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酸性反应

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The match of the acidity and basicity is very important to obtain good reactivity and high yield in the bifunctional organocatalyst system.

在双功能催化的Aldol反应中,要获得高的反应活性和好的收率,催化剂的酸性基团和碱性基团的酸碱强弱匹配非常重要。

When using urea-hydroperoxide as oxygent, just the trimethylphosphine adsorbed on the Lewis acid sites in TS-1 zeolite was oxidized. It further confirmed that the hydroperoxo-titanium species formed by the interaction between the titanium in Lewis acid sites and urea-hydroperoxide are the active oxidation center, and the titanium in the framework as Lewis acid sites enhances the oxidation ability of hydroperoxide. 3. Phenylacetaldehyde and benzaldehyde are found to be the major products in the catalytic oxidation of styrene over TS-1 zeolite, and styrene epoxide is not as speculated detected.

当以过氧化氢尿素为氧化剂时,室温条件下吸附在TS-1分子筛Lewis酸性位的三甲基膦即能被氧化,由此进一步证明,TS-1分子筛中由Lewis酸性位的骨架钛与过氧化氢相互作用形成的过氧化钛物种是三甲基膦氧化反应的活性中心,骨架钛作为Lewis酸中心提高了过氧化氢的氧化能力。

The optimum conditions of synthesis were determined as follows:molar ratio of 2,4-di-t-amylphenol and anhydrous trimeric acetaldehyde 2∶1.2,amount of water 180 g,amount of emulsifier 0.5 g,and amount of catalyst 11.0 g at reacting temperature 80~83℃ for 5 h.

以2 ,4-二叔戊基苯酚、无水三聚乙醛为反应原料,采用含有表面活性剂、酸性催化剂的水作为反应溶剂,缩合反应合成2,2′-亚乙基双(4,6-二叔戊基苯酚)。

The sodium sulfate was used as the electrolyte instead of sodium chlorid. The results elucidated the low pH of EOW was mainly caused by oxygen evolution and the high ORP was mainly generated by both chlorine and oxygen evolution.

用NazSO_4代替NaCl作电解质进行电解,结果表明酸性氧化电位水的低pH主要是由析氧反应造成的,而高ORP值主要是由析氯反应和析氧反应共同造成。

At the same time, the fouling mechanism of membranes given in this thesis can give a reasonable explanation on the change of membrane performance. Our results show that the magnetization of membranes can effectively improve the anti-fouling ability of the PAN- Fe_3O_4 membrane. The obtained result may give insight to the development of new membranes with a good anti-fouling performance in the filtration of blood solution. No chemical bond was found between PAN and Fe_3O_4 in the membrane at room temperature. The addition of Fe_3O_4 can improve the temperatures of dehydrogenated reaction and decomposition of PAN but dot change the glassy transition temperature. The resistance against acid is stronger than the resistance to base for a PAN- Fe_3O_4 membrane.

结果表明在PAN- Fe_3O_4超滤膜制备过程中使用外加磁场作用能有效提高膜的耐污染能力,这一结果为开发适用于血液处理的耐污染超滤膜提供了一种新途径;在PAN- Fe_3O_4超滤膜中,四氧化三铁与PAN在室温下没有形成化学键,也不存在官能团之间的相互作用;添加Fe_3O_4对膜的玻璃化温度没有影响,但能提高PAN环化脱氢反应的温度和分解温度;PAN- Fe_3O_4超滤膜的耐酸性强于耐碱性,在pH值为10以上的溶液中由于水解作用而溶解,使得膜失去使用价值,膜的耐酸性与酸的种类、浓度和氧化性有关。

In this paper,based on the principle of LDH synthesizing in-situ,with spectrophotometry and XRD analyses of solid,removal efficiency and mechanism of acid orange from dye aqueous solution were studied.

本文研究即时合成层状双氢氧化物处理酸性金黄溶液的效果以及影响因素,并利用XRD分析研究了酸性金黄染料在LDH结构中的嵌入方式和反应机理。

The color removal of azo dye Acid Orange Ⅱ using potassium permanganate was studied. The effect of Acid Orange Ⅱ and potassium permanganate concentration, initial pH conditions, and reaction time were investigated.

本文研究了高锰酸钾对偶氮染料酸性橙Ⅱ的脱色效果,考察了酸性橙Ⅱ初始浓度、高锰酸钾投加量、初始pH条件、反应时间的影响。

Due to the ring strain and Lewis acid character, silacyclobutanes and silacyclobutenes can undergo ring expansion reactions to afford five- and six-membered silacycles, or ring opening to give organosilicon molecules and materials as well as fulfill organic transformations under very mild conditions.

硅杂环丁烷和硅杂环丁烯由于存在环张力和具有一定的Lewis酸性,能够通过扩环反应生成五元和六元含硅杂环化合物,也能够通过开环反应生成不同结构的有机硅分子和聚合物,抑或实现有机反应在温和条件下的转化。

Sythesis and application of chlorostyrene-DVB strongly acidic cation exchange resin ;2. For this study,a series of poly( p -amino styrenes) with various amounts of supported hydrogen chloride,and a series of strongly acidic cation exchange resin s with various exchange capacity were synthesized,and their catalytic property for ketalization of cyclohexanone and glycol were investigated.

通过测定固载了不同量的氯化氢的聚和不同交换量的强酸性阳离子交换树脂催化的环己酮与乙二醇的缩酮化反应缩酮的收率,研究了聚合物固体酸催化剂的疏水性对其催化缩酮化反应性能的影响;发现在一定范围内增加催化剂的疏水性,可提高缩酮化反应的收率。

After inoculation of leukemia virus,the changes in ANAE,AcP and β-Gase reactions were observed in the thymocyte and thymie nurse cell in thymus cortex of experimental mice.

对接种白血病病毒后30d、75d 小鼠胸腺和淋巴结的组织结构及酸性非特异性酯酶、酸性磷酸酶、β~葡糖苷酸酶反应类型进行了观察,并与正常组作对照。

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交际能力和语法的关系应该是目标与途径的关系。

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这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。