醇基

In particular, when the Knoevenagel condensation of 2-hydroxybenzaldehyde was conducted with ethyl 2-cyanoacetate, 3-ethoxycarbonylcoumarin was obtained by simultaneous cyclization and alcoholysis of cyanide.

当反应底物为水杨醛与氰基乙酸乙酯的时候，产物为3-乙氧基羰基香豆素，这是水杨醛和氰基乙酸乙酯缩合关环，再发生氰基醇解的产物。

When the sodium lauryl sulfate and p-octyl polyethylene glycol phenyl ether is used and its level in 3% and 6: 4 ratio, the polymerization process has the lowest coagulum and the highest monomer conversion. Higher reaction temperature and more level hydroxyl value lead to more coagulum, the latter also lead to larger particle size. The acid value has larger influence on viscosity and coagulum, there exist a best range. The emulsion particle size is larger for its hydrophilicity, most of its particles are connected together.

在含较高亲水单体的乳液聚合体系中，难以制得稳定的预乳化液，不能采用工业生产中常用的预乳化工艺，而只能采用混合单体直接滴加的方法；由于单体混合物的亲水亲油值较高，用阴离子型乳化剂十二烷基硫酸钠和非离子型乳化剂聚乙二醇辛基苯基醚混合，用量为单体总量的3％，且比例在6：4时，乳液聚合时具有最低的凝聚物含量和最高的单体转化率；乳液聚合反应温度升高，可以提高单体转化率，增加反应速度，但凝聚率相应提高；随着羟基单体含量的增加，聚合过程中凝聚率增加，聚合物乳胶粒平均直径增加；羧基单体有一个最佳的用量（2.6％），过高或过低凝聚率均提高；羧基含量对乳液的粘度有较大的影响，当羧基含量较低时，羧基含量增加，乳液粘度增加明显；含羟基乳液粒子由于含亲水基团较多，使得乳胶粒径增大，乳胶粒子大多数互相凝聚在一起，处于凝聚态。

Firstly, 3-ethylthiobutanal was prepared from crotonaldehyde reacting with ethanehiol in triethylamine with high yield. Secondly, methyl acetoacetate was converted to 6-ethylthiohept-3-en-2-one by three steps via hydrolysis, condensation with 3-ethyltio-butanal and dehydration, then 6-ethylthiohept-3-en-2-one was cycloco ndensed with dimethyl malonate by Michael addition and Claisen condensation, followed by saponification and decarboxylation to give the intermediate of 5-(2-ethylthiopropyl)-cyclohexane-1,3-dione.

首先，以巴豆醛与乙硫醇为原料，在三乙胺的催化作用下高收率制得3-乙硫基丁醛；然后从乙酰乙酸甲酯出发，通过碱水解、与3-乙硫基丁醛缩合、脱水三步反应合成6-乙硫基-3-烯-2-庚酮，接着6-乙硫基-3-烯-2-庚酮与丙二酸二甲酯通过Michael加成和Claisen缩合成环，再通过皂化和脱羧反应生成中间体5-[2-丙基]-1，3-环己二酮；再与丙酸酐反应丙酰化，最后与0-3-氯-2-丙烯基羟胺肟化，得到目标化合物烯草酮。

Two kinds of new intermolecular complex antioxidants 3-(3, 5-di-butyl-4-hydroxyphenyl) propionyl pentaerythritol phosphate and octstearic pentaerythritol tetra- phosphite were synthesized by one-pot and two steps transesterification.

分别采用一锅法和两步酯交换法合成了两种新型分子内复合型抗氧剂，即3-(3，5-二叔丁基-4-羟基苯基)丙酰亚磷酸季戊四醇酯和八硬脂基季戊四醇四亚磷酸酯。

Results The mixing, loading and storing processes of the construction, might generate lots of occupational hazards, including toluene, dimethylbenzene, trimethylbenzene, isopropanol, butyl alcohol, propanol, methyl methacrylate, butyl acetate, methyl isobutyl ketone, methyl ethyl ketone, acetic ether, nitro-cotton, n-hexane, n-heptane, carbinol, ethanol, ethyl propionate, diisobutyl ketone, glycol ether, isoamyl acetate, 2,4-toluene diisocyanate, isophorone, noise, power frequency electric fields.

结果 该项目在混兑生产和装卸、仓储过程中，可能产生的职业病危害因素主要有甲苯、二甲苯、三甲苯、异丙醇、丁醇、丙醇、甲基丙烯酸甲酯、乙酸丁酯、甲基异丁基甲酮、丁酮、乙酸乙酯、硝化棉、正己烷、正庚烷、甲醇、乙醇、乙酸丙酯、二异丁基甲酮、乙二醇乙醚、乙酸异戊酯、2，4甲苯二异氰酸酯、异佛尔酮、噪声、工频电场。

As CAAX-mimetics, 1, 3-dihydro-5-phenyl-2-H-1, 4-benzodiazepin-2-one was modified by linking carboxyl groups with various carbon through N-1 and C-3, 3-(imidazol-4-yl) propion amido group with different substituents was connected at C-7; In the synthesis of bisubstrate analogues, thiocarbamido compounds was alkylated by alkyl iodide and then hydrolyzed to give alkylthiol benzoate compounds.

1，4-苯并二氮杂草-2-酮类化合物的合成过程中分别对其1、3、4和7位进行了基团变化，在1和3位连接不同长度含羧基或酯基的侧链，在7位连接不同取代的咪唑丙酰氨基。在苯甲酸硫醇酯化合物合成过程中，建立了一种硫原子连有不同长度碳链的苯甲酸硫醇酯的合成方法。

Bis (2,4-di-tert-butyl-phenyl) pentaerythritol diphosphite (antioxidant 626) was synthesized with pentaerythritol, di-tert-butylphenol and phosphorus trichloride.

以季戊四醇、三氯化磷和2，4-二叔丁基苯酚为原料，在实验室合成了双（2，4-二叔丁基苯基）季戊四醇二亚磷酸酯。

Composition of low molecular weight glutenin subunits and gliadins were investigated with thirty common wheat cultivars which are widely grown in Shangdong province. In our study we used acid polyacrylamide gel electrophoresis and SDS-polyacrylamide gel electrophoresis, analysed Sedimentation test, Protein content, Mixing time, Stability, Max-resistance to extension, Farinograph Quality Number and Extensogram area of the 30 common wheats. They have close relationship with the technology properties of noodle wheat cultivars.

本研究通过酸性聚丙烯酰胺凝胶电泳和SDS-聚丙烯酰胺凝胶电泳，分析了30个山东省种植面积较大且具有部分代表性的普通小麦品种的低分子量麦谷蛋白亚基和醇溶蛋白组成，测定了30个品种的蛋白质含量、沉淀值、面团形成时间、稳定性、粉质评价值、最大拉伸阻力和拉伸曲线面积等面粉及面团主要品质性状，分析了低分子量谷蛋白亚基和醇溶蛋白组成与面条小麦品质性状的关系。

Keywords alkyd modified t-octylphenolic resin;pentaerythritol;linseed oil;rosin;octylphenolic resin;rotary printing ink

醇酸改性辛基酚醛树脂；季戊四醇；亚麻油；松香；辛基酚醛树脂；轮转油墨

However, the rhodium process with oil compounds encounter problems due to the thermal sensitivity of the high boiling point oxo-products, which cannot be isolated from the homogeneous reaction mixture by distillation.

采用~1H-NMR和FT-IR谱分析了油醇的氢甲酰化反应产物，证实了其结构为甲酰基十八碳醇，且甲酰基的位置可以在主碳链的中间或端位。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。