醇基钠

At first,the intermediate of sodium 3-chloro-2-hydroxy propanesulfate was synthesized from epichlorohydrin and sodium bisulfite;And then,using NaOH as a catalyst,the title compound has been synthesized from intermediate and allyl alcohol to reach the yield of about 70%.

先由环氧氯丙烷和亚硫酸氢钠合成中间体3-氯-2-羟基丙磺酸钠，然后中间体再与丙烯醇在氢氧化钠催化下生成目标产物2-羟基-3-烯丙氧基丙磺酸钠。

PVC resin, PTFE resin, fumaric acid, anthraquinone, nitroanthraquinone, paraaminophenol, melamine, cyanuric acid, sulfanilic acid, chemical inhibitor 168, azoic coupling component As, stearate, aniline, nitroaniline, pentaerythritol, chlorcosane, sodium calcium, triethylene diamine, sodium benzene sulphinate, m-phthalic acid, thiourea, aniline black dyestuffs, acid dyestuff, etc.

聚氯乙烯树脂、聚四氟乙烯树脂、反丁烯二酸、蒽醌、硝基蒽醌、对氨基苯酚、三聚氰胺、氰尿酸、对氨基苯磺酸、抗氧剂168、色酚As、硬脂酸盐、苯胺、硝基苯胺、双季戊四醇、氯？？？腊、甲酸钙、三乙烯二胺、苯亚磺酸钠、间苯二甲酸、二甲酯五磺酸钠、硫脲、油溶性苯胺黑染料、酸性黑染料等有机化工原料和中间体。

Examples of humectants include lactic acid, urea (the urea found in creams is synthetically produced by combining one molecule of carbon dioxide with two molecules of ammonia and not obtained from urine), hyaluronic acid (able to retain 1000 times its weight of water), propylene glycol, glycerin, sorbitol, gelatin, lecithin, sodium pyrrolidone carboxylic acid, and butylene glycol.

常见的湿润剂有乳酸，尿素（面霜里的尿素来自于二氧化碳和氨分子的合成而不是从尿中提取的），透明质酸（能保持自身成分1000倍的水分），丙二醇，丙三醇，山梨糖醇，明胶，卵磷脂，吡咯钠，羧基酸和丁二醇。

Other Ingredients: Purified Soft Water, Green Tea Extract, Dimethicone, Sunflower Oil, Cyclomethicone, Stearyl Alcohol, Aloe Vera Gel, Deep Sea Algae Extract, Almond Oil, Glyceryl Tearate, PEG 100 Stearate, Polysorbate 20, Comfrey Extract, Jojoba Oil, Shea Butter, Kukui Nut Oil, Squalane, Glyceryl Caprylate/ Caprate, Caprylic / Capric Triglycerides, Panthenol (Vitamin B5), Babussu Oil, Marigold Extract, Camellia Kissi Oil, Cetyl Dimethicone, Carbomer, Beta Carotene, Ester-C,(Calcium, Sodium, Magnesium and Zinc Ascorbates, Ascorbyl Palmitate and L-Ascorbic Acid),Evening Primrose Oil, Methylparaben, Propylparaben, Triethanolamine, Phenoxyethenol, Imported Tropical Flower Oils.

其他成分：纯净水软，绿茶提取物，二甲基硅氧烷，葵花籽油，环，硬脂醇，芦荟凝胶，深海藻提取物，杏仁油，甘油Tearate，硬脂酸聚乙二醇100，吐温20，康弗里提取物，霍霍巴油，乳木果黄油，库奎坚果油，角鲨烷，甘油辛酸/癸酸，辛酸/癸三酸甘油脂，泛醇（维生素原B5），Babussu 油，金盏花精华，山茶花基西油，十六烷基二甲基硅氧烷，卡波姆，β胡萝卜素，酯- C中，（钙，钠，镁，锌Ascorbates，抗坏血酸棕榈酸酯和L -抗坏血酸），月见草油，甲酯，尼泊金丙酯，三乙醇胺，Phenoxyethenol，热带花卉进口油。

Secondly,a mixture of acetone and methyl formate was added into the methanol solution of sodium methoxide to prepare sodium formyl acetone by Claisen reaction.

以金属钠为原料，甲醇为溶剂，先制成甲醇钠的饱和甲醇溶液，再滴加丙酮和甲酸甲酯进行Claisen酯缩合制得丁酮烯醇钠，最后在强酸作用下与甲醇进行缩醛化反应合成了4，4-二甲氧基-2-丁酮，过程总收率达到73.1%，纯度98.7%。

A selective and mild PS-DIB/ionic-liquid immobilized 2, 2, 6, 6-tetramethyl-piperidin-4-ol-N-oxyl catalytic oxidation procedure of alcohols to the corresponding aldehydes and ketones in ionic liquid BF4 at room temperature was developed. The oxidant PS-DIB was prepared via the iodation and acetylation of polystyrene resin. For the preparation of the ionic-liquid immobilized TeMPO catalyst, 4-(2, 2, 6, 6-Tetramethyl-1-oxyl-4-piperidoxyl)butyl bromide was first synthesized from TeMPO and 1, 4-dibromobutane.

