酸根

In the Infrared spectrum of complexes, there are strong absorptions in ~1 660 cm-1 which can be ascribed to the antisymmetric vibration of the O -C -O unit in heterometallic multinuclear complexes. The different dates of antisymmetric stretching vibration of ox present two modes.

在红外光谱中，杂多核配合物在～800 c~(-1)有强的O—C—O反对称伸缩振动吸收，根据草酸根表现的非对称伸缩振动、对称伸缩振动的数值，判断出它们有两种不同的配位方式。

Finally, the cytotoxic and antibacterial activities of the oxamido-bridged binuclear complexes were studied in vitro.. This dissertation consists of three sections as follows:1. The crystal structure of a oxamide dinitrate,(1) [H_4dmaeoxd](NO_3)_2 H_2dmaeoxd = N,N\'-bis[2-ethyloxamide, has been obtained. The diversity of complexes with different structures is carried out by successful synthetic strategy of controlling species of metal ions, counter anions, pH values and solvents in the course of synthesis. Four dinuclear complexes bridged by trans-dmaeoxd2-: [Cu_2_2](ClO_4)_2 (2), [Cu_2_2](ClO_4)_2 (3),、[Cu_2(Me_2phen)_2](ClO_4)_2 (4), [Cu_2_2(H_2O)_2] (5); Four dinuclear complexes bridged by cis-dmaeoxd2-: [NiNi_2](ClO_4)_2 (6), [CuNi_2](ClO_4)_2·2CH_3OH (7), [CuZn_2]-(ClO_4)_2·2H_2O (8), [Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9); three 1-D polynuclear complexes: [Cu_2]_n·nH_2O (10), [Cu_2(H_2O)_2-]_n·4nH_2O (11), [Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12); one 2-D polynuclear complex,[Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n).2nH_2O (13); the others: [VO(H_2O)]·2H_2O (14), [Zn_2_4](ClO_4)_2·H_2O (15), [Cu_2]·2DCM (16) have been synthesized and characterized by X-ray single crystal diffraction, elemental analysis, IR spectra.

本论文主要包括以下三部分：一、合成得到了一个草酰胺配体硝酸盐的单晶结构，[H_4dmaeoxd](NO_3)_2 (1)；通过调控金属离子的种类、端基配体、抗衡阴离子、溶剂、pH值等条件定向合成了四个反式草酰胺桥联双核铜配合物：[Cu_2_2](ClO_4)_2 (2)、[Cu_2_2](ClO_4)_2 (3)、、[Cu_2(Me_2phen)_2](ClO_4)_2 (4)、[Cu_2_2(H_2O)_2] (5)；四个顺式草酰胺桥联同/异双核配合物：[NiNi_2](ClO_4)_2 (6)、[CuNi_2](ClO_4)_2·2CH_3OH (7)、[CuZn_2]-(ClO_4)_2·2H_2O (8)、[Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9)；三个一维聚合物： [Cu_2]_n·nH_2O (10)、[Cu_2(H_2O)_2-]_n·4nH_2O (11)、[Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12)；一个二维聚合物： [Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n)。2nH_2O (13)；单核钒配合物[VO(H_2O)]·2H_2O (14)、草酸根桥联双核锌配合物[Zn_2_4](ClO_4)_2·H_2O (15)、美洛西康铜配合物[Cu_2]·2DCM (16)，利用元素分析、摩尔电导、红外光谱、电子光谱和单晶X-射线衍射对上述所得化合物进行了结构表征，探讨了结构影响因素，并研究了其超分子结构。

How to circumvent the interferences of other acid during the non-aqueous titration of basic drugs with perchloric acid

非水滴定法中常见酸根的影响如何消除？

Methods: In the 5 mol/L H2SO4 medium, phosphomolybdic acid reacted with CV to form a ion-associate. Then resulted in the increase of RRS.

在5 mol/L H2SO4介质中，磷钼酸根阴离子与CV生成离子缔合物，导致体系共振瑞利散射增强。

Water solubility experimental showed that thesolubility of phosphines in water only containing phosphonic acid group was0.16～0.29 g/mL; After introduction of ethoxylated group, the solubility ofphosphines in water was significantly improved.

水溶性实验表明，仅含膦酸根的膦配体在水中溶解度约为0.16～0.29 g／mL；引入乙氧基后，膦配体的水溶性有明显的改善。

XRD indicated that the replacement of the terephthalate anion by the polytungstate anion had little effect on the structure.

结果表明，经过同多钨酸根阴离子的交换以后，垂直于水滑石层板方向的平行层板方向的晶格参数值变小，平行层板方向的晶格参数值不变，(003)、(006)、(009)衍射峰处的层间距值比为3：2：1；交换过程没有改变水滑石的结构，水滑石原位生长在γ-Al2O3表面及内孔，比表面积由γ-Al2O3载体的219m2/g增加到247m2/g，孔径分布则由原来的2～11nm变化为3～4nm。

XRD indicated that the replacement of the terephthalate anion by the polytungstate anion had little effect on the structure.

结果表明，经过同多钨酸根阴离子的交换以后，垂直于水滑石层板方向的平行层板方向的晶格参数值变小，平行层板方向的晶格参数值不变，(003)、(006)、(009)衍射峰处的层间距值比为3：2：1；交换过程没有改变水滑石的结构，水滑石原位生长在γ-Al2O3表面及内孔，比表面积由γ-Al2O3载体的219平方公尺/g增加到247平方公尺/g，孔径分布则由原来的2~11nm变化为3~4nm。

A terephthalate anion-pillared Ni-Al hydrotalcite-like layered double hydroxide was synthesized on the surface and within the pores of γ-Al 2O 3 by in situ crystallization and a polytungstate anion-pillared hydrotalcite was subsequently obtained by ion-exchange.

采用原位沉积法在γ-Al2O3表面原位合成了对苯二甲酸阴离子柱撑的镍铝水滑石，并用同多钨酸根阴离子部分交换了镍铝水滑石中的对苯二甲酸阴离子。

The single crystal complex [Co22] (Hqina=quinaldinic acid) was synthesized, which belongs to monoclinic system with space group P2(1)/C.

合成了配合物[Co22]单晶，其中，qina为喹哪啶酸根，DMSO为二甲基亚砜。

A single crystal complex [Ni2(H2O)2]2DMSO(Hqina=quinaldinic acid, DMSO=dimethyl sulfoxide) was synthesized at room temperature by the solvent substitution method, which belongs to monoclinic system with space group C2/m.

在常温下，通过溶剂置换法制备了[Ni2(H2O)2]2DMSO单晶，其中qina为喹哪啶酸根，DMSO为二甲亚砜。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新