酰胺化

To avoid the influence of ammonolysis, alcoholysis and hydrolysis on molecular structure identification, in this paper, derivational estimation is utilized to confirm molecular structures ofβ-naphthol-containing sulfonyl chloride intermediates. Then the structures of corresponding sulfonamide dyes are also confirmed by FTIR,~1H NMR and mass spectrometry.

为了避免磺酰氯化合物发生水解、醇解和胺解等衍生化反应影响磺酰氯化合物分子结构表征，本文采用衍生化反推法证明了β-萘酚结构磺酰氯化合物的分子结构，并利用红外光谱、核磁共振氢谱、质谱表征了含β-萘酚结构磺酰胺染料的分子结构。

Water,Hydrogenated Polyisobutene,Cyclohexasiloxane,Glycerin,Alcohol Denat,Cetearyl Alcohol,PEG-20,Petrolatum,C13-14 Isoparaffin,Zea Mays Oil,Tocopheryl Acetate,Hydroxypropyl Tetrahydropyrantriol,Hydrolyzed Soy Protein,CI 14700/Red 4,Phenoxyethanol,Adenosine,PEG-100 Stearate,Ethylparaben,Triethanolamine,Polyacrylamide,Malus Domestica Stem Cell Culture,CI 19140/Yellow 5,Dimethyl Isosorbide,Dimethicone,Dimethiconol,Limonene,Xanthan Gum,Pentaerythrityl Tetra-Di-T-Butyl Hydroxyhydrocinnamate,Linalool,2-Oleamido-1,3-Octadecanediol,Capryloyl Salicylic Acid,Acrylates/C10-30 Alkyl Acrylate Crosspolymer,Passiflora Edulis Seed Oil,Disodium EDTA,Castanea Sativa Seed Extract,Butyrospermum Parkii· Cetyl Alcohol,Butylene Glycol,Octyldodecanol,Cetearyl Glucoside,Methylparaben,Citronellol,Prunus Armeniaca Kernel Oil,Laureth-7,Coumarin,Oryza Sativa Bran Oil,Glyceryl Stearate,Fragrance

水，甘油，氢化聚异丁烯，液体石蜡/矿油，丁二醇，环己硅氧烷，鲸蜡醇，甘油硬脂酸酯，棕榈油，玉米胚芽油，PEG-100硬脂酸酯，白蜂蜡/蜂蜡，肉豆蔻醇肉豆蔻酸酯，石蜡，香精，腺苷，苧烯，山梨醇，CI 14700，CI 19140，稻糠油，杏仁油，EDTA二钠，羟丙基四氢吡喃三醇，苯氧乙醇，聚乙二醇-14M，异十六烷，氢氧化钠，辛基十二醇，季戊四醇四（双-t-丁基羟基氢化肉桂酸）酯，山梨坦三硬脂酸酯，水解大豆蛋白，卡波姆，鸡蛋果籽油，苹果果实提取物，欧洲栗籽提取物，异山梨醇酐二甲醚，聚山梨醇酯-80，辛酰水杨酸，2-油酰胺基-1，3-十八烷二醇，氯苯甘醚，麦芽糖醇，香豆素，黄原胶，微晶蜡，丙烯酰胺/丙烯酰基二甲基牛磺酸钠共聚物，丙二醇，芳樟醇，香茅醇，玉米油，羟苯丙酯，羟苯甲酯

Besides,through Arbuzov reaction,Vilsmer-Haack Hydroformylation,Wittig-Horner reaction,nitryl hydrogenation deoxidize,and imidization five steps synthesized another compound which included hole-transporting,electron-transporting and luminescence materials.

此外，又通过Arbuzov反应、Vilsmer-Haack甲酰化反应、Wittig-Horner反应生成二苯乙烯、硝基加氢还原、酰亚胺化5步反应合成了一种集空穴传输-电子传输-发射三位一体的新型苝酰亚胺化合物。

The preparation process of self-holing polyimide with organosilicon block includes the following steps: 1 the first reaction of polyacid anhydride in functionality not lower than 2, silicon oil with 2 or more amino or imino groups and polyamine with 2 or more amino groups, and the second reaction with one or several kinds of added isocyanate with 2 or more isocyanate radicals to produce sol of polyamido acid containing organosilicon block; 2 solidifying the sol to obtain solid polyamido acid containing organosilicon block; and 3 imidonating the solid to obtain self-holing polyimide with organosilicon block.

