酸基

We investigated constituent of triterpenoid saponins ofAlbizzia, two new compounds together with two known compounds were isolated from Albizzia julibrissin Durazz. by using column chromatography (macroreticular resin, silica gel, Sephadex gel, reverse phase silica gel),preparative HPLC methods et al.On the basis of spectroscopic analysis, including IR,ESI-MS,~1H-NMR,~(13)C-NMR,HMBC,HMQC,~1H-~1HCOSY and chemical methods, the structure of two new compounds were identified as 3 - O -[β-D-xylopyranosyl(1→2)-β-D-fucopyranosyl (1→6)-β- D -2- deoxy - 2 - acetoamidoglucopyranosyl] -21-O-[(6S)-2- trans- 2,6-dimethyl - 6 - O-β- D - quinovopyranosyl -2,7- octadienoyl] - acacic acid- 28 - O-β-D-glucopyranosyl(1→3)[α-L-arabinofuranosyl(1→4)]-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside acacic acid 3- O -β- D- glucopyranosy(1→3)-β- D- fucopyranosl(1→6) [β-D- xylopyranosyl (1→2)]-β-D-glucopyranoside ;two known compounds were acacic acid lactone 3- O -β-D- xylopyranosyl-(1→2)-β-D-fucopyranosl (1→6)- 2-deoxy -2 -acetoamido -β-D- glucopyranoside ; acacic acid lactone 3- O-β-D-xylopyranosyl(1→2)-α-L- arabinopyranosl (1→6)- 2- deoxy - 2- acetoamido -β-D-glucopyranoside . The study lays chemical foundation and chemical reference substance for enhancing quality standard of Albizzia julibrissin Durazz.

本研究论文在综述国内外对合欢属Albizzia三萜皂苷化学成分和药理作用研究进展的基础上，利用传统植化分离手段和现代分离技术，包括大孔树脂、硅胶、葡聚糖凝胶、反相硅胶等柱色谱，制备高效液相色谱法等技术从中药合欢皮中分离得到了4个化合物，其中，2个新化合物和2个己知化合物，并进一步通过现代分析技术IR，ESI-MS，~1H-NMR，~(13C-NMR，HMBC，HMQC，~1H-~1HCOSY等和化学方法鉴定了2个新化合物的结构分别是：3-O-[β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖基]-21-O-[(6S)-2-反式-2，6-二甲基-6-O-β-D-吡喃鸡纳糖基-2，7-辛二烯酸基]-金合欢酸-28-O-α-L-呋喃阿拉伯糖基(1→4)[β-D-吡喃葡萄糖基(1→3)]-α-L-吡喃鼠李糖基(1→2)-β-D-吡喃葡萄糖苷，金合欢酸3-O-β-D-吡喃葡萄糖基(1→3)-β-D-吡喃夫糖基(1→6)[β-D-吡喃木糖基(1→2)]-β-D-吡喃葡萄糖苷；2个已知化合物结构分别是：金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷，金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-α-L-吡喃阿拉伯糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷。

Agent TJ-201 is an organic phosphonocarboxylic acid containing maleic group, p hosphonic group, and ethoxyl group etc.

TJ-201是一种含马来酸基、磷酸亚基、氧乙烯基等的膦基聚羧酸。

In order to improve their water solubility, 4"-fatty amido-3"-sodium carboxylate azobenzene-4-sodium sulfonates were synthesized. They are azo compounds with two hydrophilic groups of carboxyl and sulfonyl. They decrease the surface tension in dilute solution slowly, and show some surfactivity, but are not surfactants. The probable reason is their relative strong hydrophile. Furthermore, their colors are not fresh and far from our destination.

为了改善其水溶性，改用对氨基苯甲酸为原料合成了4′-脂肪酰氨基-3′-羧酸钠偶氮苯-4-磺酸钠盐，以偶氮结构为主的亲水基团上连有羧酸基和磺酸基两个亲水性较强的基团，但可能由于其亲水性太强，在稀溶液中只能缓慢地降低溶液的表面张力，具有一定的表面活性，但不是表面活性剂，而且颜色不鲜艳，距离我们的目标较远。

The mechanism of dioxygen oxidation of 4-nitrotoluene-2-sulfonic acid to 4,4'-dinitrostilbene-2,2'-disulfonic acid in alkali solution under mild condition was investigated.

