酰氧基

Part 2. Annulation reaction of 3, 4-dichlorocoumarin (1) and 3, 4-dichloromaleimide (8) by a new general annulation strategy developed in this group with 2-phenylbenzofuran (15), 3-phenylbenzofuran (16), 2, 5-diphenyloxazole (17), 2, 5-diphenylthiazole (18), 2-methyl-4-phenylthiazole (19) and 2, 3-dimethoxy-1, 3-butadiene (40) were investigated.

二。在本课题组前一阶段提出的从二氯代环烯酮与1，1-二芳基乙烯的光化反应以及光化反应中得到的环丁烷产物的连续电环化反应对3，4-二氯马来酰亚胺以及3，4-二氯香豆素进行增环反应的工作基础上，研究了3，4-二氯香豆素（1）和3，4-二氯马来酰亚胺（8）与5个α-苯基取代的环烯烃2-苯基苯并呋喃（15），3-苯基苯并呋喃（16），2，5-二苯基噁唑（17），2，5-二苯基噻唑（18），2-甲基-4-苯基噻唑（19），以及一个丁二烯——2，3-二甲氧基丁二烯（40）进行的芳香族增环反应。

Methoxycoumarin-3-carboxylic acid geranyl ester was synthesized from geraniol and 8-methoxycoumarin-3-carboxylic acid and its structure was characterized by IR, HRMS, 1H NMR and 13C NMR.

采用酰氯酯化法，以8-甲氧基－香豆素－3-甲酸与香叶醇为原料合成了8-甲氧基－香豆素－3-甲酸香叶酯，经IR，HRMS，1H NMR，13C NMR等鉴定，证实了其结构。

Cephalotaxine ester of 2-oxo-6-methylheptanoic acid was treated with lithium diisopropylamide and Me O-(1-methoxyisopropyl)glycolate to give a mixture of homoisoharringtonine and its stereoisomers with 56% yield. The four stereoisomers separated by TLC showed identical mass spectra and almost superimposed IR but with different 1H NMR spectra. The configuration of the 2'-C and 3'-C of the four isomers were postulated based upon their 1H NMR spectra as compared with the 1H NMR spectra of isoharringtonine and its stereoisomers.

2-氧代-6-甲基庚酰基三尖杉碱(3)与0-(1-甲氧基异丙基)羟基乙酸甲酯(4)在强碱性试剂二异丙胺锂存在下，起亲核加成反应，反应中间体5在室温用酸性丙酮水解，得到一种新的三尖杉酯类生物碱一一高异三尖杉酯碱(6c)及其立体异构体(6a、6b、6d)的混合物，产率56%、通过制备薄层层析分得这四个立体异构体，它们的1H NMR和异三尖杉酯碱及其立体异构体的1H NMR类似，推定了它们的绝对构型。

Methacryloyloxydecyl-2-thiouracil-5-carboxylate was synthesized from the reaction of thiouracil with diethyl ethoxymethylene malonate and ω-hydroxy-decyl-methacrylate.

以硫脲、乙氧基次甲基丙二酸二乙酯和甲基丙烯酸ω-羟癸酯为主要原料合成了一种新的粘接性单体10-甲基丙烯酰氧癸基－2-硫脲嘧啶－5-羧酸酯。

The polymerization reacts from the inverse emulsion . Selecting white oil as continuous medium , Span60 and TX-10 as the complex emulsifier , AM-01﹑(NH4)2S2O4 and NaHSO3 as new-type complex initiator , the copolymerization of dimethylamino ethyl acrylate methyl chloride/acrylamide was developed . The effects of the concentration of monomer﹑emulsifier and initiator﹑ temperature﹑reaction time and pH on the molecular weight﹑intrinsic viscostity﹑conversion ratio and cation degree of copolymer were studied .

