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Objective To research the effects of a chiral aminoalcohol in the asymmetric allylation of acylhydrazones.

目的 研究手性氨基醇在酰腙不对称烯丙基化反应中的促进作用。

E. value of productions were detected by high performance liquid chromatography. Results The chiral aminoalcohol ligand compound Ⅰ can promote the asymmetric allylation of acylhydrazones and the yield was 57%; The highest values of e. e. obtained for this reaction was 22%.

结果 手性氨基醇配体化合物Ⅰ能够促进烯丙基三氯硅烷和酰腙的烯丙基化加成反应,在它的辅助作用下,烯丙基化加成产物的产率可达到57%,对映体过量值最高达到22%。

The most commonly used method for the covalent binding of biomolecules onto 1-D nanostructures is through the diimide-activated amidation of carboxylic acid terminated nanostructures.

最常用的方法是通过端羧酸基纳米结构的二酰亚胺活化氨基化合物来进行生物分子与1-D纳米结构的共价结合。

Polyimide/nano carborundum composite films were made from pyromellitic dianhydride、4, 4'-aminodiphenyl ether、N, N'-dimethyl acetamide and nanometer carborundum.

以均苯四甲酸二酐、4,4'-二氨基二苯醚、N,N'-二甲基乙酰胺为原料,经化学合成反应制备了聚酰亚胺/纳米碳化硅复合薄膜。

Poly-[N-(2-hydroxyethyl)-L-glutamine] was then obtained by aminolysis of PBLG with 2-aminoethanol.

以L -谷氨酸为单体,经r -羧基的苄基保护,与光气/甲苯液反应制备L-谷氨酸苄酯的羧酸酐,均聚得L -谷氨酸苄酯,然后经由 2 -氨基乙醇胺解得聚 [N -( 2 -羟乙基)-L -谷酰胺 ] 。

Methods Compound 3 was got via the formation of the amide from 2-chloro-3-amino-4-methyl pyridine and 2-chloronicotinoyl chloride, and then nevirapine was acquired by the aminolysis of 3 with cyclopropylamine in an autoclave, followed by the intramolecular nucleophilic substitution.

以2-氯-3-氨基-4-甲基吡啶为原料,依次与2-氯烟酰氯缩合成化合物3、再与环丙胺高压氨解、最后发生分子内亲核取代反应,成功合成了奈韦拉平。

The amphoteric fatliquor of N-amidel- polyethylene polyamine -β-aminopropionic acid types has been synthesized by nature oil and fat reaction with polyethylene polyamine and acrylic acid .

用天然油脂、多乙烯多胺和丙烯酸合成制得N -酰胺基多乙烯多胺-β-氨基丙酸型两性加脂剂,最佳合成条件分两步的反应温度分别控制在 10 0℃及 12 0℃、两步反应时间分别为 2h和 4h ,天然油脂与多乙烯多胺及丙烯酸的物质量的比为 1:0 。

Rizaben ; N -(3; 4 - dimethoxycinnamoyl)- anthranilic acid ; compounded solvent ; synthesis

曲尼司特; N-(3; 4-二甲氧基肉桂酰);邻氨基苯甲酸;复合溶剂;合成

Rizaben was synthesized directly from anthranilic acid ,3,4- dimethoxy cinnamic acid, and benzene sulfochloride using 3EA/pyridine as compounded solvent.

采用3EA/吡啶复合溶剂,以邻氨基苯甲酸、3,4-二甲氧基肉桂酸和苯磺酰氯为原料直接合成曲尼司特。

Phthalimide,anthranilic acid,2methyleneglutaronitrile bromina 1bromobutane 1,2benzisothiazole3one.

邻苯二甲酰亚胺,邻氨基苯甲酸,2亚甲基戊二脯,2溴2溴甲基戊二脯,溴代正丁烷,1.2苯并异噻唑3酮。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

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