酸式酯

We investigated constituent of triterpenoid saponins ofAlbizzia, two new compounds together with two known compounds were isolated from Albizzia julibrissin Durazz. by using column chromatography (macroreticular resin, silica gel, Sephadex gel, reverse phase silica gel),preparative HPLC methods et al.On the basis of spectroscopic analysis, including IR,ESI-MS,~1H-NMR,~(13)C-NMR,HMBC,HMQC,~1H-~1HCOSY and chemical methods, the structure of two new compounds were identified as 3 - O -[β-D-xylopyranosyl(1→2)-β-D-fucopyranosyl (1→6)-β- D -2- deoxy - 2 - acetoamidoglucopyranosyl] -21-O-[(6S)-2- trans- 2,6-dimethyl - 6 - O-β- D - quinovopyranosyl -2,7- octadienoyl] - acacic acid- 28 - O-β-D-glucopyranosyl(1→3)[α-L-arabinofuranosyl(1→4)]-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside acacic acid 3- O -β- D- glucopyranosy(1→3)-β- D- fucopyranosl(1→6) [β-D- xylopyranosyl (1→2)]-β-D-glucopyranoside ;two known compounds were acacic acid lactone 3- O -β-D- xylopyranosyl-(1→2)-β-D-fucopyranosl (1→6)- 2-deoxy -2 -acetoamido -β-D- glucopyranoside ; acacic acid lactone 3- O-β-D-xylopyranosyl(1→2)-α-L- arabinopyranosl (1→6)- 2- deoxy - 2- acetoamido -β-D-glucopyranoside . The study lays chemical foundation and chemical reference substance for enhancing quality standard of Albizzia julibrissin Durazz.

本研究论文在综述国内外对合欢属Albizzia三萜皂苷化学成分和药理作用研究进展的基础上，利用传统植化分离手段和现代分离技术，包括大孔树脂、硅胶、葡聚糖凝胶、反相硅胶等柱色谱，制备高效液相色谱法等技术从中药合欢皮中分离得到了4个化合物，其中，2个新化合物和2个己知化合物，并进一步通过现代分析技术IR，ESI-MS，~1H-NMR，~(13C-NMR，HMBC，HMQC，~1H-~1HCOSY等和化学方法鉴定了2个新化合物的结构分别是：3-O-[β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖基]-21-O-[(6S)-2-反式-2，6-二甲基-6-O-β-D-吡喃鸡纳糖基-2，7-辛二烯酸基]-金合欢酸-28-O-α-L-呋喃阿拉伯糖基(1→4)[β-D-吡喃葡萄糖基(1→3)]-α-L-吡喃鼠李糖基(1→2)-β-D-吡喃葡萄糖苷，金合欢酸3-O-β-D-吡喃葡萄糖基(1→3)-β-D-吡喃夫糖基(1→6)[β-D-吡喃木糖基(1→2)]-β-D-吡喃葡萄糖苷；2个已知化合物结构分别是：金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷，金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-α-L-吡喃阿拉伯糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷。

The common chemical constituents were juniper camphor,1,3,3-trimethylcyclohex-1-ene-4-carboxaldehyde,borneol,α-curcumene,α-bisabolol,cis-caryophyllene,benzyl benzoate,methyl β,β-dimethylbenzenepropanoic acid ester,2,4-decadienal and heneicosane in the essential oil of the five cultivars' Hangjuhua.Among them,juniper camphor is most which were composed of 11.96%,10.51%,10.95%,13.28% and 10.77% of the total essential oil,and methyl β,β-dimethylbenzenepropanoic acid ester is second,which were composed of 1.51%,1.86%,2.52%,4.89% and 2.51% of the total essential oil,respectively.

5种栽培类型杭菊花挥发油中共有成分为1，3，3-三甲基环己-1-烯-4-甲醛、冰片、α-姜黄烯、α-甜没药萜醇、顺式石竹烯、桧脑、安息香酸苄酯、β，β-二甲基苯丙酸甲酯、2，4-癸二烯醛和二十一烷；其中桧脑含量最高，分别占挥发油总量的11.96%，10.51%，10.95%，13.28%和10.77%，为5种栽培类型杭菊花挥发油中最具特征的成分；其次是β，β-二甲基苯丙酸甲酯，分别占挥发油总量的1.51%，1.86%，2.52%，4.89%和2.51%。

The main chemical components of Bulgaria are Citronellol、Trans-Geraniol、Nerol、Methyl eugenol、Linalool、β-Phenyl ethyl alcohol. The main chemical components of Xinjiang Province areβ-citronellol、trans-geraniol,β-phenyl ethyl alcoho, farnesol, geranellyl acetete, 7-octamoic acid ethyl ester.

