酰胺化

A photoresist composition including a polymer is disclosed, wherein the polymer includes at least one monomer having the formula: wherein, R1 is selected from H, linear, branched or circular alkyl with 1-20 carton atoms, linear, branched or circular alkyl with 1-20 C atom, which is perfluorinated or semi-perfluorinated; and CN; R2 is alicyclic group with 5 or more carbon atoms; X is selected from methylene, aether, ester, amide and the connecting part of the carbonate; R3 is linear or branched alkylene with one or more carbon atoms or perfluorinated or semi-perfluorinated linear or branched alkylene; R4 is selected from H, CH3, CF3, CHF2, CH2F and perfluorinated or semi-perfluorinated aliphatic group; R5 is selected from the CF3, CHF2, CH2F and perfluorinated or semi-perfluorinated substituted and unsubstituted aliphatic group; n is 1 or higher integer; OR12 is OH or at least an acid unstable group selected from the tert-alkyl carbonate, tert-alkyl ester, tert-alkyl aether, acetal and ketal.

本发明公开了一种包含一种聚合物的光刻胶组合物，该聚合物包括至少一种具有下列结构的单体：其中，R 1 选自氢、具有1～20个碳原子的线形、支化或环状烷基、半氟化或全氟化的具有1～20个碳原子的线形、支化或环状烷基、以及CN；R 2 为具有5个或更多个碳原子的脂环基团；X为选自亚甲基、醚、酯、酰胺和碳酸酯的连接部分；R 3 为具有1个或多个碳原子的线形或支化亚烷基或者半氟化或全氟化的线形或支化亚烷基；R 4 选自氢、甲基(CH 3 )、三氟甲基(CF 3 )、二氟甲基(CHF 2 )、氟代甲基(CH 2 F)、以及半氟化或全氟化的脂族基团；R 5 选自三氟甲基(CF 3 )、二氟甲基(CHF 2 )、氟代甲基(CH 2 F)、以及半氟化或全氟化的取代或未取代的脂族基团；n为1或更大的整数；OR 12 为OH或者选自叔烷基碳酸酯、叔烷基酯、叔烷基醚、缩醛和缩酮的至少一种酸不稳定基团。

Using 2-bromo-ethanesulfonic acid sodium salt ,α,ω- binary primary amine and dodecanoic acid as the main raw materials, drawing support from two-step synthesis of experiments—Alkylated reaction and Schotten-Baumann acylation, A series of LAS(12-s-12) gemini surfactants were synthesized.

并以2-溴乙基磺酸钠、α，ω-二元伯胺、月桂酸等为主要原料，借助胺基的烷基化和Schotten-Baumann酰基化反应制备了α，ω-烷撑-双钠盐LAS(12-s-12)表面活性剂，联结基团为亚甲基—(CH2)s—(S=2，4，6，8，12)，取得以下进展

American Dupont NOMEX fragrant gathers the amide paper, it is (chromatographic analysis textile fiber and short fiber) is composed of two kind of shape aromatic polyamide polymer, uses the special papermaking or the system board method, agglutinates Cheng Jibo the fibrous reticulum, undergoes high temperature high pressure processing, carries on the densification and the calendering causes them reliable to fix lowly in the same place, becomes not penetrable, electrical and mechanicalness energy level high whole.

美国杜邦NOMEX芳香聚酰胺纸，它是是由两种形态的芳香族聚酰胺的聚合物组成，使用特殊的造纸或制板方法，粘合成极薄的纤维网，经过高温高压处理，进行密化和轧光使它们牢固低固定在一起，成为不可渗透的，电气和机械性能极高的整体。

Originally limited to dialkylamino methylenation, the application of Mannich reaction has been expanded much further in recent years to a wide variety of monosubstituted amines, amine equivalents and amides. In addition, a variety of Aza-Mannich and Mannich-Michael methodologies have emerged.

最初该反应的应用范围仅局限于二烷基胺亚甲基化反应，近年来才得到了长足的发展，其研究范围扩展到单取代的胺、胺的类似物以及酰胺等化合物，并发展形成Aza-Mannich和Mannich-Michael等复合Mannich反应。

The copolymer of N isopropylacrylamide and acrylamido azobenzene was synthesized for the study of the effect of the photoisomerization of a water soluble copolymer containing azobenzene groups on the photocontrolled release behavior of liposomes.

