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The change on the spectra of the colored-form is alsohigher than that of the corresponding fulgide.

当冠与金属离子的匹配情况较好时,吸收光谱的蓝移更为显著,表现出冠所特有的选择性。

The electron donorability of the electron donor part of the fulgide decreases when cationcomplexes with crown ether, and the intromolecular charge transfereffect reduces.

金属离子较大的电荷密度以及金属离子与冠较好的匹配使冠俘精酸酐分子内的电荷转移更不易进行,造成了光谱较大的蓝移。

Chapter 2 has analysized the conversly synthetic means of solanesol and designed novelly synthetic routes of solanesol and key intermediate Chapter 3 has summarized the preparation of trans-3-methyl-4-hydroxy (bromo-2-butenyl oxy methyl benzene In chapter 4 ,a novel technology of important intermediate(all trans-8-bromo geranyl acetate),which is suitable for industrial procedure , was found .meanwhile,an another new way has been invented ,of which the key intermediate (all trans-8-hydroxy geranyl acetate) has been produced.

第二部分分析了茄尼醇的逆合成方法,设计了一条适合于合成茄尼醇的合成路线及其重要中间体的合成路线。第三部分研究了重要中间体[Trans-3-甲基-4-羟基-2-丁烯基乙酰基(苄基,2,3-二氢吡喃基)]的合成新方法,找到了一条适合于工业化生产的制备反式-3-甲基-4-羟基-2-丁烯基苄基的新方法。第四部分研究了重要中间体[-3,7-二甲基-8-羟基-2,6-辛二烯-1-醇乙酸酯、-3,7-二甲基-8-溴-2,6-辛二烯-1-醇乙酸酯]的合成新方法,找到了一条适合于工业化生产的制备它们的新方法;同时研究了一条制备-3,7-二甲基-8-羟基-2,6-辛二烯-1-醇乙酸酯的另一新方法。

The process of preparing NCAGE included the following steps: alkalization of the treated cellulose; etherification of the alkali cellulose; nitration of the water-soluble cellulose ether; and azidation of nitrocellulose glycidol ether.

利用高压蒸汽闪爆处理后的Novel纤维素为原料,经过碱化、化、硝化和叠氮化反应,得到了一种新型高能粘合剂——硝化纤维素叠氮甘油,并采用元素分析、DSC、FIT红外光谱和X-射线等对其含氮量、结构和性能进行了分析表征。

Based on the principle of ester hydrolyzation to ether in alkali condition, the process for preparation of dimethyl sulfide from sodium methyl sulfate residue was investigated.

根据酯在碱性条件下水解反应生成的原理,研究了以甲基硫酸钠废渣为原料制备二甲基硫的方法。

The concentration of liquid hydrocarbon B is 10%.the dosage of hydrophobe is 15%~20%. The condensation and used environment of defoaming agent were studied ,the experiments show that self-made defoamer can be the same with many bubbly systems,such as anion, zwitterions, Nonionic bubbly liquid et al.and it can be used from acidity to alkalescence conditions.the fitting dosage is 9‰~10‰to polyester,6‰to siloxane-polyester copolymer,and 3‰to mulriple defoamer.

对消泡剂的投加浓度、适用环境等作了相关应用研究,结论为:消泡剂适用的起泡体系较广,阴离子、两性离子、非离子型起泡液均可使用;适用PH值范围可从酸性至弱碱性,适宜加入量为(以占起泡体系的体积分数计):聚酯消泡剂9-10‰,有机硅改性聚酯消泡剂6‰,复配消泡剂3‰。

The formation mechanism for the C-PPV aggregation we proposed is: complex between K+ and the crown ether derivatives in the C-PPV brings two polymer chains closer together, and the K+ ions create interpolymer bridges, forming aggregations in the solution.

本文合成了可溶的带冠取代基的聚苯撑乙烯,其中冠基团的氧原子直接连在PPV主链上苯环的2、3位,并研究了聚合物在K~+存在下的自组装形成聚集体的行为。

With rapid development of internal fixator manufacture, materials for interspinous process device become increasing, such as bone allograft, titanium, poly (ether-ether-ketone) and lactoprene composite.

随着内固定器制作工艺的飞速发展,腰椎棘突间内固定器的材料构成范围也很广泛,包括同种异体骨移植物、钛、聚酮和人造橡胶复合物等。

We have developed a simple and easy-handling procedure for copper-catalyzed cyanation of aryl halides using K4[Fe_6] as the cyanide source. The present procedure has ligand- and base-free advantages, and was accomplished under the conditions of exposure to the air without degassing of the solvent.4. We carried out the selective control of preparation for phenyl ether and phenol from iodobenzene with 10 mol% of Cu_2·H_2O as the catalyst under the condition of exposure to air.

这个程序有无配体无碱的好处,并能够在暴露于空气的条件下进行,溶剂也不用脱气。4、空气气氛下,用10 mol%的Cu_2·H_2O催化碘苯偶联,实现了制备二苯和苯酚的选择性控制:即在有(来源:Aa955BC55论文网www.abclunwen.com)机溶剂NMP中实现了碘苯直接制备二苯的Ullmann反应,在H2O中实现了碘苯直接制备苯酚。

The rate of breath holding, laryngospasm, and desaturation wassimilar between those receiving desflurane versus sevoflurane.

憋气、喉痉挛或者氧饱和度下降的发生率在接受地氟与七氟对比的患者之间是相近的。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力