保加利亚玫瑰油的主要成分为β-香茅醇、反式－香叶醇、橙花醇、芳樟醇、β-苯乙醇、甲基丁子香酚；新疆玫瑰油的主要成分为β-香茅醇、反式-香叶醇、β-苯乙醇、7-辛烯酸乙酯、乙酸香叶酯、金合欢醇。

The cis novel bisoxazoline ligands L1-L4 have been synthesized through the treatment of new cis dihydroxy diamide with p-toluenesulfonyl chloride in the presence of catalytic quantity of 4--pyridine, and the cis dihydroxy diamide could be achieved from the condensation of the amino alcohols and cis cyclopropane dicarbonyl chloride prepared via oxidation and halogenation from cis-2,2-dimethyl-3-formylcyclopropanecarboxylate with DCC.

我们以蒈醛酸内酯为起始原料，经过氧化反应、酰氯化反应得到顺式环丙烷二酰氯，然后在二环己基碳二亚胺的催化下与相应的氨基醇反应合成了顺式二羟基酰胺，再用对甲苯磺酰氯将羟基活化，最后在二甲氨基吡啶的催化下关环合成顺式双噁唑啉配体L1～L4。

A novel and sensitive thin-layer chromatography method for specific and simultaneous detection of both lactone form Monacolin K and acid form Monacolin K is developed in this study.

通过实验筛选出了适于特异性的同步检测酸式和内酯式莫奈呵啉K的薄层色谱法。

We utilized several parameters including ECN, CN, DB, Log α and Log β to explore the reliability of the analyzing methods of triacylglycerol types, and on the other hand, also to cultivate oleaginous yeast using batch fermentation method to explore the bacterial activation, before and after fermentation, on the changes of three fatty acid types in triacylglycerol.

本实验利用HPLC-ELSD来分析食用大豆油之三酸甘油酯中三个脂肪酸种类，利用许多参数，包括：ECN、CN、DB、Log α及Log β，探讨分析三酸甘油酯种类方法之可靠性，另外以批式发酵培养产油酵母菌Rhodotorula glutinis，探讨发酵前活化菌体与发酵后菌体之三酸甘油酯中三个脂肪酸种类变化。

In addition, a benzene, toluene (0.32%), was also detected in 80% ripening fruit. In 90% ripening fruit were detected 27 kinds of aroma components belonging to 2 categories. Among the components, 17 were esters, and 10 alkenes. Of the 17 esters, methyl octanoate is the highest (21.00%), followed by ethyl hexanoate (17.64%), methyl hexanoate (14.34%). Of the 10 alkenes cis-β-ocimene is the highest (1.00%), followed by à-copaene (0.81%) and trans-ocimene (0.48%).

在9成熟果实中检测到2类共27种香气成分，分别是酯类17种和烯类10种；在酯类中，相对含量最高的是辛酸甲酯(25.27%)，其次是辛酸乙酯(21.00%)、己酸乙酯(17.64%)、己酸甲酯(14.34%)；在烯类中相对含量较高的有β-顺式－罗勒烯(1.00%)、à-蒎烯(0.81%)和反式－罗勒烯(0.48%)。

A diacid triglyceride containing two molecules of palmitic acid and one of stearic acid could be named dipalmitostearin or steartodipalmtin.

含有二分子棕榈酸和一分子硬脂酸的二酸式甘油三酸脂可命名为二棕榈酰硬脂酰甘油酯或硬脂酰二棕榈酰甘油酯。

A diacid triglyceride containing two molecules of palmiticacid and one of stearic acid could be named dipalmitostearin orsteartodipalmtin.

含有二分子棕榈酸和一分子硬脂酸的二酸式甘油三酸脂可命名为二棕榈酰硬脂酰甘油酯或硬脂酰二棕榈酰甘油酯。

The production process of fatty acid methyl ester with high acid value acidulated oil and fatty acid replaced superior quality fat and oil by high temperature gas phase method and supplemental ester translation process was also introduced.

对间歇式酯化-酯交换工艺进行了具体分析，并着重介绍了采用高温气相法及补充酯交换工艺，以高酸值酸化油和脂肪酸代替高档油脂生产脂肪酸甲酯的生产工艺。

In the negative and interrogative forms, of course, this is identical to the non-emphatic forms.

。但是，在否定句或疑问句里，这种带有"do"的方法表达的效果却没有什么强调的意思。

Go down on one's knees;kneel down

屈膝跪下。。。下跪祈祷