为了研究侧链含有偶氮苯基的水溶性共聚物的光异构化对脂质体内包容物的光控释放的影响，设计合成了N－异丙基丙烯酰胺和丙烯酰胺基偶氮苯的共聚物。

A series of polyimide/talc composite films with different contents of talc were prepared via thermal imidization of in-situ polymerized poly/talc solutions based on pyromellitic anhydride, 4,4'-oxydianiline and talc.

用原位聚合法合成一系列不同滑石粉含量的聚酰胺酸／滑石粉溶液，再将其热酰亚胺化制备出聚酰亚胺／滑石粉复合薄膜。

The phosphorus oxychloride or phosphorus tribromide N, N-dimethylformamide mix and react to form the Vilsmeier reagent used in the reaction. The newly prepared Vilsmeier reagent is added into the reaction bottle provided with the return condenser and the blender; a reaction raw material N, N-dimethylformamide solution expressed in the reaction formula is added into the system; the temperature is risen; the corresponding multi substituting pyridine-2 (1 H)-ketone compound can be made after the column chromatography of the silica gel; the production rate is between 60 and 95 percent according to different reactions.

由三氯氧磷或三溴化磷N，N-二甲基甲酰胺混合获得反应中所用Vilsmeier试剂；将新配制的Vilsmeier试剂加入装有回流冷凝管、搅拌器的反应瓶中，向体系中加入反应通式中表示的一种反应原料的N，N-二甲基甲酰胺溶液，升温，经硅胶柱层析分离得相应的多取代吡啶-2(1H)-酮类化合物，产率视不同反应在60~95％之间。

Results showed that there were the morphological changes of mitochondria, such as vacuolization, degeneration and cristae swelling or disappearance, in HT-29 cells treated by C2-ceramide for 24 hours. Under the fluorescence microscope, mitochondria of apoptotic cells aggregated and emitted red fluorescence, however, mitochondria of normal cells emitted green fluorescence. The mitochondrial membrane potential began to decrease after 6 hours in HT-29 cells treated with C2-ceramide in time and dose dependent manner.

结果显示C2-神经酰胺作用HT-29细胞24小时，线粒体发生空泡化、变性、嵴肿胀或消失等形态学改变；此时荧光显微镜下可观察到线粒体聚集，发出红色荧光，而正常细胞线粒体发出绿色荧光。C2-神经酰胺作用细胞6小时，线粒体膜电位即开始降低，呈时间-剂量-效应关系。

Two new methods about preparation of nano-inorganic coated polymer microsphere have been found. The research mainly focused on controlled precipitation of inorganic precurdors onto the polymer microspheres, technique of preparation and size distribution of transition metal oxides and sulfides emulsion particles, nano-paticles''surface modification and the HLB values adjustment, emulsification of oil-soluble monomer in inorganic colloid and emulsion stability, emulsion polymerization that inorganic particles act as medi-phase, the preparation of inorganic nano-particle/polymer hybrid microspheres, preparation of hybrid materials in inverse emulsion, inverse emulsion polymerization of acrylamide and its phase behavior. Inorganic nano-particles we studied concerning TiO2、SiO2、Fe3O4、ZnO、ZnS、Ag and black carbon. Also we studied the morphology and capability of the hybrid materials.

主要内容有：无机物在高分子乳胶模板体系的界面定位沉积研究；过渡金属氧化物、硫化物纳米胶体粒子的制备工艺与胶粒尺寸分布研究；纳米粒子的表面修饰及其亲水亲油平衡值的调制；油溶性单体在无机胶体中的乳化行为与乳液稳定性研究；以无机纳米粒子做中介相的乳液聚合与无机纳米粒子/高分子复合微球制备研究；反相体系中杂化材料的制备；丙烯酰胺水溶液反相乳液聚合、相行为与稳定性；丙烯酰胺反相体系中无机粒子的制备研究；涉及到TiO2、SiO2、Fe3O4、ZnO、ZnS、Ag、碳黑等纳米无机物，系统考察了相关材料的形态与性能，为其应用开发奠定了基础。

The pKa values of the amide nitrogen atom are calculated at various hybridization states in amides.

在酰胺中，计算了不同杂化状态时，酰胺氮原子的不同pKa值。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。