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In this paper the study on optimizing the esterification of cellulose and some character of CAB(the degree of substitution of cellulose, solubility, the thermal properties and molecular weight) was discussed. The mechanism of the esterification of cellulose in butyric acid/ acetic acid/ butyric anhydride which comprises the creation of the acetic butyric anhydride, acetyl cation and butyryl cation was investigated by the study of the effect of the content of the organic acid and anhydride on the degree of acetyl and butyryl substitution of cellulose.

最后本文根据纤维素在丁酸/乙酸/丁酸酐中的酯化反应中有机酸以及酸酐的添加量对最后产物纤维素醋酸丁酸酯中乙酯或者丁酯取代度的影响,提出纤维素在丁酸/乙酸/丁酸酐中的酯化反应经历一个混和酸酐以及乙酰碳正离子、丁酰碳正离子的生成过程。

The copolycondensation type polyamic acid was synthesized by using 3,3', 4,4'-Benzophenonetetracarboxylic dianhydride as the dianhydride monomer, 4,4'-Diamino diphenylmethane and 4,4'-Oxydianiline as the diamine monomer under microwave irradiation in Dimethylformamide.

在微波辐射条件下,采用3,3',4,4'-二苯酮四羧酸二酐、4,4'-二氨基二苯甲烷和4,4'-二氨基二苯醚为单体,N,N'-二甲基甲酰胺为溶剂,低温合成一种共缩聚聚酰亚胺的前驱体聚酰胺酸,化学亚胺化脱水环化生成BTDA型共缩聚聚酰亚胺。

Using 2-bromo-ethanesulfonic acid sodium salt ,α,ω- binary primary amine and dodecanoic acid as the main raw materials, drawing support from two-step synthesis of experiments—Alkylated reaction and Schotten-Baumann acylation, A series of LAS(12-s-12) gemini surfactants were synthesized.

并以2-溴乙基磺酸钠、α,ω-二元伯胺、月桂酸等为主要原料,借助胺基的烷基化和Schotten-Baumann酰基化反应制备了α,ω-烷撑-双钠盐LAS(12-s-12)表面活性剂,联结基团为亚甲基—(CH2)s—(S=2,4,6,8,12),取得以下进展

Bromoundecanoic acid was synthesized with 10-undecanoic acid and hydrobromic acid as raw materials.

以10-十一烯酸和溴化氢为原料合成11-溴代十一酸,考察了引发剂、溶剂、反应温度、后处理方法、熟化时间等因素对反应和产品的影响。

Bromoundecanoic acid was synthesized with 10-undecanoic acid and hydrobromic acid as raw materials. The effects of initiating agent, solvent, reaction temperature, the ways of disposal, ripening time etc. on the reaction and product were investigated.

以10-十一烯酸和溴化氢为原料合成11-溴代十一酸,考察了引发剂、溶剂、反应温度、后处理方法、熟化时间等因素对反应和产品的影响。

Isobutyl butyrate was synthesized from butyric acid and isobutyl alcohol using tungstosilicic acid as catalyst.

以钨硅酸为催化剂,通过桂酸和戊醇酯化反应合成桂酸戊酯,研究了各有关因素对产品酯化率的影响。

Niobic acid as a solid catalyst can be directly applied in the hydrolysis, esterification, condensation and alkylation reaction etc.

铌酸可直接作为固体催化剂,应用于水解、酯化、缩合、烷基化等反应中;铌酸也作为载体负载金属,应用于F-T合成、氧化反应和加氢等反应中;含铌化合物也可作为负载型催化剂,负载到不同类型的载体上;含铌化合物也作为助剂或光催化剂,广泛地应用于催化多种化学反应。

The effects of the spray-drying process of the ammonium paratungstate and the carburization temperature on the formation of the precusor and WC powder were investigated.

采用喷雾干燥-固定床法制备碳化钨粉末,研究了喷雾干燥和碳化反应温度对制备偏钨酸铵前驱体以及碳化钨的影响,前驱体粉末呈现均匀的球状形态,平均粒径为10~20μm,喷雾温度对影响粒径大小和分布影响小;400℃的进口温度下进行喷雾干燥,喷雾粉末仍然保持偏钨酸铵原来的基本组成不发生分解。

This research utilizes the method of organic synthesis to put different amount of aminophenol into hydroxybenzoic acid or caffeic acid so as to produce a series of high yield of polyhydroxy benzamides (1~40).Through the following different activity tests, discussing the applied value of cosmetics.Ⅰ.

摘要 本研究主要利用有机合成方法,将具有不同数量及在不同位置之羟基取代之安息香酸及咖啡酸分别与胺基苯酚化合物进行醯胺化反应,得到一系列高产率之多酚醯胺类衍生物(1~40),经由下列不同活性测试方法,探讨其化菻~上的应用价值。

Propargyl alcohol was protected by dihydrophran with the catalysis of PPTS ,and then reacted with Ethyl Mag bromide to prepare its corresponding Grignard reagent.

炔丙醇在 PPTS 催化下由二氢吡喃保护,与溴乙烷格氏试剂反应生成相应的格氏试剂,然后与氯甲酸甲酯反应得到羟基丁炔酸甲酯四氢吡喃醚,在 PPTS 催化下脱保护后进行甲磺酰化,由溴化钠进行溴取代后合成了4-溴-2-丁炔酸甲酯,总收率达53%。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。