烷的选择性不变。

Company development and production of ethylene glycol phenyl ether and its acetate, propylene glycol phenyl ether and its acetate, low-foam wetting dispersant, silane coupling agent, solubilizer, emulsifier, such as series of many products, domestic innovative products, quality has been well-known shoulder to shoulder similar foreign products.

公司研制生产的乙二醇苯醚及其醋酸酯、丙二醇苯醚及其醋酸酯、低泡润湿分散剂、硅烷偶联剂、增溶剂、乳化剂等系列的许多产品，为国内独创产品，品质优良，已比肩国外同类知名产品。

In this thesis, this system is used for epoxidation of propylene and styrenewith good results. The solvent effect is investigated for epoxidation of styrene. In the mixedsolvent of dimethyl phthalate / TBP or phenyl ether / TBP, the selectivity for styreneoxide is good but the conversion of styrene is low due to the coordination to thecatalyst of the solvent. When part of dimethyl phthalate or phenyl ether is replacedby toluene, the conversion increases and the selectivity keeps constant.

邻苯二甲酸二甲酯或二苯醚等与磷酸三丁酯的混合溶剂中环氧化的选择性较高，但由于溶剂对催化剂的配位作用抑制了催化剂的活性，苯乙烯转化率很低；当部分的邻苯二甲酸二甲酯或二苯醚被甲苯取代后，苯乙烯的转化率提高，生成环氧苯乙烷的选择性不变。

A series of sulfonated poly(arylene thioether phosphine oxide)s with various degrees of sulfonation was prepared by polycondensation of 4,4'-thiobisbenzenethiol with the mixture of sBFPPO and BFPPO at different ratios. The effect of IEC on the properties of the products was studied.

以BFPPO、sBFPPO和4，4'-二巯基二苯硫醚为单体，通过改变BFPPO/sBFPPO的配比，合成了一系列不同磺化度的磺化聚芳硫醚三苯基氧膦，考察了IEC对产物性能的影响。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。