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L-aspartic acid s are intercalated into magnesium aluminum layered double hydroxidesby using the methods of reprecipitation and coprecipitation.

以镁铝水滑石为插层主体、L-天冬酸离子为插层客体,分别用返混沉淀法和共沉淀法制备了 L-天冬酸根插层镁铝水滑石手性层柱材料,并用 FT-IR、XRD 和 DTA 对其结构进行了表征。

The treatment process of liquid waste in synthesis of cuprous thiocyanate by use of sulfocyanide ion existed in the liquid waste of potassium rhodanate was investigated.

硫氰酸实验研究了利用硫氰酸钾生产废液中的硫氰酸根制备硫氰酸亚铜过程中合成废液及洗涤废水无害化处理技术。

The reaction mechanism was discussed in view of both AC impedance and IR spectroscopic techniques.

因此,对硫氰酸根离子的测定和监控非常重要。

The anodic behavior of electrolytic nickel anode in nickel sulfamate plating Solution was investigated,using anodic polarization curves,metallographic observation of cross-sections of nickel deposits,Hull Cell tests with solutions with and without Cl-,F-,bending tests with five solutions of different compositions,and sulfur content analysis in nickel deposit with mass spectrometry.

采用极化曲线、金相观察、赫尔槽电镀试验、弯曲试验和质谱分析方法,研究了氨基磺酸盐镀镍的阳极行为,证明了当在氨基磺酸盐镀液中使用电解镍阳极时,其活化峰值电流和镀液组成有很大的相关性,当镀液中不含F-和Cl-时其阳极活化峰值电流小,阳极处于极化状态,或相当大面积处于极化状态,使氨基磺酸根在极化的阳极表面氧化,从而使含硫化合物夹附于镀镍层,形成镀层内应力,并使镀层成为层状结构,并出现半光亮的外观。

Sulfonic group is ionizated completely in AB-I to keep stable concentration difference inside and outside.

吸水凝胶的体积相变与弱酸根的电离程度关系密切。

Using the crystal structure of CDK2 complexed with indirubin-5- sulphonate as the template, models of CDK4 complexed with indirubin and its analogue were built by homology modeling and molecular docking.

以获得晶体结构的CDK2与5-磺酸根-靛玉红的复合物为模板,通过同源模建和分子对接的方法构建出的CDK4与靛玉红及其衍生物的结合模式。

Two organosulfonate complexes, [M22]·H2O (M=Cd 1, M=Pb 2), were obtained from the reaction of 1,10-phenanthroline, sodium 4-aminonaphthalene-1-sulfonate tetrahydrate and Cd2·2H2O or Pb (NO3)2 in a mixed solvent of water and methanol at 25 ℃. The compounds were characterized by elemental analysis, IR, and X-ray diffraction single crystal structure analyses.

合成了2个新型有机磺酸配合物,[Cd22]·H2O(1)和[Pb22]·H2O(2)(phen=1,10-邻菲咯啉,ans=4-氨基-1-萘磺酸根),通过元素分析、红外光谱等对配合物进了表征,用X-射线单晶衍射方法测定了配合物的单晶结构。

In order to get the information of interaction between metal complex and DNA and select metal complexes which can cleave DNA effectively, twenty seven transition metal complexes containing O/N coordinate atoms have been synthesized in this thesis. We report the synthesis, crystal structure and properties of the complexes. One of the complexes is the first μ〓-oxalato tetranuclear Cu complex, in which there is ferromagnetic interaction between the copper atoms bridged by oxalate ions. Two trinuclear copper complexes containing partial cubane Cu〓O〓 cores have been synthesized and discussed the magnetic properties.

为了解金属配合物与DNA的相互作用及筛选能有效切割DNA的金属配合物,为无机药物合成及应用提供基础信息,本文利用十个含N、O原子的多齿配体设计合成了二十七个未见文献报道的过渡金属配合物,并解析了它们的晶体结构:其中包括首例μ〓-草酸根的四核铜配合物;合成了两个具有μ〓-OH〓三核缺角立方烷结构的Cu配合物;以HCBP衍生物为配体合成了七个过渡金属配合物;以SCN〓、N〓,C〓O〓等为桥联配体,以dmpyen为端基配体合成了十一个配合物。

The main contributions of this thesis are:(1) Seven mononuclear complexes of tetradentate ligand NTB have been obtained using N〓 or SCN〓 as the additional ligand;(2) Seventeen binuclear complexes of Fe , Zn , Co , Cu have been designed and the complexes of Co , Cu exhibit antiferromagnetic properties;(3) Changing the bridged-ligand such as PO〓, CO〓, o-phth, mai, Ag (CN 〓, Au 〓, etc , fourteen tetranuclear complexes of polypridine ligand have been synthesized;(4) Two antiferromagnetic 1D chain complexes of KH〓pdc ligand have been prepared from hydrothermal reactions; in addition, one ferromagnetic 1D chain copper complex of tpdp which is bridged by oxalate has been obtained.

本论文的主要贡献为:(1)合成了配体NTB的七个新型单核配合物;(2)合成了十七个铁、锌、钴及铜系列混桥双核配合物,其中双核钴和双核铜配合物为反铁磁偶合;(3)选用多吡啶配体tpdp和TPA,改变桥联配体,合成了十个四核配合物;(4)选择配体KH〓pdc,采用水热合成方法得到了反铁磁性一维链状锰、铜配合物;以草酸根为桥联配体,合成了配体tpdp的一维链状铜配合物,该化合物为铁磁偶合,文献较少报道。

Determination of phytate and phosphate by suppressed conductivity ion chromatography was investigated. Plant samples were extracted with 1% trichloroacetic acid.

采用抑制型高效离子色谱法检测植物样品中植酸根和磷酸根的含量。

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