探讨了在温和条件下在碱的水溶液中氧气液相氧化 4-硝基甲苯- 2 -磺酸制取 4，4'-二硝基二苯乙烯- 2 ，2 '-二磺酸的反应机理，发现 4-硝基甲苯- 2 -磺酸在碱作用下发生离子化生成 4-硝基- 2 -磺酸基苄基阴离子，然后被活化的分子氧氧化成 4-硝基- 2 -磺酸基苄基自由基是反应的关键步骤。

And humic substance (fulvic acids, humic acids and humin). The features of fulvic acids of humic substance at the southwestern part of Turfan-Hami basin are: the content of C is low, and the content of H, S, O is relatively high, atomic number of C/H is low.

研究证实吐哈盆地腐殖质中黄腐酸的特点是C含量较低，H、S、O含量偏高，C/H原子数比较低；官能团分析证实黄腐酸的总酸基、羧基、酚羟基含量较高，反映出黄腐酸具有较高的活性。

Property : This product is a polymer composed of carboxyl, sulphonic, phosphonic . There is organophosphate in the chain and side chain, so it is of superior effect of scale-preventative and be of certain corrosion-proof effect.

5.1性能：本品是含有羧基、磺酸基、膦酸基羟基等基团的共聚物，由于它的直链上和部分支链端含有膦基酸，因此本共聚物具有优异的防垢性能，并具有一定的防腐蚀性能。

In this paper, the orthogonal experimental analysis method is used to study on the effects of molar ratio of the unsaturated vinyl monomers, with carboxylic groups or sulphonic groups or polyoxyethylene side chain groups,etc., and the effects of the mean degree of polymerization in PEO side chains.

根据聚羧酸系高效减水剂的结构特点，采用正交试验分析法，分别研究了带羧基、磺酸基、聚氧化乙烯链酯基等活性基团的不饱和单体的物质的量之比及聚氧化乙烯链的聚合度等因素对聚羧酸系减水剂性能的影响，从而得出合成聚羧酸系高性能减水剂的一种最佳配方，并对试制产品进行了性能试验。

By way of orthogonal testing analysis,study was carried out on effects of molar ratio of unsaturated monomers with carboxylic groups,sulphonic groups,polyoxyethylene side chain groups and mean degree of polymerization of polyoxyethylene side chain groups on performance of polycarboxylic series of water reducer.

采用正交试验分析法，研究了带活性基团羧基、磺酸基、聚氧化乙烯链基等不饱和单体的摩尔比及聚氧化乙烯链的聚合度等对聚羧酸系减水剂性能的影响，提出一种合成聚羧酸系高性能减水剂的最佳配方。

A convenient method to synthesize three kinds of novel 2-(2-hydroxyphenyl) benzimidazole in order to improve the solubilities of the fluorophores with substituent of carboxyl, ester and double-bond which are aimed for determining the sulphydryl group was reported.

合成了N-{3-(2-苯并咪唑基)-4-羟基苯基}马来酰亚胺酸， N-{3-(2-苯并咪唑基)-4-乙酸酯基苯基}和马来酰亚胺N-{3-(2-苯并咪唑基)-4-羟基苯基}马来酰亚胺，在基本荧光发射团上分别引入了羧酸基；酯基；双键活性基团。

The mechanism of dioxygen oxidation of NTS to DNS in alkali solution under mild condition was inquired into. The result showed that the key step in the preparation of DNS from NTS was the formation of 4-nitro-2-sulfobenzyl anion as a result ionization of NTS in strong alkali and then oxidization to 4-nitro-2sulfobenzyl radical by activated dioxygen.

探讨了在温和条件下于碱的水溶液中氧气液相氧化4-硝基甲苯-2-磺酸制取4，4'-二硝基二苯乙烯-2，2'-二磺酸的反应机理，发现4-硝基甲苯-2-磺酸在碱作用下发生离子化生成4-硝基-2-磺酸基苄基阴离子，然后被活化的分子氧氧化成4-硝基-2-磺酸基苄基自由基是反应的关键步骤。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新