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In 0.015 mol/L NaOH medium, AuCl4(superscript -)reacted with hexadecyl trimethyl ammonium bromide, forming water soluble CTMAB-AuCl4 complex that exhibited a weak absorption peak at 400 nm. In the presence of hydrazine, the reaction produced orange-red nanogold particle and exhibited a surface plasma resonance absorption peak at 520 nm.

在0.015mol/LNaOH介质中,氯金酸根离子AuCl(上标-下标 4与阳离子表面活性剂十六烷基三甲基溴化铵反应生成水溶性的CTMAB-AuCl4缔合物,在400nm处产生一个很弱的吸收峰,当有肼存在时,反应生成橙红色的金纳米粒子,在520nm处出现一个表面等离子体共振吸收峰,从而可实现废水中微量肼的分光光度测定。

The XRD results showed that the materials with hexangular configuration was prepared successfully.

结果表明:制得了六角结构的介孔材料,同时在材料中引入了羧酸根

For the production of reactive polyurethane cross-linkinger and curing agents, 2, 4-diisocyanate toluene terpolymer, which possesses the rigid structures of hexatomic ring and three reactive functional groups, was synthesized and characterized by the Fourier transform infrared, the gel permeation chromatography and the chemical analysis methods.

为了制备高活性聚氨酯交联固化剂,用2,4-二异氰酸基甲苯三元聚合反应合成了具有3个活性异氰酸根的六元环结构异氰脲酸酯。

The activated hydroxyl of the rare earth complex reacted with the -NCO of the of isophorone diisocyanate,and a new bonding-type rare earth polymer materials was prepared. We studied the optical property, thermodynamic properties of the materials were, and the results obtained show that the materials have high light transmittance and thermal stability as well as good fluorescence properties.

同时利用配合物的活性基团羟基与异佛尔酮-二异氰酸酯中的异氰酸根活性基团进行反应,制备出一种新型的键合型稀土高分子材料,并考察了该材料的光学性能、热力学性能等。

In this thesis, five polydentate ligands including azido, oxalate, terephthalic acid, isophthalic acid and Pyridine-2,6-dicarboxylic acid were used to construct new transition metal complexes (M = Ru, Fe and Zn). Eight new complexes as listed below were synthesized and fully characterized.

本论文以草酸根、叠氮根、对苯二甲酸、间苯二甲酸和吡啶-2,6-二羧酸等含O、N的多齿共轭配体为研究对象,合成了以下八个结构新颖的化合物,并对它们的结构和谱学性质进行了详细的表征。

The rest positions of 〓 unit are occupied by water and an oxygen atom of carboxylates from another type of ligand. With two carboxylates of this type of ligand, two ladderlike long chains are connected to form one-dimensional ladderlike chain structure.

第二类配体中每个羧酸根的一个氧原子与水分子饱和四面体结构单元余下的位置,并连接两个梯形长链形成一维梯形链状聚合物。

The first part is to synthesize 5-formyl -8- quinolinol from 8-uinolinol and chloroform , using ethanol as a solvent. Then analysizing the 5-formyl-8-quinolinol by IR. The second part is , according to ideas of molecule designing, to synthesize the new self-assembly Inorganic-Organic coordination polymers Co(u2-bpyV2O6,(C4H4N2)Ni2(H2O)2-V4Ol2,(Cl2Hl2N2)Co-V2O6 using Cu, Ni, and Co as templating, 4-cyano-pyridine(4-CNPy), 4,4-bipyridine,pyrazine, l,2-bis(4-pyridyl)ethane, 5-formyl -8- quinolinol as building blocks and Ammonium Metavanadate (NH4VO3) as subordinate building blocks by Hydrothermal , analysizing their content of element determining their structures by X-Ray diffraction.

本课题实验分为两部分:一是配体的合成,以8-羟基喹啉、三氯甲烷为原料,以乙醇为溶剂,合成了5—甲醛基—8羟基喹啉并且对其进行了IR的分析测定;二是配位聚合物的合成,通过分子设计,采用溶剂热法以Cu、Ni、Co为中心离子,以5—甲醛基—8羟基喹啉、4,4-联吡啶、吡嗪、1,2-二吡啶基乙烷为配体,以偏钒酸根(VO_3~-)为辅助配体,通过水热法自组装合成了新的3-D网状结构配位聚合物Co(μ_2-bpy)V_2O_6,(C_4H_4N_2)Ni_2(H_2O)_2·V_4O_(12),C_(12H_(12)N_2Co·V_2O_6,并对其进行了元素分析和晶体结构的测定。

The sodium lignosulfonate with low molecular weight which has more hydroxyl groups and sulfonic groups, less methoxyl groups, has better corrosion and scale inhibition performances.

研究表明,分子量较小的木素磺酸钠级份含有较多的羟基和磺酸根、较少的甲氧基,具有较好的缓蚀阻垢性能。

Raman spectrum of saturated aqueous solution of ammonium dimolybdate crystal was recorded, and compared with those of ammonium dimolybdate crystal , ammonium heptamolybdate crystal, saturated aqueous solution of ammonium heptamolybdate crystal and monomolybdate anion in aqueous solution respectively.

记录了常温下二钼酸铵晶体饱和水溶液的Raman光谱,并分别与二钼酸铵晶体、仲钼酸铵晶体、仲钼酸铵晶体饱和水溶液、水溶液状态下单钼酸根离子的Raman光谱进行了比较研究。

Syntheses,Crystal Structures and Properties of Multinuclear Ferric Complexes with Organic Carboxylates and N, N-chelate ligand

论文标题:含铁有机酸根和N,N-双齿配体形成的多中心配合物的合成、晶体结构及性质研究

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推荐网络例句

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。

This is not paper type of business,it's people business,with such huge money involved.

这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。