醇胺

Synthesis of fatty acid alkylolamide phosphate using cocoanut oil,methanol and monoethanolamide as material.

以椰子油、甲醇和单乙醇胺为原料合成椰子油脂肪酸烷醇酰胺，然后经磷酸化及中和反应制得椰子油脂肪酸烷醇酰胺磷酸酯盐。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明：1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体；2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明： 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体； 2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

LIN Hailin,CUI Yingde,DU Lin,CHEN JianpingInstitute of Applied Chemistry,Zhongkai University of Agriculture and TechnologySuper water absorbent resins P,SA/NaAA,SA/NaAA/PVA and SA/NaAA/AM were synthesized from sodium alginate,acrylic acid,polyvinyl alcoholand acrylamide,with N,N–methylenebisacrylamide as crosslinking agent,(NH4)2S2O8 - NaHSO3 as initiator,by means of aqueous solution polymerization.

以醚化海藻酸钠、聚乙烯醇、丙烯酰胺、丙烯酸为单体，N， N–亚甲基双丙烯酰胺为交联剂，过硫酸铵-亚硫酸氢钠为引发剂，采用水溶液法制备聚丙烯酸钠p吸水树脂和海藻酸钠/丙烯酸钠、海藻酸钠/丙烯酸钠/聚乙烯醇（SA/NaAA/PVA）及海藻酸钠/丙烯酸钠/丙烯酰胺吸水性复合树脂。

In this paper the emulsion of polyacrylamide was synthesized in the polyglycol solutions, acryl amide and acrylic acid sodium was used as the monomer. In more detail, we investigated the effect of the concentration of the monomers, the ratio of monomer and PEG, the ratio of monomers, temperature, and emulsifier on the stability of the HPAM emulsion and the molecular weight of the HPAM.

为了提高聚丙烯酰胺相对分子质量，以丙烯酰胺与丙烯酸钠为原料，在聚乙二醇水溶液中合成了聚丙烯酰胺水包水乳液，考察了初始单体质量分数、共聚单体与聚乙二醇摩尔比、共聚单体摩尔比、聚合反应温度、乳化剂种类及其浓度对HPAM水包水乳液稳定性及相对分子质量的影响，所得共聚产物相对分子质量可达1.5×10^7。

Water, Sodium Laureth Sulfate, Cocamidopropyl Betaine, Cocamide MEA, Disodium Cocamphodiacetate, Sodium Lauryl Sulfate, PEG 40 Hydrogenated Castor Oil, Perfume, Sodium Chloride, Propylene Glycol, Quaternium 80, Methylparaben, Polyquaternium 10, Hydroxypropyl Guar Hydroxpropyltrimonium Chloride, Citric Acid, Diazolidinyl Urea, Tetrasodium EDTA, Polyquaternium 7, Propylparaben, Sodium Hydroxide, Panthenol, Persea Gratissima Oil, Penta Sodium Pentetate, Hedera Helix Extract, Bambusa Vulgaris Extract

水，月桂醇聚醚硫酸酯钠，椰油酰胺丙基甜菜碱，椰油酰胺MEA，椰油酰两性基二乙酸二钠，月桂醇硫酸酯钠，PEG 40 氢化篦麻油，香料，氯化钠，丙二醇，季铵盐-80，苯甲酸甲脂，聚季铵盐-10，羟丙基瓜尔胶羟丙基三甲基氯化铵，柠檬酸，重氮烷基咪唑脲，乙二氨四醋酸四钠，聚季铵盐-7，对羟基苯甲酸丙酯，氢氧化钠，泛酰醇，酪梨油，喷替酸五钠，常春藤萃取物，银竹萃取物。

Ingredients: Water,Lauric Acid,Myristic Acid,Stearic Acid,Propylene Glocol,Potassium Hydroxide,Cocamidopropyl Betaine,Starch Hydroxypropyltrimnium Chloride,Sodium Laureth Sulfate,Glycol Distearate,Lavandula Angustifolia Oil,Creatine,Tetrasodium Edta,Perfume,Dmdm Hydantoin.

成分： 去离子水，月桂酸，肉豆蔻酸，硬脂酸，丙二醇，氢氧化钾，椰油酰胺丙基甜菜碱，淀粉羟丙基三甲基氯化铵，月桂醇聚醚硫酸钠，乙二醇双硬脂酸酯，薰衣草精油，肌酸，乙二胺四乙酸四钠，香精，DMDM 乙内酰脲。

Amino-monomethoxypoly(ethy1ene glycol)(mPEG-NH2) was synthesized based on the principle of Gabriel synthesis.Monomethoxypoly(ethy1ene glycol) tosylate was prepared at first,and then reaction with potassium salt of phthalimide as nucleophile to produce the monomethoxypoly(ethy1ene glycol)phthalimide derivative.

摘 要：首先合成了单甲氧基聚乙二醇对甲苯磺酸酯，然后根据盖布瑞尔合成法原理，以邻苯二甲酰亚胺钾盐为亲核试剂与mPEG-OTs反应，生成单甲氧基聚乙二醇的邻苯二甲酰亚胺衍生物，mPEG-PI与水合肼反应肼解生成伯胺，合成了一端为氨基的单甲氧基聚乙二醇(mPEG-NH2)。

The hydrophobic core serves as a reservoir for water-insoluble drugs.Hence,these nanoparticles can be used as carriers for hydrophobic drugs.For the synthesis of cholesterol-modified glycol chitosan conjugates,a carboxyl group was initially introduced to cholesterol molecule using succinic anhydride,and then covalently coupled with the primary amino group of glycol chitosan in the presence of 1-ethyl-3-(3-dimethylaminopropyl)-carbodiimide hydrochloride and N-hydroxyl succinimide.

本文采用二步反应将胆固醇接枝到乙二醇壳聚糖，首先将胆固醇进行羧基化，将胆固醇与琥珀酸酐反应生成胆固醇半琥珀酸酯，然后用1-乙基-3-(3-二甲基氨丙基)碳二亚胺盐酸盐与N-羟基琥珀酰亚胺作为偶联剂，将胆固醇半琥珀酸酯的羧基与乙二醇壳聚糖主链的氨基进行反应，得到胆固醇疏水改性乙二醇壳聚糖共聚物。

It was found that zymosterol in S. cerevisiae GL7 cells and cycloartenol in P. wickerhamii cells were accumulated when treated with solasodine. Zymosterol and cycloartenol are respective substrates of sterol 24Cmethyltransferase in S. cerevisiae GL7 and P. wickerhamii, hence we deduced that sterol C-24-methyltransferase is the main target of solasodine.

根据澳洲茄胺对S.cerevisiae GL7和P.wickerhamii的甾醇生物合成途径的抑制结果均积累24位甾醇甲基化转移酶的底物，分别是zymosterol和cycloartenol，初步阐明了澳洲茄胺的主要作用靶点是24位甾醇甲基化转移酶，而其它几种抗真菌生药活性成分不影响甾醇的生物合成途径。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。