本发明公开了一种有机硅嵌段自发孔聚酰亚胺的制备方法，该方法包括以下步骤：(1)有机溶剂中具有大于或者等于2的酸酐官能团度的多酸酐与具有大于或者等于2的胺基或亚胺基的硅油以及具有大于或者等于2的胺基的多胺反应，随后添加一种或多种具有含有等于或者大于2个异氰酸酯基的异氰酸酯反应，生成含有机硅嵌段聚酰胺酸的溶胶。(2)溶胶固化制成有机硅嵌段聚酰胺酸固体。(3)固体亚胺化，即得有机硅嵌段自发孔聚酰亚胺。

The glutamine synthetase produced by the engineering bacteria can specially act on NH4 and aminoglutaric acid, the durability to the high concentration ammonium ion has been distinctively improved because of the dissolution of adenosine acylation modification, the major bottleneck of glutamine with enzymatical production has been solved, and the concentration of the obtained glutamine can reach 47.6g/L.

本发明工程菌产的谷氨酰胺合成酶可专一性的作用于NH 4 和谷氨酸，且因解除了腺苷酰化修饰作用对高浓度铵离子的耐受能力显著提高，解决了酶法生产谷氨酰胺的重要瓶颈，生成的谷氨酰胺的浓度最高达到47.6g/L。

Bis-(4-bromobenzoyl) benzene as the monomer of poly was synthesized by Friedel-Crafts benzoylation reaction. Poly-Ⅱ synthesized via palladium-catalyzed aryl amination reaction using 1, 4-bis-(4-bromo-benzoyl) benzene and 4, 4'-diaminodiphenyl ether as monomers.

通过傅－克酰基化反应合成了1，4-双－（4'-溴苯酰基）苯，以1，4-双－（4'-溴苯酰基）苯和4'4-二氨基二苯醚为单体，通过钯催化的胺基化缩聚反应合成了高性能聚合物－聚亚胺酮－Ⅱ。

The copolycondesation type polyamic acid was synthesized by using pyromellitic dianhydride and 3,3',4,4'-benzophenonetetracarboxylic dianhydride as the dianhydride monomers, 4,4'-diamino diphenylmethane and 4,4'-oxydianiline as the diamine monomers under microwave irradiation in dimethylformamide.

在N，N'-二甲基甲酰胺溶剂中，以均苯四甲酸酐和3，3'，4，4'-二苯酮羧酸二酐为二酐单体，4，4'-二氨基二苯醚和4，4'-二氨基二苯甲烷为二胺单体，采用微波辐射低温溶液共缩聚，合成了聚酰胺酸预聚体，然后亚胺化脱水、环化，生成共缩聚聚酰亚胺。

The influences of the concentration and generation of polyamidoamine dendrimer, the ratio of dodecanoic acid to toluene, and pH in the water phase on the extraction yield of helianthine were systematically studied by selecting helianthine as the guest molecule and electrostatic self-assembled PAMAM as the host.

本文采用低支化树枝状大分子聚酰胺胺与月桂酸进行分子自组装得到了一系列具有稠密的疏水性外围和亲水性内核的自组装大分子，再以自组装大分子为宿主，系统地研究了树枝状大分子聚酰胺胺的浓度、支化代、月桂酸与甲苯的质量比及水相pH值对客体分子甲基橙相转移行为的影响规律。

The latices were stable ,thixotropic and monodisperse .The particle sizes range from 192 to 94 nm depending on the acrylamide fractions. The Hofmann reactions of these latices were carried out to introduce primary amines on the particle surface.

由于一直以来，丙烯酰胺-苯乙烯的共聚物胶乳只能用于制备两性胶乳，为了得到较高的胺化度，我们对不同单体配比的丙烯酰胺-苯乙烯共聚物胶乳进行Hofmann反应，探讨了丙烯酰胺在单体中所占的比例对Hofmann反应的影响。

Based on the comparison of the infrared spectra of polyamide homologues, on the changes in the infrared spectra of deuterated and iodine-treated samples of polycaprolactam, and also on the observations of the infrared dichroism of drawn film, the main absorption bands of polycaprolactam in the region 400 cm(-1)-1400cm-1, which are rather structure sensitive, have been assigned as follows: 1370 cm-1 band-VC-N;, 1265 cm-1 and 1205 cm-1 bands-; 1170 cm-1 band-VC-N; 730 cm-1 band-γCH2 of (CH2)n when n≥...

根据对聚酰胺类高聚物红外光谱的类比和对聚酰胺6试样进行氘化和碘处理后红外光谱的改变，以及根据对拉伸过的聚酰胺6薄膜试样的偏振红外光谱的观察，我们对聚酰胺6红外光谱中400cm~(-1)—1400cm~(-1)之间的主要吸收带，作了如下解释：1370cm~(-1)吸收带为ν_；1265cm~(-1)和1205cm~(-1)吸收带为δ_+ν_；1170cm~(-1)吸收带为ν_；730cm~(-1)吸收带为γ_(CH_2)[当(CH_2)_n的n≥4时]；690cm~(-1)吸收带为δ_；580cm~(-1)吸收带亦为δ_。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。