以反相乳液为初始聚合体系，油酸失水山梨醇酯Span60和辛基酚聚氧乙烯醚TX-10构成复配乳化剂，白油为连续介质，AM-01、过硫酸铵和亚硫酸氢钠组成新型复合引发体系，进行丙烯酰胺/（2-甲基丙烯酰氧乙基）三甲基氯化铵的反相准微乳液共聚合，研究了单体浓度、乳化剂、反应温度、反应时间、pH等因素对聚合产品分子量、特性粘数、转化率及阳离子度的影响。

EM analysis the worn surface morphology shows the following results: elastic deformation and fatigue are the main wear mechanisms of SMCC when impacted with lower erodent velocity, while the dominant mechanisms change into microcutting and microploughing with the increment erodent velocity.The slurry erosion behaviors of ceramic particles reinforced epoxy matrix composite coating were explored using a self-designed slurry pot tester.

首次采用自制的模拟罐式泥浆冲蚀试验机对环氧基复合涂料的泥浆冲蚀磨损性能进行了研究，通过调整固化剂聚酰胺与环氧的质量比，设计出最佳的基体组成；尽管涂层的铅笔硬度对其抗冲蚀性能有一定的影响，但起决定性作用的因素是涂层的韧性和硬度有机结合。

The intermediate which obtained from oximation of 7a-e reacted withmethyl N-(2-bromomethylphenyl)-N-methoxycarbamate to synthesize oxime ether methyl carbamate 3a-e.

以邻位卤代苯甲醛和3-丁烯-2-醇为原料通过钯催化&一锅法&反应合成了2-乙酰基茚7a-e，7a-e 肟化之后和N-(2-溴甲基苯基)-N-甲氧基氨基甲酸甲酯反应合成了肟醚类氨基甲酸甲酯3a-e，进一步胺解之后得到了肟醚类氨基甲酰甲胺3f-j。

In chapter four, molecular imprinting polymers against amino acid derivatives utilizing 2-VP+AM as combined functional monomer and trimethylolpropane trimethacrylate as tribasic cross-linker were prepared and result was compared with those with the same amino acid derivative as the imprinted molecules utilizing ethyleneglycol dimethacrylate as dibasic cross-linker. It was found that cross-link intensity of the molecular imprinting polymer is higher when TRIM was utilized and baseline separation for the imprinted molecule could be achieved. When TRIM was utilized as cross-linker more molecule is imprinted during the polymerization.

第四章采用2-乙烯基吡啶+丙烯酰胺复合功能单体，考察了三元交联剂三甲氧基丙烷三甲基丙烯酸酯烙印氨基酸衍生物的情况，并与二元交联剂乙二醇二甲基丙烯酸酯烙印相同氨基酸衍生物的情况进行了对比，发现三甲氧基丙烷三甲基丙烯酸酯交联剂在较小的用量下就可使分子烙印聚合物达到足够的交联度，实现烙印分子的基线分离。

Firstly, the 10-methoxy-5H-dibenzazepine is synthesized through brominating and methoxylation and hydrolyzation from 5H-dibenzb, fJazepine-5-carbonyl chloride.

首先，研究了以5-氯甲酰基亚氨基芪为原料，经溴化、甲氧基化、水解合成了10-甲氧基亚氨基芪。

A series of pH- and temperature-sensitive hydrogels carrying pendant phosphategroups have been synthesized by copolymerizing 2-methacryloyloxyethyl dihydrogenphosphate with N-isopropylacrylamide. The swelling ratio, swelling and deswellingkinetics have been investigated. High loading percentage of lysozyme into hydrogelshas been achieved and the release profile has been studied.

通过N-异丙基丙烯酰胺和含磷酸基团的单体2-甲基丙烯酰乙氧基二氢磷酸酯的共聚合，合成了一类含磷酸基团的既对温度敏感又对pH敏感的水凝胶，研究了它们在不同pH及温度时的溶胀率及溶胀动力学，并初步研究了其对溶菌酶的释放行为。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新