酸值

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

It is seen that oxygen group function of additives is very remarkably in tribological characteristics, that is EP property of dihydroxy docosanoic acid without active element is very near to that of SO with active element sulfur.

双羟基廿二酸的极压性与不含氧基团的硫化烯烃十分接近，以液体石蜡为基础油，最大无卡咬负荷P〓值，前者为539N，后者为588N，再者相差49N，可以看出，氧基团的作用是十分显著的，即无活性元素的双羟基廿二酸的极压性可以十分接近于含活性元素的抗磨极压剂硫化烯烃。

The polyesters with terminal hydroxyl groups were prepared by condensation polymerization of adipic acid with 1,4-butanediol or ethylene glycol and, in some cases, a little amount of propylene glycol. The polyurethane thermoplastics were then prepared with the polyester, 4,4'-diphenylmethane diisocyanate and 1,4-butanediol.

采用己二酸、乙二醇(或加入少量1，2-丙二醇)和1，4-丁二醇制备了端羟基聚酯，并用该聚酯和4，4'-二苯基甲烷二异氰酸酯、1，4-丁二醇制备了聚酯型热塑性聚氨酯；考察了NCO/OH值、聚酯分子量等因素对热塑性聚氨酯的物理机械性能的影响。

Adding dividedly the solution of two drugs with different concentration into the heperplastic scar fibroblasts and keloid fibroblast which were in logarithmic growth phase. After 48 hours in vitro culture, hydroxyproline colorimetric test was conducted, then statistics comparison was carried out in accordance with hydroxyproline content which was calculated based on OD value.

向对数生长期的增生性瘢痕成纤维细胞及瘢痕疙瘩成纤维细胞中加入不同浓度的两种药液，培养48小时后进行羟脯氨酸比色试验，并将 OD 值依公式换算成羟脯氨酸含量，进行统计学比较。

The influences of the concentration and generation of polyamidoamine dendrimer, the ratio of dodecanoic acid to toluene, and pH in the water phase on the extraction yield of helianthine were systematically studied by selecting helianthine as the guest molecule and electrostatic self-assembled PAMAM as the host.

本文采用低支化树枝状大分子聚酰胺胺与月桂酸进行分子自组装得到了一系列具有稠密的疏水性外围和亲水性内核的自组装大分子，再以自组装大分子为宿主，系统地研究了树枝状大分子聚酰胺胺的浓度、支化代、月桂酸与甲苯的质量比及水相pH值对客体分子甲基橙相转移行为的影响规律。

Conclusion］ The change of pH value of solution had effect on degree of ionization of fumaric acid,and then affected the adsorption quantity of basic resin on fumaric acid.

结论］溶液pH值的变化影响富马酸的离子化程度，进而影响碱性树脂对富马酸的吸附量。

In this experiment we use the alcohol to replace the Fumaric acid and using the NaOH and HCl to control the pH number.

而本实验就是以过锰酸钾加入酒精以代替过去使用的反丁烯二酸并以HCl及NaOH来调控其酸碱值并比较其反应后的各种性质。

The soil pH was found to be the main factor affecting BR formation of 14 C\|metsulfuron methyl among the basic properties of soil.(2)During the whole periods of the incubation,the 14 C\|BR of 14 C\|metsulfuron methyl in soils was mainly distributed in fulvic acid and humin.The relative percentage of 14 C\|BR in fulvic acid was higher than in humin,while the content of the 14 C\|BR distributd in humic acid only account for less than 1% of applied amount.

土壤pH是14 C 甲磺隆在土壤中形成BR的主要影响因子。14 C -甲磺隆在各类土壤中的14 C BR的最大值分别占引入量的 48 5%、46 5%、52 6%、1 9 3 %、49 7%、42 0 %和 46 5%；( 2 )在整个培养试验过程中，14 C 甲磺隆在 7种不同类型土壤中的14 C BR ，主要分布在富啡酸和胡敏素中，前者中的相对百分比大于后者，而在胡敏酸中的相对百分比较小。

Firstly, polyacrylamide with 26 million molecular weight was compounded in lab through establishing optimum compounding initiator proportionality of 1:1. 3 and mass concentration of 170 mgL^(-1), temperature of 10 ℃, acrylamide mass percentage of 25%, electrical conductivity of 3.6 μSm^(-1) and pH value of 6.57. The salt-resistance, thermal endurance and shear-resistance of polyacrylamide could be enhanced b introducing sulfonic acid group or styrene sulfonate group or drawing the two groups above at the same time. Secondly, chelator HEDP, bactericide isoquinoline ketone and oxygen scavenger thiourea were optimized to improve the compatibility of polyacrylamide and formation water.

在由室内试验确定了复合引发剂最佳比值1：1.3和质量浓度170 mgL^(-1)、合成最佳温度10℃、丙烯酰胺单体质量分数25%、电导率3.6μSm^(-1)和pH值6.57后，合成出相对分子质量高于2.6×10^7的聚丙烯酰胺，同时通过丙烯酰胺单体复配引入磺酸基团、苯乙烯磺酸基团或同时引入此两种基团，提高了聚合物的抗盐、抗温、抗剪切性能；后针对聚丙烯酰胺与地层水配伍性差的问题，优选出HEDP螯合剂、异噻唑烷酮杀菌剂和除氧剂硫脲，对聚合物稳定效果明显。

In this paper,we synthesized five new tungstosilicates clusters by using differert lacunary Keggin species in different pH values,temperatures under ambient conditions.

中文摘要：本论文中，在室温条件下，我们通过使用不同的多酸Keggin缺位片段、控制不同的PH值、反应温度、反应时间，合成得到五个新型多钨酸盐簇。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。