酰氨基

The main study of this dissertation is shown as follows.1.Two new amphiphilic steroid derivatives(N-cholesteryl succinyl glucosamine, CSG and N-deoxycholyl glucosamine,DCG) were designed and synthesized.Their chemical structures have been confirmed by means of Fourier Transform Infrared Spectrometry,Nuclear Magnetic Resonance Spectrometry and Mass Spectrometry.

设计、合成了新型的两亲性甾族衍生物—N-胆固醇琥珀酰基氨基葡萄糖(N-cholesteryl succinyl glucosamine，CSG)和N-脱氧胆酰基氨基葡萄糖(N-deoxycholyl glucosamine，DCG)，并采用傅立叶红外波谱仪(Fourier TransformInfrared Spectrometry，FT-IR)、核磁共振波谱仪(Nuclear Magnetic ResonanceSpectrometry，NMR)和质谱等分析仪器对原料、中间产物和最终产物的化学结构进行表征。

Rhodamine B, Malachite green, Auramine O, Bismark Brown,Methyl Violet 5BN, Basic Magenta, Acid Orange II, Chrysophenine GX, Direct Fast Black G, Indigo, Sulphur Black, Solvent Red 24, Solvent Red 49, Solvent Brown 41, Solvent Orange 3,Pigment Yellow 154,155, Pigment Red 188,208, Meta-Diethyiaminophenol, M-Amino acetanilide , P-Amino acetanilide, etc.

主要产品：碱性玫瑰精，碱性品绿，碱性嫩黄O，碱性品红，碱性紫5BN，碱性红6DDN，酸性橙II，靛蓝，硫化黑，直接冻黄，直接黑G，溶剂红24，溶剂红49，溶剂棕41，溶剂橙3，溶剂橙62，颜料黄154，155，颜料红188，208，间羟基－N，N－二乙基苯胺，间氨基乙酰苯胺，对氨基乙酰苯胺。

The photoproducts of CCU in organic solvents have also been identified with HPLC- and GC-MS. The photoproducts identified in methanol are isocyanato bezene, 4-chlorophenyl isocyanate, 2-chloro benzamide, chlorobenzene, 4-chlorophenyl urea, N-phenyl methylcarbamate, N-(4chlorophenyl) methylcarbamate, and 2-chloro-N-(4-chlorophenyl) benzamide.

对灭幼脲在各种有机溶剂中的光解产物作HPLC/UV和GC-MS鉴定，发现其在甲醇中的光解产物含有：异氰酸苯酯、对氯苯基异氰酸酯、邻氯苯甲酰胺、氯苯、对氯苯基脲、N-苯基氨基甲酸甲酯、N-氨基甲酸甲酯、以及N-邻氯苯甲酰胺等。

Similarly, 5TPS-AVB〓 or 5-TPS-IVB〓 reacted with carbamino chloride or phosphoryl chloride in IM/DMAP system to produce six new 4"-carbamates or 4"-phosphorylates in good yields.

LA-47与氨基甲酰氯和磷酰氯反应，得到3个对应的5-4-TPS-AVB〓氨基甲酸酯或膦酸酯衍生物，产率良好。

Co condensation type polyamides were prepared by using 1,2 dihydro 2 (4 aminophenyl) 4 [4 (4 aminophenoxyl) phenyl] phthalazin 1 one and 4,4′ diamino biphenyl ether or 4,4′ diamino biphenyl methane as the co diamine monomers and aromatic diacid as the co condensation monomer.

采用 1 ，2 -二氢-2 -( 4-氨基苯基)-4 -[4 -( 4-氨基苯氧基)-苯基 ]-二氮杂萘-1 -酮、4 ，4′-二氨基二苯醚、4 ，4′-二氨基二苯甲烷为共缩聚二胺单体与对苯二甲酸进行共缩聚反应，制备共缩聚型聚酰胺。

The copolycondensation type polyamic acid was synthesized by using 3,3', 4,4'-Benzophenonetetracarboxylic dianhydride as the dianhydride monomer, 4,4'-Diamino diphenylmethane and 4,4'-Oxydianiline as the diamine monomer under microwave irradiation in Dimethylformamide.

在微波辐射条件下，采用3，3'，4，4'-二苯酮四羧酸二酐、4，4'-二氨基二苯甲烷和4，4'-二氨基二苯醚为单体，N，N'-二甲基甲酰胺为溶剂，低温合成一种共缩聚聚酰亚胺的前驱体聚酰胺酸，化学亚胺化脱水环化生成BTDA型共缩聚聚酰亚胺。

The copolycondesation type polyamic acid was synthesized by using pyromellitic dianhydride and 3,3',4,4'-benzophenonetetracarboxylic dianhydride as the dianhydride monomers, 4,4'-diamino diphenylmethane and 4,4'-oxydianiline as the diamine monomers under microwave irradiation in dimethylformamide.

在N，N'-二甲基甲酰胺溶剂中，以均苯四甲酸酐和3，3'，4，4'-二苯酮羧酸二酐为二酐单体，4，4'-二氨基二苯醚和4，4'-二氨基二苯甲烷为二胺单体，采用微波辐射低温溶液共缩聚，合成了聚酰胺酸预聚体，然后亚胺化脱水、环化，生成共缩聚聚酰亚胺。

Keywords acylhydrazone;sulfamic acid;N-aminophthalimide;fine chemical intermediate

酰腙； 氨基磺酸； N-氨基邻苯二甲酰亚胺；精细化工中间体

All of the tripodal schiff base ligands and their complexes were characterized.

以三乙醇胺、巯基苯胺、巯基乙胺为初始原料，设计合成了六个三脚架结构的化合物，其合成路线如下：三乙醇胺与氯化亚砜反应得到三(2-氯乙基)胺(1)，然后与巯基苯胺或巯基乙胺在碱性条件下反应生成三脚架结构的三{[2-(2-氨基苯基)硫代]乙基}胺(2)或三{[2-(2-氨基乙基)硫代]乙基}胺(3)，然后再与水杨醛、2-甲酰基-8-羟基喹啉(8)、2-甲酰基-8-苄氧基喹啉(7)反应得到六种新型的含硫西佛碱化合

The kinetic approach of the substrate reaction during modification of enzyme activity has been applied to a study on the kinetics of the course of inactivation of metal enzyme by metal ion chelator and reactivation of apo-enzyme by metal ion restoration.

应用邹承鲁先生建立的底物反应动力学的理论研究了含金属锌离子的氨基酰化酶在金属螯合剂的作用下去金属失活的动力学研究和去金属失活的氨基酰化酶与金属离子重组恢复活性的动力学过程的研究中。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。