醇基

The results of AD reactions are as follows:(1) When the AD reaction of eight olefins was performed at 0.5mo1% OsO〓 and 2mol% ligand 8 in PEG/NMO system, the diols were obtained in 78～90% yields and 78～96% ees (except for trans-5-decene and ally naphthyl ether).

催化结果如下：(1)在PEG/NMO体系中，将配体8用于八种烯烃的AD反应，配体、OsO〓和底物的摩尔比为0.02/0.005/1时，化学产率为78～90％，除反式-5-癸烯和萘基烯丙基醚较低外，其它六种烯烃的相应二醇产物的ee值为78～96％。

Isopentanol, nitrochlorobenzene, nitrotoluene and diethylbenzene were well separated in the range of optimal carrier gas velocity of 13~17cm/s.

SE-30系列毛细管色谱柱的最佳载气线这范因为13~17cm/s，且在最佳线速度下很好地分离了异戊醇、硝基氯苯、硝基甲苯及二乙苯同分异构体体系。

In addition, the invention further relates to a catalyzer combination used for polymerizing a conjugated dialkene monomer and the anions of an optional mono-vinyl aromatic hydrocarbon into a polydiene polymer having high and medium vinyl content. The catalyzer combination comprises an organolithium compound used as an anionic polymerization initiator, at least an alkali metal alkoxide compound expressed by the formula as a structure regulator.

此外，本发明还涉及一种用于将共轭二烯烃单体和任选的单乙烯基芳烃阴离子聚合成具有中高乙烯基含量的聚二烯聚合物的催化剂组合物，其包含作为阴离子聚合引发剂的有机锂化合物，和作为结构调节剂的至少一种式所示的碱金属醇盐化合物。

The intermediate which obtained from oximation of 7a-e reacted withmethyl N-(2-bromomethylphenyl)-N-methoxycarbamate to synthesize oxime ether methyl carbamate 3a-e.

以邻位卤代苯甲醛和3-丁烯-2-醇为原料通过钯催化&一锅法&反应合成了2-乙酰基茚7a-e，7a-e 肟化之后和N-(2-溴甲基苯基)-N-甲氧基氨基甲酸甲酯反应合成了肟醚类氨基甲酸甲酯3a-e，进一步胺解之后得到了肟醚类氨基甲酰甲胺3f-j。

Promoted by metal dysprosium, aldehydes and ketones could react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohols in good to excellent yields, and no allenic alcohol s were found.

当用苯基炔丙基溴代替炔丙基溴与醛、酮反应时，主要得到了相应的连二烯醇，而没有发现高快丙醇的存在，由此提出了六元环过渡态的反应机理

And the corresponding chiral tertiary propargylic alcohols were obtained with enantiomeric excesses of up to 86%, which provided a simple, practical and inexpensive method to generate chiral tertiary propargylic alcohols.

经过筛选、测试，发现一β-磺酰胺基醇-钛复合物可在温和条件下，有效促进炔基锌对简单非活化酮的不对称加成，并且得到相应的手性三级炔丙醇，ee值达到了86%。

The cis-decalin 79 was obtained from 2-methoxy-4-methylphenol (77) via a sequence of reactions involving intermolecular Diels-Alder reaction of masked o-benzoquinone derived from 77 and ethyl vinyl ketone, silyl enol ether formation and Cope rearrangement.

第一部份：以2-甲氧基-4-甲基酚(77)为起始物，经由二乙醯基亚碘苯氧化、分子间Diels-Alder反应、烯醇矽醚的形成及Cope重排反应得到具有十氢萘骨架化合物79。

A C-C bond type radical initiator i.e. 1,1,2,2-tetraphenyl-1,2-ethanediol and a S-S bond type thermal iniferter, i.e., tetraethyl thiuram disulfide were used to consist of new reverse ATRP initiation systems TPED/FeCl3/PPh3 and TD/FeCl3/PPh3, respectively."Living"/controlled polymerizations of a polar monomer MMA and a non-polar monomer St were investigated with the initiation systems as well as other new initiation systems; behavior of vinyl polymerization with a new asymmetrical C-C bond type thermal monomeric iniferter was studied also.

前者选用C-C键型的自由基聚合引发剂1，1，2，2-四苯基-1，2-乙二醇、S-S键型的热iniferter二硫化四乙基秋兰姆组成新引发体系TPED/FeCl3/PPh3、TD/FeCl3/PPh3，研究这些引发体系引发MMA、 St聚合的&活性&/控制聚合行为，同时研究一些其他新引发体系；后者合成了一种新的非对称C-C键型热引发转移终止剂，并研究其自由基聚合规律。

Using 1,4-dibromobenzene,1,3,5-tribromobenzene and 2-methyl-3-butyn-2-ol as starting materials and PdCl2,triphenylphosphine,CuI and KOH as catalysts,1-bromo-4-ethynylbenzene,1,4-diethynylbenzene and 1,3,5-triethynylbenzene were synthesized by Sonogashina coupling reaction and elimination reaction.

以对二溴苯、1，3，5-三溴苯和2-甲基-3-丁炔-2-醇为原料，在PdC l2、PPh3和CuI的催化作用下进行Sonogash ina偶联反应，偶联产物在KOH作用下发生消去反应，分别得到对溴苯乙炔、对二乙炔基苯、1，3，5-三乙炔基苯。

A readily available β-sulfonamide alcohol-titanium complex was found to be effective on promoting the asymmetric addition reaction of an alkynylzinc reagent to unactivated simple ketones under very mild conditions.

为此我们合成了一系列β-磺酰胺基醇，并将其作为配体与Ti4一起催化炔基锌对简单非活化酮的不对称加成反应。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。