醋酐

The synthetic route of glycidyl nitrate was improved. Glycidol was synthesized by the cyclization process from allyl alcohol and m-CPBA, then glycidyl nitrate was synthesized with glycidol as raw materials and HNO3/ 2O as nitrating agent.

为了改进缩水甘油醚硝酸酯的合成路线，以丙烯醇为原料，经间氯过苯甲酸环氧化后得到缩水甘油醇，然后GA经硝酸／醋酐硝化后得到了GN，硝化产物GN的收率为70.2%，经过减压精馏后GN的纯度达到了98.9%。

Monochloroacetic acid is a rather important chemical raw material and organic intermediate product, which is mainly manufactured by chloride of acetic acid using sulfur and anhydride acetic acid as catalyst.

氯乙酸是一种及其重要的化工原料和有机中间体，目前氯乙酸主要以硫磺或醋酐为催化剂进行乙酸氯化生产而得。

The nitration of toluene was carried out in the presence of acetic anhydride with CCl4 as solvent, 95% nitric acid as nitrating reagent, and niobic acid calcinated at 300℃ for 3 h as catalyst for 60 min at 40℃.

实验结果表明，当反应温度为40℃，反应时间为60min时，以CCl4为溶剂，以质量分数为95%的硝酸为硝化剂，在醋酐存在条件下，以经300℃焙烧3h后的铌酸作为催化剂，甲苯硝化产物中异构体的邻对比达1.26，较硝硫混酸的1.67显著降低，产物得率达99.3%。

The results show high selectivity when the temperature is controlled at 50 CC , and the nitrated reaction time is 90 mm, toluene is nitrated by using 95% nitric acid as nitrating reagent at the presence of acetic anhydride, 1.0g silicotungstic acid catalyst is calcinated at 300℃ for 1.5h. The o/p (ratio of ortho to paro isomer of toluene nitration) ratio is 0.89 in product distribution of toluene nitration, lower than 1.67 using sulfonitric acid as catalyst. The yield of products is 91.6%.

结果表明，在醋酐存在条件下，以CCl4为溶剂，以质量分数为95%的硝酸为硝化剂，反应温度控制在50℃，反应60 min， 1.0g经300℃焙烧1.5h后的硅钨酸催化剂，对甲苯表现出强的区城选择性，甲苯硝化产物o/p值（甲苯硝化产物邻位和对位异构体的质量比）达0.89，较硝硫混酸的1.67显著降低，产物收率达到91.6%。

METHOD:Synthesis of paracetomol by hydrogenating and acetylating the p-nitrogenation at different conditions.

以对硝基酚和醋酐为原料，Pd-C或Pt-C作催化剂，加氢制备扑热息痛，优选反应条件。

Methods: 2ethyl aniline was used as starting material of the synthesis and was processed by acetic anhydride acylation, strong nitric acid nitraction at low temperature, and desacyl synthesis to produce 2ethyl5nitro aniline. The product was then synthesized to 3methyl6nitro1Hindazole by using ringclosing reaction in the presence of NaNO2, and then ethylated to obtain 2,3diethyl6 nitro2Hindazole. The latter compound was then reduced by SnCl2/Hcl to get target compound 2,3diethyl6nitro2Hindazole.

以2乙基苯胺为原料经醋酐酰化、浓硝酸低温硝化及去酰基保护合成2乙基5硝基苯胺，后用亚硝酸钠关环得3甲基6硝基1H吲唑，经硫酸二甲酯甲基化得2，3二甲基6硝基2H吲唑，最后用氯化亚锡将其还原得到目标产物，通过1H NMR确定结构与目标产物一致。

Methods: 2-ethyl aniline was used as starting material of the synthesis and was processed by acetic anhydride acylation, strong nitric acid nitraction at low temperature, and desacyl synthesis to produce 2-ethyl-5-nitro aniline. The product was then synthesized to 3-methyl-6-nitro-lH-indazole by using ring-closing reaction in the presence of NaNO2, and then ethylated to obtain 2, 3-diethyl-6- nitro-2H-indazole. The latter compound was then reduced by SnC12/Hcl to get target compound 2, 3-diethyl-6-nitro-2H-indazole.

以2-乙基苯胺为原料经醋酐酰化、浓硝酸低温硝化及去酰基保护合成2-乙基－5-硝基苯胺，后用亚硝酸钠关环得3-甲基－6-硝基－1H-吲唑，经硫酸二甲酯甲基化得2，3-二甲基－6-硝基－2H-吲唑，最后用氯化亚锡将其还原得到目标产物，通过1HNMR确定结构与目标产物一致。

The binding energies assigned to each of these peaks is in accordance with the accepted value for these functionalities [18,28]. The O–C_O high energy binding peak may include anhydrides, esters, and carboxylic acid groups, if present. The C1s spectrum of the 40W films could be fitted with a minimum of 5 peaks according to the above notations, as shown in Fig.

装订 被指定给每一个这些峰巅的能源是符合那为这些功能性〔18，28 的一般承认的价值。O－C_O 高的能源装订山顶可能包括醋酐，酯，和含有羧基的酸聚集，如果呈现。40W 的 C1s 光谱电影可能根据配备有 5 的最小量峰巅到那在记号法上面，如图 3 A 所示。

The polyesters are obtained by the polymerization of maleic anhydride and polyethylene glycols.

多元酯被 maleic 醋酐和聚乙烯乙二醇的聚合获得。

Several glycosyl phosphate and phosphonates, as inhibitors of AGPase, were synthesized.In the synthesis of β〓-6 linked oligosaccharide phosphonates, A new method was developedfor preparation of 〓,6-〓-di-acetyl-2,3,4-〓-tri-benzyl-D-hexoses by acetylation of benzylatedmethyl glycosides in high yield under the conditions of 〓 and cat.〓.

合成了一些磷酸酯及其类似物作为嗜热AGPase的抑制剂，在研究β 1-6连接的寡糖膦酸酯的合成中，发现了制备1，6-〓-二乙酰基-苄基保护糖的新方法：苄基保护的糖苷在醋酐和催化量的硫酸作用下，在0℃反应进行7-10 min，可以选择性、高收率地得到此化合物。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。