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醌基

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Molecular configurations in LB films undergo change from keto form to zwitterion assurface pressures increase,companied by intermolecular hydrogen bonds decreaseand intramolecular hydrogen bonds increase.

在LB膜中,随表面压增加,分子间氢键减少,分子内氢键增加,SBC18头基构型在转折区发生醌式→双性离子构型转变。

Rate constants of carbon dioxide radical anion〓 reacting with 5,5dimethyl-1-pyrroline-N-oxide、1-naphthoquinone and N,N,N,N-tetramethyl 1,4 -phenylene diamine were determined by detecting the changes of radical concentrations with time, and they were 5.5×10〓mol〓Ls〓、4.5×10〓mol〓Ls〓 and 6.7×10〓nol〓Ls〓 respectively.

测定了在含〓的CdS胶体体系中〓与5,5-二甲基-1-吡咯氮氧化物、1-萘醌和N,N,N,N-四甲基对苯二胺正离子自由基反应的速率常数,它们分别为5.5×10〓mol〓Ls〓、4.5×l0〓mol〓Ls〓和6.7×10〓mol〓Ls〓。

The results showed that the amorphous iron oxide has highly catalytic activity. The intermediate products are pyrocatechin, hydroquinone, benzoquinone and low-grade fatty acid. The mechanism of catalyst oxidation is assumed that the free radical OH attacks benzene cycle at the adjacent position and para-position of OH on phenol so that the benzene cycle is opened and low-grade fatty acid is produced and transformed into CO2 and H2O.

结果表明,非晶铁氧化物催化剂在催化氧化降解苯酚时具有较高的催化活性,苯酚降解的中间产物有:对苯二酚、邻苯二酚、苯醌和低级脂肪酸,其降解机理是羟基自由基攻击苯环上OH的部位或对位而使苯环开环,生成低级脂肪酸,并最终转化成二氧化碳和水,从而使苯酚得以降解。

Their infrared spectrum changes under UV-irradation and in the heating process have been monitored by ATR-FTIR. Then the aging mechanism has been induced by the infrared spectra before and after aging and their difference spectra. In the condition of UV-irradiation, the polyurethanes degrade to quinoid structures or azo-compounds, which is why polyurethanes' color can easily become yellow.

在紫外线照射下,聚氨酯类有机高分子涂料降解生成偶氮化合物或醌式结构,这也是聚氨酯老化颜色易变黄的原因;丙烯酸类有机高分子涂料降解机理为酯基断裂、形成稳定性较好的内酯,同时伴随侧链断裂的反应。

Vitamin E, or tocopherol, is a lipid-soluble antioxidant and essential for human health. 2-methyl-6-phytyl-1, 4-benzo- quinol methyltransferase, one of the key enzymes in vitamin biosynthetic pathway in plants, converts 2-methyl- 6-phytyl-1,4-benzoquinol to 2,3-dimethyl-6-phytyl-1,4-benzoquinol.

维生素E是一类人体必需的脂溶性抗氧化剂,具有重要的生理功能。2-甲基-6-叶绿基-1,4-苯醌甲基转移酶是天然维生素E合成途径中的关键酶之一,催化MPBQ甲基化,生成DMPBQ。

Methyl-6-phytyl-1, 4-benzo- quinol methyltransferase, one of the key enzymes in vitamin biosynthetic pathway in plants, converts 2-methyl- 6-phytyl-l,4-benzoquinol to 2,3-dimethyl-6-phytyl-l,4-benzoquinol.

甲基。6。叶绿基。1,4-苯醌甲基转移酶是天然维生素E合成途径中的关键酶之一,催化MPBQ甲基化,生成DMPBQ。

It was found that the substituent leads to thestructural changes of quinone,and then results in the charge distribution and dipolemoment changes.

研究结果表明,取代基导致醌的结构发生扭曲,并由此导致了电荷分布和偶极矩的变化。

The substituent effect on the structure andproperties of quinone were studied first.

首先用AM1方法研究了取代基对醌的结构及性质的影响。

Therate constant of the cross electron transfer reaction between neutral quinone andsuperoxide anion radical can be obtained with the same method.

其逆向电子转移反应,即中性醌与超氧阴离子自由基之间电子转移反应的速率常数可用类似方法得到。

More recently, lactoquinomycin has been shown to be a potent inhibitor of serine/threonine AKT kinases.

最近研究显示,乳醌霉素是一种丝氨酸/苏氨酸AKT激酶的有效抑制剂,它通过与AKT以及具有催化作用的T环上的关键性半胱氨酸残基不可逆的相互作用而发挥功能。

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