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酸性反应

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The influence of reaction time, temperature, the acidity strength and amount of IL, on benzophenone yield were investigated.

考察了反应时间、温度、离子液体用量及Lewis酸性调变对反应的影响。

The kinetic parameters of vanadium catalytic oxidation of azomethine H by bromate have been determined by using spectrophotometric method .

以酸性介质中痕量钒催化溴酸钾氧化甲亚胺 H显色反应为对象,利用光度法研究了反应的动力学参数。

CdS nanoarods have been synthesized by using Cetyltrimethyl Ammonium Bromide as the soft template under γ-irradiation through the reaction of cadmium sulphide (CdSO4·8/3H2O) and thiacetamide in acidic condition for pH value of 3. The physical and chemical properties and the structure of CdS nanorods were characterized by XRD, UV-Vis, SAED, TEM and PL.

在pH=3的酸性条件下,以硫酸镉和硫代乙酰胺为反应前驱体,采用十六烷基三甲基溴化铵自组装形成的管状胶束为模板,通过γ射线辐照法成功合成了CdS纳米棒,并通过XRD、UV-Vis、SAED、TEM和PL等技术对反应中间产物及最终产物进行了表征。

Amino-5-acety laminobenzenesulfonic acid has been synthesized from 2, 5-diaminobenzene sulfonic acid and Acid Red BG (CI Acid Red 37) has been synthesized by coupling the diazonium salt of 2-amino-5-acetylaminobenzenesulfonic acid with racid.

利用2,5-二氨基苯磺酸为原料合成2-氨基-5-乙酰氨基苯磺酸,并进一步经2-氨基-5-乙酰氨基苯磺酸重氮盐与γ酸的偶合反应合成了酸性红BG(CIAcidRed37),并对影响反应的因素进行了讨论

The catalysts are arranged in the order of their acidities as reflected in the amount of the disproportionation and skeletal isomerization products.

依不均衡反应及骨架异构化反应之产物的量,可把触媒按照其酸性程度排列。

Acid protease in pure draft beer was determined by Forint phenol method.

福林酚法测定纯生啤酒中的酸性蛋白酶,对反应系统中的参数进行了优化,优化后的条件为:反应温度37℃、缓冲液pH5。

Cephalotaxine ester of 2-oxo-6-methylheptanoic acid was treated with lithium diisopropylamide and Me O-(1-methoxyisopropyl)glycolate to give a mixture of homoisoharringtonine and its stereoisomers with 56% yield. The four stereoisomers separated by TLC showed identical mass spectra and almost superimposed IR but with different 1H NMR spectra. The configuration of the 2'-C and 3'-C of the four isomers were postulated based upon their 1H NMR spectra as compared with the 1H NMR spectra of isoharringtonine and its stereoisomers.

2-氧代-6-甲基庚酰基三尖杉碱(3)与0-(1-甲氧基异丙基)羟基乙酸甲酯(4)在强碱性试剂二异丙胺锂存在下,起亲核加成反应,反应中间体5在室温用酸性丙酮水解,得到一种新的三尖杉酯类生物碱一一高异三尖杉酯碱(6c)及其立体异构体(6a、6b、6d)的混合物,产率56%、通过制备薄层层析分得这四个立体异构体,它们的1H NMR和异三尖杉酯碱及其立体异构体的1H NMR类似,推定了它们的绝对构型。

The color fading reaction of pyrocatechol violet with iodate ion in stronger acid was studied and a method for determination of iodine in the salt was proposed.

研究了在强酸性条件下,邻苯二酚紫与碘酸根离子的褪色反应,拟定了测定加碘食盐中碘离子简便、快速的分析方法,确定了该褪色反应的最佳褪色条件。

It was found that Pd-Co/active carbon catalyst was the optimal catalyst, and Pd-Co/γ-Al2O3 was also good, but silica and kieselguhr were not proper carriers for the object reaction, because of their stronger surface acidity, which could result in the formation of polymer, jammed the micro pores of catalyst, and then resulted in its deactivation. Addition of Bi, Ce and Cu promoters could not improve the activity of catalyst, but La and Ba promoter could enhance the activity of catalyst apparently, and the Co was the best promoter, especially Co was impregnate in advance. It was attributed to that the pre-impregnated Co may occupy the micro pores of active carbon, and cover some bad functional groups on the surface of catalyst, so that the active and selectivity of catalyst could be enhanced obviously.

研究结果表明,Pd-Co/活性炭催化剂是目标转移加氢反应的最适宜催化剂,Pd-Co/γ-Al203效果也较好,而硅胶和硅藻土由于表面酸性较强,容易造成生成聚合物而堵塞催化剂微孔、使催化剂迅速失活;此外,添加Bi、Ce、Cu等助剂时对活性并无改善作用,而添加La和Ba助剂时可使Pd的催化活性有所提高,效果最好的是Co助剂,尤其是先浸渍Co的Pd-Co/C催化剂,原因是Co占据了活性炭的微孔、覆盖了某些对目标反应不利的官能团,使其活性和选择性都有较大幅度的提高。

The experimental results showed that the composition of dry gas produced from Daqing VGO in the presence of acidic catalyst was similar to that of cracking FCC olefin enriched gasoline,and dry gas was mainly produced through monomolecular mechanism.

结果表明,大庆蜡油在酸性催化剂上反应所产生的干气组成与高烯烃催化裂化汽油相同,干气的产生主要是单分子裂化反应所造成的。

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We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。

This is not paper type of business,it's people business,with such huge money involved.

这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。