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A modified method of free radical alkylation has been using for synthesizing of quinone derivatives with an alkyl side chain variation.

应用经过改进的自由基烷基化新方法,合成了一系列的具有长侧链结构的苯醌类化合物。

The photoconductive properties of the pigments containing anthraquinone are studied in bilayer photoreceptor. A linear relationship between pigments that bear a substituent in the anilide ring in the coupler moiety and Hammett constant σ was obtained. Therefor, we conclude that electron-withdrawing groups enhances the sensitivity of these pigments.

对蒽醌系列偶氮染料光敏性的研究结果表明,偶合基酰胺芳环上的基团会影响其光敏性,并随吸电子性质的增强光敏性增加,首次揭示了其光敏性与Hammett常数σ间有良好线性关系的规律。

To observe the oxygen derived free radicals scavenging of diterpenoid tanshinones by pyrogallol autoxidation systems.

目的:探讨丹参二萜醌对邻苯三酚自氧化反应产生的氧自由基的作用。

The photo reactions of β-diketones compounds with chloranil in C6D6 were through free radical intermediates.

β二酮类化合物与四氯苯醌在C6D6溶液中的光化学反应过程具有自由基反应的特点。

The different substitutes had an effect on the main form of β-diketones, making the hydrogen donors to chloranil different correspondingly.

二酮类化合物中的不同取代基会影响其主要存在形式,因而使得四氯苯醌夺取氢的对象也有所不同。

1 At a reaction temperature of 100 ℃ and a reaction time of 30 min to give 2,which was then subjected to condensation reaction with p-propoxy mandelic acid in the presence of phosphoric acid at a molar ratio of m(2)∶m( p-propoxy mandelic acid )∶m=1∶1∶1 at a reaction temperature of 60 ℃ for 3 h to yield 3,which was further oxidized by chloranil to give t.

对现有分散红356合成工艺进行了优化,以n∶n=1.2∶1投料,100℃反应30 min得缩合物2,再在等质量磷酸催化下与分批加入的等质量对丙氧基扁桃酸60℃缩合3 h得缩合物3,经温和氧化剂四氯苯醌氧化得标题化合物,总收率55%。

In the process, chloranil firstly was excited to singlet state and then a labile hydrogen abstraction interaction between singlet chloranil andβ-diketones was involved to form singlet stable neutral radical pairs.

光照作用下,四氯苯醌首先跃迁至单线态,然后夺取β二酮类化合物分子中的活泼氢,形成单线态中性自由基对。

After culture in 2, 6-dimethoxyl pbenzoquinone for 24-26 h, the anterior part extended, formed the protuberance, then transformed into a root hair-like structure called primary haustorium.

用2,6二甲氧基-对苯醌培养肉苁蓉24-26小时后,其先端膨大并产生突起,形成类似根毛状的结构,即初生吸器。

DMBQ, resorcin, ferulic acid, and hydroxybenzoic acid were effective chemical signal substances in the inducement of haustorium, but the haustorium formation rate was only 3.3%.

适当浓度的2,6-二甲氧基对苯醌、间苯二酚、阿魏酸和对羟基苯甲酸均可诱导肉苁蓉种子萌发形成吸器,吸器形成率最高为3.3%。

The inhibition effect of 2,2,6,6-tetramethyl-4-hydroxylpiperidine-oxyl and some phenols and quinones on the AIBN initiated radical polymerization of styrene was studied by using dilatomitry method.

用膨胀计法,研究了2,2,6,6-四甲基-4-羟基哌啶氧自由基及一些醌、酚类化合物对偶氮二异丁腈引发的苯乙烯自由基聚合的阻聚效应。结果表明,当 St在80℃聚合时,加入TMHPO·或TMHPO·-BQ,阻聚效果较为显著。

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