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When anthrone react with aryl aldehyde in the presence of pyridine by using xylene as the solvent,besides 10 arylmethylene anthrone derivatives we found other oxygenated anthrone which have not been reported.

发现其生成物中除含有目标化合物 1 0 -芳香基甲叉基蒽酮外,还含有部分文献中没有报道的蒽酮氧化物,经物理方法确定其为蒽醌。

In p - benzoquinone solution with ethylene glycol as solvent,emission lines from PBQH'and R2 were obtained.

实验结果指出,在乙二醇溶液中得到苯半醌自由基和以碳为中心的自由基_2。

It was found that both the conversion and the initiating efficiency of methyl methacrylate polymerization system were decreased in the presence of small amounts of addition inhibitions 2,4,6-trinitrophenol or Benzoquinone, the system exhibited some retardation characteristics; at the same time, the molecular weights of obtained polymers was small and the molecular weight distributions was narrow, it was suggested that this polymerization system exhibited some ""living""/controlled radical polymerization characteristics.

发现在甲基丙烯酸甲酯的普通自由基聚合体系中加入少量的加成型阻聚剂2,4,6-三硝基苯酚或1,4-苯醌时,体系转化率降低,引发效率降低,呈现出一定的缓聚性质:同时得到的聚合物分子量变小,分子量分布变窄,具有一定的&活性&/可控的特征。

RESULTS: Sixteen compounds, ursolic acid (1), indole-3-carboxaldehyde (2), indole-3-carboxylic acid (3), p-coumaric acid (4), azelaic acid (5), N-trans-feruloyl tyramine (6), blumenol A (7), 2-hydroxy-3-methylanthraquinone (8), rubiadin l-methyl ether (9), rubiadin (10), quercetin (11), luteolin (12), chrysoeriol 6-C-β-boivinopyranosyl-7-O-β-glucopyranoside (13), alternanthin (14), stigmasta-5, 22-dien-3β-ol (15), and α-spinasterol (16) were obtained from the EtOAc extract of Alternanthera philoxeroides.

结果:得到并鉴定了16个化合物,分别为乌苏酸(1)、吲哚-3-甲醛(2)、吲哚-3-甲酸(3)、对-香豆酸(4)、壬二酸(5)、N-反式阿魏酰基酪胺(6)、布卢姆醇A(7)、2-羟基-3-甲基蒽醌(8)、甲基异茜草素-1-甲醚(9)、甲基异茜草素(10)、槲皮素(11)、木犀草素(12)、柯伊利素-6-C-β-波伊文糖基-7-O-β-吡喃葡萄糖苷(13)、莲子草素(14)、豆甾醇(15)和α-菠甾醇(16)。

With the aim of enhancing the nonlinear optical property of poly, poly[(thiophene-2,5-diyl)p-(N,N-dimethylamino) azobenzylidene] is prepared from 4-aldehyde-4'-dimethylamino azobenzene and thiophene through condensation polymerization reaction.

为了提高聚噻吩甲烯的非线性光学性能,通过4-醛基-4'-二甲胺基偶氮苯和噻吩的缩聚反应,合成了聚噻吩对二甲氨基偶氮苯甲烷,再用PTDMAAB与四氯苯醌发生脱氢反应合成了侧链含偶氮的聚噻吩甲烯。

Results:From the extraction of 95% in the green peel of Juglans Mandshurica,we got five compounds,which were respectively:β-sitosterol;juglone;3,5-dimethoxy-4-hydroxybenzoic acid;regiolon;succinic acid 4-oxyethyl-5-hydroxide-β-tetralone;...

结果:从核桃楸的乙醇提取物中分离鉴定了5个化合物,分别是:β-谷甾醇;胡桃醌;3, 5-二甲氧基-4-羟基苯甲酸;regiolon;琥珀酸;4-乙氧基-5-羟基-β-四氢萘酮;胡桃酮。结论:化合物Ⅲ、Ⅶ、Ⅵ为首次从核桃楸青皮中分离得到,Ⅶ、Ⅵ为新的天然化合物。

A second group includes those compositions, which include an organic polymeric binding material, eg, mixed cellulose esters of monobasic or dibasic acids such as cellulose acetate succinate; an addition-polymerizable ethylenically unsaturated compound, eg, vinylidene and vinyl monomers, preferably of the acrylic or alkacrylic ester type; eg, triethylene glycol diacrylate; and an addition-polymerization initiator which forms radicals under the influence of actinic radiation, eg, anthraquinone.

第二组包括那些作品,其中包括有机聚合物具有约束力的物质,例如,对一元或二元酸混合纤维素酯,如醋酸纤维素琥珀酸; 1此外,聚合ethylenically不饱和化合物,例如,偏和乙烯基单体,丙烯酸最好的或alkacrylic酯类型,如,三乙二醇二丙烯酸酯;和加成聚合引发剂的形式下光化辐射的影响自由基,例如,蒽醌。

The present doctoral dissertation was carried out to study the chemical constituents isolated from stems of two medicinal schisandraceous plants.34 compounds were isolated from the ethanol extracts of the stems S.henryi collected in the Jiangxi province by various column chromatographies.27 of them were identified on the basis of spectral analysis.There are 18 lignans,(including 5 dibenzocyclooctadienes,6 aryltetralins,2 tetrahydrofurans,3 diarylbutanes,2 other lignans),3 flavanols,2 glyceroesters,1 naphthoquinone,1 xanthine and 2 steroids,of which 6 compounds were new compounds,and 7 compounds were isolated from this family for the first time.

采用多种色谱技术进行分离纯化,从翼梗五味子藤茎的乙醇提取物中分离到34个化合物,综合运用现代波谱学技术鉴定了27个化合物,包括木脂素类化合物18个(其中联苯环辛烯类木脂素5个,芳基四氢萘类木脂素6个,四氢呋喃类木脂素2个,二芳基丁烷类3个,其他类型木脂素2个),黄烷醇类化合物3个,甘油酯类化合物2个,萘醌类化合物1个,黄嘌呤类化合物1个,甾体类化合物2个,其中,5个为新化合物,7个为本科首次报道。

Chloro-5,12-naphthacenequinone was synthesized from 2-(1-hydroxy-2-naphthyl)carbonylbenzoic acid by chlorination reaction using a mixture of phosphorus pentachloride and phosphorus oxychloride as a chlorating agent and then by ring-closing reaction using sulfuric acid as a dehydrating agent.

以2-[(1-羟基-2-萘基)羰基]苯甲酸为原料、五氯化磷/三氯氧磷为氯化剂进行氯化反应,然后用浓硫酸脱水环化,合成了6-氯-5,12-萘并萘醌,优化了反应条件,总收率达68.2%。

At the same time, adding thymoquinone to pancreatic cancer cells reduced the production and activity of enzymes called histone deacetylases, which remove the acetyl groups from the histone proteins, halting the gene transcription process.

同时,添加百里香醌到胰腺癌细胞能够减少细胞产物并且激活组蛋白脱乙酰基酶,这种酶将从组蛋白中移除乙酰基基团,从而阻止了基因的转录过程。

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