酸基

Part I, the Friedel-Crafts acylation on DAA and methyl dehydroabietic acid was carried out with acetyl chloride, benzoyl chloride or phthalic anhydride as acylating regents, anh- ydrous aluminum chloride as catalyst and with different solvents to compare with, we have got t- hree new compounds.

第一部分，分别以脱氢松香酸和脱氢松香酸甲酯为底物，乙酰氯、苯甲酰氯、邻苯二甲酸酐为酰化试剂，无水三氯化铝作催化剂，采用不同的溶剂及反应条件进行傅克酰基化反应，得到3个新化合物。

Besides, n-butyl and sec-butyl tosylate that are difficult for oxidative addition can react with phenylmagnesium bromide to form corresponding cross-coupling products. Primary alkyl halide which contains β-hydrogen and is relatively hard to undergo the reaction , n-butyl chloride for instance, can react with aryl Grignard reagents in the presence of NiB alloy as well.

此外，难以进行氧化加成的对甲苯磺酸正丁酯和对甲苯磺酸仲丁酯可以与苯基溴化镁作用生成相应的交叉偶联产物；反应相对困难的含β-H的伯卤烷，如：正氯丁烷也可以在NiB催化下与芳基格氏试剂发生偶联。

L-Phenylalanine was then obtained by alkylation of N- glycine ethyl ester with benzyl bromide in the presence of an asymmetric phase-transfer catalyst-N-benzyl-cinchonine chloride, followed by hydrolysis of the resulting product.

以甘氨酸乙酯盐酸盐和二苯甲酮为起始原料合成了N-二苯亚甲氨基乙酸乙酯，后者在手性相转移催化剂-N-苄基氯化辛可宁诱导下与烷基化试剂溴化苄发生不对称相转移催化烷基化反应，水解得到L-苯丙氨酸。

The company mainly produces cinnamaldehyde, cinnamic acid, cinnamic alcohol, cinnamic nitriles,-bromo-cinnamic aldehyde, amyl cinnamic aldehyde, acetic acid Gui ester, cinnamic acid acetate, L-carnitine, coumarin , vitamin B1 and so on, one of cinnamon products only amounted to more than 100 kinds of quality and technical content are up to domestic advanced level, is expected to reach an annual output value of 10 billion yuan.

公司主要生产肉桂醛、肉桂酸、肉桂醇、肉桂腈、α-溴代肉桂醛、戊基肉桂醛、乙酸桂酯、肉桂酸乙脂、左旋肉碱、香豆素、维生素B1等，其中仅肉桂系列产品就达100多种，其质量及技术含量均达到国内先进水平，预计年产值可达10亿元人民币。

The company mainly produces benzaldehyde, cinnamic aldehyde, cinnamic acid, cinnamic alcohol, cinnamic nitriles,-bromo-cinnamic aldehyde, amyl cinnamic aldehyde, acetic acid Gui ester, cinnamic acid acetate, L-carnitine, coumarin, vitamin B1, etc., of which only cinnamon series reached more than 100 kinds of products, its quality and technical content are up to domestic advanced level, is expected to reach an annual output value of 10 billion yuan.

公司主要生产苯甲醛、肉桂醛、肉桂酸、肉桂醇、肉桂腈、α-溴代肉桂醛、戊基肉桂醛、乙酸桂酯、肉桂酸乙脂、左旋肉碱、香豆素、维生素B1等，其中仅肉桂系列产品就达100多种，其质量及技术含量均达到国内先进水平，预计年产值可达10亿元人民币。

Segmented polyester polyurethaneurea based n 4, 4'-disphenylmethane diisocyanate, ethylene diamine and polybutylene adipate elastomers and their deuterated polymers were studied by means of IR spectroscopy.

用红外光谱法对基於4，4'-二苯基甲烷二异氰酸酯、乙二胺和聚己二酸丁二醇酯的嵌段聚酯型聚脲氨酯弹性体及其氘化產物进行了研究。

Extracellular-regulated kinase 3(ERK3) is an atypical member of ERKs, lacking the threonine and tyrosine residues in the activation loop, carrying a unique C-terminal extension and being mainly regulated by its own protein stability.

其活化环不同于一般的ERK，缺少苏氨酸和酪氨酸残基，拥有一段独特的C端延伸序列。ERK3蛋白是一个不稳定的蛋白，它的生物学活性主要依靠其蛋白稳定性和激酶活性调节。

Our company covers an area of 1,500 acres, employs more than 1,000 people, since the plant since the company produces about 50 tons per day, Yangsan factory main production, Water Margin and other brands of paint, mainly engaged in: Alkyd series, marketing-based paint, car paint,á, acrylic paint series, amino baking finish, floor paint, anti-corrosion Antirust Paint, high temperature paint, helmets, stove paint, plastic powder, latex, and so on and±diluent.

本公司占地1500亩，拥有员工1000余人，自建厂以来我公司每天生产约50吨，本厂主要生产梁山水泊，水浒等品牌油漆，主要经营：醇酸系列、销基漆、汽车专用漆、聚脂漆、丙稀酸系列漆、氨基烘漆、地坪漆、防腐防锈漆、耐高温漆、头盔、炉具漆、塑粉、乳胶漆等及无苯稀释剂。

The quality of purified 2-KGA from its fermentation products was up to industrial standard. In addition, several hexoses, such as D-glucose and D-sorbitol can be utilized to synthesize 2-KGA by this newly-mixed culture. The growth and anabolism of the B529-V6 were studied in 4M〓 and 300M〓 fermentor respectively. The results showed that its growth and anabolism were affected by carbon sources, ratio of D-glucose and L-sorbose, nitrogen sources, growth factors, inoculum quality and culture condition including the initial pH value, temperature and ventilation.

新菌系B529-V6表现出了较强的高浓度L-山梨糖耐受能力、较高的底物代谢速率和较高的2-KGA转化能力，在8％山梨糖浓度的发酵培养基中培养48h，糖酸转化率较对照菌系提高了5.94％；山梨糖浓度提高至10％，其生长代谢受影响程度较小，且能不同程度地利用葡萄糖和山梨醇为底物，合成维生素C前体-2-酮基-L-古龙酸（2-KGA），其发酵产物2-KGA经反相高效液相色谱分析其质量符合工业化生产要求。

The preparing on calcium sulfonate grease with high performance of rust had proof was then synthesized.

从润滑脂的极压防锈机理着手，利用小分子有机酸等活性氢物质，直接对磺酸钙原料吸附的碳酸钙进行晶型转化，探讨了具有高极压防锈性磺酸钙基脂的研制。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。