将聚苯乙烯树脂先碘化再乙酰基化，制得了负载型二乙酰氧碘苯作为氧化剂。2， 2， 6， 6-四甲基－N-氧自由基哌啶醇与1， 4-二溴丁烷反应生成4-溴丁氧基－2， 2， 6， 6-四甲基－哌啶－1-氧化物，再与N-甲基咪唑发生季铵化反应，生成的溴化季铵盐与四氟硼酸钠进行离子交换制得氟硼酸型2， 2， 6， 6-四甲基－N-氧自由基哌啶负载离子液体。

A selective and mild PS-DIB/ionic-liquid immobilized TEMPO catalytic oxidation procedure of alcohols to the corresponding aldehydes and ketones in ionic liquid BF4 at room temperature was developed. The oxidant PS-DIB was prepared via Iodation and acetylation of polystyrene resin. For the preparation of the ionic-liquid immobilized TEMPO catalyst, 4-(2,2,6,6-Tetramethyl-1-oxyl-4-piperidoxyl)butyl bromide was first synthesized from 2,2,6,6-tetramethyl-piperidin-4-ol-N-oxyl and 1,4-dibromobutane.

将聚苯乙烯树脂先碘化再乙酰基化，制得了负载型二乙酰氧碘苯(diacetoxyiodo polystyrene，PS-DIB)作为氧化剂。2，2，6，6-四甲基-N-氧自由基哌啶醇(2，2，6，6-tetramethyl-piperidin-4-ol-N-oxyl，TEMPO)与1，4-二溴丁烷反应生成4-溴丁氧基-2，2，6，6-四甲基-哌啶-1-氧化物，再与N-甲基咪唑发生季铵化反应，生成的溴化季铵盐与四氟硼酸钠进行离子交换制得氟硼酸型2，2，6，6-四甲基-N-氧自由基哌啶负载离子液体TEMPO-IL。

In this thesis, 1, 5-diaryl-3-pyrazilidinones, 1, 5-diaryl-3-hydroxypyrazoles and 3-(2, 3, 4, 6-tetraacetyl-β-D-glucopyranos-1-yl)-1, 5-diaryl-1H-pyrazoles are designed and synthesized.1, 5-diaryl-3-pyrzolidinones were obtained by condensation of 3-arylpropenates and phenylhydrazine or fluorophenylhydrazine under the catalysis of sodium methylate and the yields were about 55-80%.

在本文中，设计合成了1，5-二芳基-3-吡唑烷酮化合物、1，5-二芳基-3-吡唑烷酮化合物和3-(2，3，4，6-四乙酰基-β-D-吡喃葡萄糖-1-基)-1，5-二芳基吡唑化合物。以3-芳基-2-丙烯酸酯为原料，与芳基肼在醇钠的催化作用下，反应可以生成1，5-二芳基-3-吡唑烷酮，产率在55%以上。

Some research and analysis on the reaction of 2,4-difluoronitrobenzene and nucleophilic reagent alcohol sodium (methyl alcohol ,ethyl alcohol, propyl alcohol, n-butyl alcohol, t-butyl alcohol, et hl) and the reaction choice of opposite -F in different solvent and conditions have done in this paper.

论文以2，4-二氟硝基苯为主要原料，研究了其与亲核试剂醇钠(甲醇、乙醇、丙醇、正丁醇、叔丁醇等)在不同溶剂中的反应情况，讨论了在几种代表性的溶剂——醇、四氢呋喃、苯、N，N-二甲基甲酰胺中亲核取代反应的情况，研究了温度、反应时间、亲核试剂、溶剂等条件对亲核取代反应的影响。

The process comprises the subsequent steps a through e: a reacting phthalic anhydride with fluorobenzene or a derivative thereof in appropriate reaction conditions; b over reducing the product obtained in step a at the ketone moiety; c reducing the product obtained in step b with sodium dihydro-bis (2- 15 methoxyethoxy) aluminate to the corresponding alcohol ; d chlorinat ing the alcohol obtained in step c ; e inserting CO into the product obtained in step d through an appropriate Pd-containing catalytic system.

该方法包括以下步骤a～e：a使邻苯二甲酸酐与氟苯或者其衍生物在适当的反应条件中反应；b完全还原步骤a中获得的产品的酮部分；c用二氢-二(2-甲氧基乙氧基)铝酸钠将步骤b中获得的产品还原成相应的醇；d对步骤c中获得的醇进行氯化；e通过适当的含Pd的催化剂体系，将CO插入到步骤d中获得的产品中。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。