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酰氨基

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The methylated amidogen still held protonation at low pH. Therefore, the adsorption ability of biomass was almost unchangeable through methylation of amidogen in biomass. The acetylated amidogen lost protonation at low pH, and the capacity of dye adsorption of biomass decreased by 51.6% after acetylation of amidogen in biomass.

甲基化氨基在酸性条件下仍然可以质子化,故氨基甲基化修饰后染料吸附性能不变;乙酰化氨基在酸性体系中失去质子化能力,乙酰化修饰菌体染料吸附性能下降51.6%。

The cis novel bisoxazoline ligands L1-L4 have been synthesized through the treatment of new cis dihydroxy diamide with p-toluenesulfonyl chloride in the presence of catalytic quantity of 4--pyridine, and the cis dihydroxy diamide could be achieved from the condensation of the amino alcohols and cis cyclopropane dicarbonyl chloride prepared via oxidation and halogenation from cis-2,2-dimethyl-3-formylcyclopropanecarboxylate with DCC.

我们以蒈醛酸内酯为起始原料,经过氧化反应、酰氯化反应得到顺式环丙烷二酰氯,然后在二环己基碳二亚胺的催化下与相应的氨基醇反应合成了顺式二羟基酰胺,再用对甲苯磺酰氯将羟基活化,最后在二甲氨基吡啶的催化下关环合成顺式双噁唑啉配体L1~L4。

A series of diazonium salts of 4-(N-methyl-N-phenylamino)-3-amino-1,8-naphthalic anhydride 5a, its naphthalimide derivative 5b, and 5e were designed and synthesized,and it was the first time to discover that aromatic radical-induced intramolecular aromatic 1, 5-hydrogen transfer was also involved in the nitrogen-contianed system during Pschorr cyclization.

实验设计合成了4--3-氨基-1,8-萘酐的重氮盐5a、其衍生物N-丁基-4--3-氨基-1,8-萘酰亚胺的重氮盐5b和N--4--3-氨基-1,8-萘酰亚胺的重氮盐5c,并首次发现了通过普朔尔环化反应以氮甲基化的氮为桥原子的体系存在着芳香自由基诱导的芳香1,5-氢转移。

In our paper,1-hexylcarbamoyl-5-fluorouracils and1-cyclohexyl-carbamoyl-5-fluorouracils were prepared through 5-fluorouracil reacting with hexyl isocyanate or cyclohexyl isocyanate by using dimethylaminopyridine as the catalyst.

以5-氟尿嘧啶(5-FU)、正己基异氰酸酯和环己基异氰酸酯为原料,在N,N-二甲氨基吡啶的催化下,通过N-脲化反应制成1-己基氨基甲酰基-5-氟尿嘧啶及1-环己基氨基甲酰基-5-氟尿嘧啶。

The protonation constants of formylformic acid thiosemicarbazone (A, H2FFTSC) and glycylglycine and stability constants of binary complexes formed they with Mn, Co, Ni, Cu and Zn and trinary complexes of M-FFTSC-GG at 25±0.1℃ and in the presence of 0.1 mol.L-1 KNO3 were determined. The relation between the stability of binary complexes of M-FFTSC and their disinfectivity and disinfection mechanism were discussed.

在25±0.1℃,I=0.1 mol.L-1 KNO3条件下,应用pH法测定了甲酰基甲酸缩氨基硫脲(A配体,缩写H2FFTSC),甘氨酰甘氨酸的质子化常数,它们与锰、钴、镍、铜和锌的二元配合物以及过渡金属-甲酰基甲酸缩氨基硫脲-甘氨酰甘氨酸三元配合物稳定常数,讨论了过渡金属席夫碱配合物的杀菌活性与其稳定性之间的关系,对杀菌机理提出了一些看法。

To understand the reaction of tetrakis hydroxymethyl phosphonium chloride with collagen protein,the interactions of THPC with polycaprolactam,poly vinyl alcohol or ethylenediamine which were used as the model substances of amido,hydroxy and amino groups of collagen protein were examed.

通过研究THPC与聚己内酰胺、聚乙烯醇、乙二胺的酰胺基、羟基、氨基的反应,间接证明THPC主要与胶原蛋白的氨基结合,可与氨基以n∶n=1.0∶2.2形成交联,THPC与羟基和酰胺基均有少量结合,并在pH=8.0时结合量最高。

2A series of alternating polyamide-imideswith fluorenyl cardo structure was synthesized by "one-pot" polycondensation of cardo diamines,trimellitic anhydride and various aromatic diamines including p-phenylene diamine,m-phenylene diamine, 4,4\'-oxydianiline,3,4\'-oxydianiline,2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(3-aminophenoxy)phenyl]propane respectively using triphenyl phosphite as condensing agents.

采用&一锅法&(One—pot Synthesis),由Cardo二胺、偏苯三酸酐和不同二胺包括对苯二胺、间苯二胺、4,4\'—二氨基二苯醚、3,4\'—二氨基二苯醚、2,2—双[4—(4—氨基苯氧基苯基]丙烷和2,2—双[4—(3—氨基苯氧基)苯基]丙烷合成了一系列含有芴基Cardo结构的交替聚酰胺酰亚胺。

2A series of alternating polyamide-imideswith fluorenyl cardo structure was synthesized by "one-pot" polycondensation of cardo diamines,trimellitic anhydride and various aromatic diamines including p-phenylene diamine,m-phenylene diamine, 4,4\'-oxydianiline,3,4\'-oxydianiline,2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(3-aminophenoxy)phenyl]propane respectively using triphenyl phosphite as condensing agents.

采用&一锅法&O(来源:88AB57C论文网www.abclunwen.comne—pot Synthesis,由Cardo二胺、偏苯三酸酐和不同二胺包括对苯二胺、间苯二胺、4,4\'—二氨基二苯醚、3,4\'—二氨基二苯醚、2,2—双[4—(4—氨基苯氧基苯基]丙烷和2,2—双[4—(3—氨基苯氧基)苯基]丙烷合成了一系列含有芴基Cardo结构的交替聚酰胺酰亚胺。

The intermediate which obtained from oximation of 7a-e reacted withmethyl N-(2-bromomethylphenyl)-N-methoxycarbamate to synthesize oxime ether methyl carbamate 3a-e.

以邻位卤代苯甲醛和3-丁烯-2-醇为原料通过钯催化&一锅法&反应合成了2-乙酰基茚7a-e,7a-e 肟化之后和N-(2-溴甲基苯基)-N-甲氧基氨基甲酸甲酯反应合成了肟醚类氨基甲酸甲酯3a-e,进一步胺解之后得到了肟醚类氨基甲酰甲胺3f-j。

The yield reached 67.0% The medicinal and pesticidal activities of a part of the compounds have been measured .

在进行氨基酰化时,论文克服了该类嘧啶环上4位氨基在常规条件下不与芳香类和带有强吸电子基如三氯乙酰基酰化试剂发生反应的困难,通过采用在强碱性条件下进行酰化,得以成功。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力