酸基

The results show that a MgSnO3·H2O conversion film is formed by treatment in the stannate solution at 90℃, and the immersion test and potentiodynamic polarization show that the corrosion resistance of the AZ91D alloy is improved to some extent.

结果表明：锡酸盐转化处理后合金表面形成了以MgSnO3·H2O为主要成分的转化膜，可对合金起到一定的防护作用；转化膜由细小的球形颗粒密积而成，颗粒之间存在间隙，它可以为化学镀镍的前处理过程提供良好的吸附条件；转化膜上的化学镀镍层组织致密、无缺陷， MgSnO3·H2O转化膜在镀镍层与基体之间起到过渡作用，镀层的磷含量达到9%，与基体结合良好；在3.5% NaCl (pH=7)溶液中的动电位极化测试表明，镀镍以后的合金在阳极极化过程中发生了明显的钝化，耐腐蚀性能进一步提高，对基体起到了较好的防护作用。

The results show that the formation of stable radical AH-R*between the antioxidant and the carbon-centred free radical R*from fat may be a main mechanism of the antioxidation to retard lipid rancid, and dihydrotanshinone I can also act as an antioxidant by donating a hydrogenatom to R*, becoming themselves an unreactive radical A*.

结果表明，抗氧化剂与油脂中碳中心自由基复合成稳定自由基，可能是丹参醌抑制或阻止油脂氧化酸败的主要途径，双氢丹参醌Ⅰ也可借助释放活泼H（本身转化成稳定自由基A*）有效清除R*。

The results show that the formation of stable radical AH-R* between the antioxidant and the carbon-centred free radical R* from fat may be a main mechanism of the antioxidation to retard lipid rancid, and dihydrotanshinone Ⅰ can also act as an antioxidant by donating a hydrogenatom to R*, becoming themselves an unreactive radical A*.

结果表明，抗氧化剂与油脂中碳中心自由基复合成稳定自由基，可能是丹参醌抑制或阻止油脂氧化酸败的主要途径，双氢丹参醌Ⅰ也可借助释放活泼H（本身转化成稳定自由基A*）有效清除R*。

Regarding polyurethane varnish as host of the formaldehyde absorbent,mainly aminoacetic aicd , casein, tannins, L - glutamate, DL - a - amino acid, urea, hexamethylenetetramine, lignin and molecule are chosen to serve as formaldehyde absorbent.

以硝基清漆为吸收基质，主要选择了如氨基乙酸、干酪素、鞣质、L-谷氨酸、DL-α氨基丙酸、尿素、六次甲基四胺、木质素、分子筛等作为甲醛吸收剂，涂布于聚氯乙烯胶片上做甲醛吸收测试；根据测试结果，制作的甲醛吸附剂能起到较好的甲醛吸收效果；并探讨了硝基清漆中吸收剂用量的筛选及吸收时间对甲醛消除的影响因素。

The method comprises the steps of dipping and mixing the mipor asphaltic base globular active carbon prepared by the traditional method with an inorganic metal salt solution by a certain ration; heating under an inert atmosphere to 600 to 1200 DEG C at a temperature increasing rate of 1 to 20 DEG C/min for the secondary carbonization; using acid to wash off the remaining metal inside the carbonized material, so as to obtain the asphaltic base globular active carbon with a high mesoporous rate and narrow distribution of mesoporous spertures.

本发明提供了一种浸渍金属盐二次炭化制备中孔沥青基球形活性炭的方法，该方法是将传统方法制备得到的微孔沥青基球形活性炭按一定比例与无机金属盐溶液浸渍混合，然后在惰性气氛下以1～20℃/min的升温速率加热到600～1200℃下进行二次炭化，炭化料经酸洗除去内部残留的金属后，可制得中孔率较高、中孔孔径分布窄的沥青基球形活性炭。

A novel liquid crystalline compound named p-phenylenediamine di 4-[2- benzamide] was synthesized from allyl 2-hydroxyethylether, ethyl 4-hydroxybenzoate and p-phenylenediamine.

