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Apparent partition coefficient in octanol-water and binding percentage to BSA of ~(153)Sm-NTMP,~(153)Sm-HEDTMP,~(153)Sm-DCTMP,~(153)Sm-EDTMP,~(153)Sm-DTPMP,~(113,117) Sn~m-EDTMP,~(113,117) Sn~m-HEDTMP,~(113,117) Sn~m-DTPMP are measured. The results show that there is a linear relationship between the relative magnitude of the apparent partition coefficient in octanol-watetr and the relative magnitude of the binding percentage to BSA of these ~(153)Sm~(113,117Sn~m complexes.

测定了NTMP,HEDTMPN (羟乙基乙二胺基三亚甲基膦酸,DCTMP(1,2 环己二胺四亚甲基膦酸),EDTMP(乙基二胺基四亚甲基膦酸),DTPMP(二乙基三胺基五亚甲基膦酸)的153Sm配合物以及HEDTMP,EDTMP,DTPMP的113,117Snm配合物在正辛醇水中的表观脂水分配系数和在0 5%牛血清白蛋白水溶液中与BSA的结合率。

An experiment was conducted to study the antifeeding effects of ethanol, ethyl acetate and water solutions of linoleic acid, pimelic acid, suberic acid, azelaic acid, and n-nonanoic acid against imago of Pissodes punctatus. Absolute antifeeding rate and relative antifeeding rate were used to appraise the antifeeding effects of organic acids.

为了寻找华山松木蠹象(Pissodes punctatus Langor et Zhang)环境友好的防治方法,研究了亚油酸、庚二酸、辛二酸、壬二酸、壬酸的酒精溶液、乙酸乙酯溶液和水溶液对华山松木蠹象成虫的拒食作用,采用了完全拒食虫率与相对拒食率来评价有机酸的拒食效果。

The Density Function Theorymethod are employed to study the geometries of the cyanic acid and isocyanic acid on the base of B3LYP/6-31++Gin the paper.

主要采用密度泛函理论方法,在B3LYP/6-31++G水平上,优化了氰酸、异氰酸的结构,分别得到氰酸的能量为-168.69356 a.u,异氰酸的能量为-168.73227 a.u,并对过渡态进行了反应的内禀反应曲线IRC计算。

The Density Function Theorymethod are employed to study the geometries of the cyanic acid and iso cyanic acid on the base of B3LYP/6-31+Gin the paper.

本文主要采用密度泛函理论方法,在 B3LYP/6-31+G基础上,通过优化氰酸、异氰酸的结构,分别得到的能量为-168.64128a.u 的氰酸和能量为-168.68027a.u 的异氰酸。

Catalytic Synthesis of Methyl Furoate by Peroxhydrogen and Sulphate Acid;2. Using hydrochloric acid as a cheap catalyst,perfume methyl furoate was synthesized from methanol and furoic acid prepared from furfural,and was characterized by GC,IR and 1H-NMR.

从糠醛出发,由制备的糠酸和甲醇反应,在盐酸催化下,合成了香料糠酸甲酯,并用IR、1HNMR、GC等进行了表征;探讨了包括高纯度糠酸的制备在内的反应影响因素,在醇酸物质的量之比为 5∶1、催化剂体积占甲醇体积 13。

And humic substance (fulvic acids, humic acids and humin). The features of fulvic acids of humic substance at the southwestern part of Turfan-Hami basin are: the content of C is low, and the content of H, S, O is relatively high, atomic number of C/H is low.

研究证实吐哈盆地腐殖质中黄腐酸的特点是C含量较低,H、S、O含量偏高,C/H原子数比较低;官能团分析证实黄腐酸的总酸基、羧基、酚羟基含量较高,反映出黄腐酸具有较高的活性。

The results show that the optimum conditions are: the mole ratio of malonic acid to benzaldehyde 1.0:0.9, the dosage of proline 4.0% of the weight of malonic acid and the reaction time 4h, the yield of cinuamic acid is 99.0% under the optimum conditions.

实验结果表明,合成肉桂酸的最合适条件:原料比为1.0:0.9,L-脯氨酸用量为丙二酸质量的4.0%,反应时间4h,在此最佳条件下,肉桂酸的收率达到99.0%。

By the polycondensation of amino acid 5-fluorouracil -1, 3-dipropyl esters with bis (2-chloroethyl) phos- phoramidic dichloride in the presence of 〓 or in vacuo, ten new polymers containing 5- fluorouracil, nitrogen mustard and amino acid were synthesized.

将1,3-双-5-氟尿嘧啶与二氯膦甲酸乙酯或二氯膦乙酸乙酯在DMF中反应制备得到20个三元共聚物,体外抗肿瘤试验表明:含有甘氨酸、缬氨酸、苯丙氨酸和酪氨酸的聚合加显示了一定的选择性,并且分析讨论了生物活性与结构之间的关系。

The stimu- lating effect of glycine on nitrate reduction was greatly influenced by preillumination treat- ment of tobacco leaves,and also by the activity of respiratory chain.

但乙醇酸脱氢酶主要存在于低等植物如藻类巾;在高等植物中,乙醇酸的氧化主要是由乙醇酸氧化酶催化的,形成乙醛酸和H言02,但没有还原剂的生成L19,。

To carry out statically corrading experiments of the naphthenic acid to Q235-A specimen; and to analyse its' dynamic mechanism at this reaction condition. The adsorption-corrosion isothermal line of the naphthenic acid has been obtained.

以易腐蚀设备的Q235-A钢材为研究对象进行环烷酸的静态腐蚀试验,对该条件下环烷酸腐蚀动力学作用机理进行了分析,得出环烷酸腐蚀的温度和酸值关系式。

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