以乙二醇单烯丙基醚、对羟基苯甲酸乙酯、对苯二胺为原料合成了末端为不饱和双键的芳香聚酰胺溶致型液晶化合物——二对烯丙氧基乙氧基苯甲酰对苯二胺，最佳合成的摩尔比为∶羧酸∶对苯二胺∶吡啶=2。

Direct competitions of intramolecular C - H insertions into benzylic C - H and 4-nitroor 4-methoxy substituted benzylic C - H of methyl 2-diazo-3-oxo-6-(4-substituted phenyl)-4-(2-phenylethyl)hexanoate 44a and 44b catalyzed by Rh-mediated carbenoid were alsoinvestigated, and the relative reactivities obtained by compound 44a or 44b were comparableto those obtained by indirect method.

此外，还研究了Rh催化分解下，对位硝基取代或甲氧基取代的4-(2-苯基乙基)-6-(4-取代苯基)-2-重氮基-3-氧代己酸甲酯44a、44b苯甲位C-H插入反应的相对速率，与化合物47a和47f得到的结果比较，数据平行。

Therelative rates of the Rh-mediated carbenoid insertion into the benzylic C - H bonds of aseries of para-substituted phenyl substrates: methyl 2-diazo-3-oxo-6-(4-substituted phenyl)-4-propylhexanoate 47a - g, have been measured by an indirect intramolecular competitionmethod under the condition in which the possible steric and conformational effects have beenminimized.

为了将立体因素和构象因素最大程度减小，以便较为准确地评价电子效应对该反应的影响，设计并合成了不同对位取代基的化合物4-丙基-6-(4-取代苯基)-2-重氮基-3-氧代己酸甲酯47a-g，并研究了它们在不同Rh催化剂作用下的分子内C-H插入反应。

New ruthenium benzylidene complexes benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-diphenylphosphinoacetato] monochlororuthenium (46), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene][k~2-3-propionato]monochlororuthenium (47), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-2-benzonato]monochlororuthenium (48) featured five-membered, flexible six-membered and rigidsix-membered chelating rings respectively are prepared by reactions of complex 41 withcorresponding sodium phosphino-carboxylates. It is confirmed by X-ray crystallographicanalysis that the coordination geometries of complexes 46 and 47 are distorted squarepyramids with phosphino-carboxylate ligands chelating to ruthenium, and the coordinationbetween ruthenium and benzylidene ligands are strengthened.

用二苯基瞵乙酸盐、二苯基膦丙酸盐、二苯基膦苯甲酸盐与钌卡宾配合物41反应合成了三个新的钌卡宾配合物：含五元膦-氧螯合环的1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基1-苯亚甲基--一氯合钌(46)、含六元柔性膦-氧螯合环的[1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基1-苯亚甲基--一氯合钌(47)及含六元刚性膦-氧螯合环的[1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基]-苯亚甲基--一氯合钌(48)。X射线单晶衍射分析证明，配合物46、47都为变形的四方锥构型，膦-氧与钌形成螯合配位，其中苯亚甲基与钌的配位得以加强。

A series of novel chiral aminophosphine ligands with binaphthyl backbone and partially reduced binaphthyl backbone were synthesized from optically pure NOBIN and H〓-NOBIN respectively. The effects of binaphthyl backbone and substitutes at the phosphorous atom on Pd (0)-catalyzed allylation of racemic 1, 3-dipheylprop-2-en-1-yl acetate with dimethyl malonate were systematically investigated.

从NOBIN出发合成了一系列膦上含有不同取代基的氮膦配体MAPs以及含有被部分还原的联萘骨架的氮膦配体H〓-MAPs，将此两类配体运用于钯催化的乙酸1，3-二苯基烯丙基酯与丙二酸二甲酯的反应中，考查了膦上取代基和配体骨架对反应的影响。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。